美国能源部---生物质平台化合物利用路线图_精品文档资料下载.pdf

美国能源部---生物质平台化合物利用路线图_精品文档资料下载.pdf

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A.AdenandJ.Bozell（NREL）;

J.HolladayandJ.White（PNNL）;

andAmyManheim（DOE-HQ）OtherContributions（research,models,databases,editing）:

D.Elliot,L.Lasure,S.JonesandM.Gerber（PNNL）;

K.Ibsen,L.LumbergandS.Kelley（NREL）August2004NationalRenewableEnergyLaboratoryNOTICEThisreportwaspreparedasanaccountofworksponsoredbyanagencyoftheUnitedStatesgovernment.NeithertheUnitedStatesgovernmentnoranyagencythereof,noranyoftheiremployees,makesanywarranty,expressorimplied,orassumesanylegalliabilityorresponsibilityfortheaccuracy,completeness,orusefulnessofanyinformation,apparatus,product,orprocessdisclosed,orrepresentsthatitsusewouldnotinfringeprivatelyownedrights.Referencehereintoanyspecificcommercialproduct,process,orservicebytradename,trademark,manufacturer,orotherwisedoesnotnecessarilyconstituteorimplyitsendorsement,recommendation,orfavoringbytheUnitedStatesgovernmentoranyagencythereof.TheviewsandopinionsofauthorsexpressedhereindonotnecessarilystateorreflectthoseoftheUnitedStatesgovernmentoranyagencythereof.Availableelectronicallyathttp:

/www.osti.gov/bridgeAvailableforaprocessingfeetoU.S.DepartmentofEnergyanditscontractors,inpaper,from:

U.S.DepartmentofEnergyOfficeofScientificandTechnicalInformationP.O.Box62OakRidge,TN37831-0062phone:

865.576.8401fax:

865.576.5728email:

mailto:

reportsadonis.osti.govAvailableforsaletothepublic,inpaper,from:

U.S.DepartmentofCommerceNationalTechnicalInformationService5285PortRoyalRoadSpringfield,VA22161phone:

800.553.6847fax:

703.605.6900email:

ordersntis.fedworld.govonlineordering:

http:

/www.ntis.gov/ordering.htmPrintedonpapercontainingatleast50%wastepaper,including20%postconsumerwasteAcknowledgement:

TheauthorsgratefullyacknowledgethesupportandassistancefromNRELstaffmembersS.Bower,E.Jarvis,M.Ruth,andA.SinghandreviewbyPaulStoneandMehmetGencer,independentconsultantsfromthechemicalindustryaswellasspecificinputandreviewsonportionsofthereportbyT.EggemanofNeotericsInternationalandBrianDavisonofOakRidgeNationalLaboratory.iiiTableofContentsExecutiveSummary.11Background.32Objective.43OverallApproach.54InitialScreeningtotheTop30.65SelectedSugar-derivedChemicals.136SyngasResultsTopProducts.177PathwaysandChallenges.188MovingForward.209Top12CandidateSummaryBios.219.1FourCarbon1,4-Diacids（Succinic,Fumaric,andMalic）.229.22,5-Furandicarboxylicacid（FDCA）.269.33-Hydroxypropionicacid（3-HPA）.299.4Asparticacid.319.5Glucaricacid.369.6Glutamicacid.399.7Itaconicacid.429.8Levulinicacid.459.93-Hydroxybutyrolactone.499.10Glycerol.529.11Sorbitol（AlcoholSugarofGlucose）.589.12Xylitol/arabinitol（Sugaralcoholsfromxyloseandarabinose）.6110CatalogofPotentialChemicalsandMaterialsfromBiomass.65ivBibliography.66ReferencesUsedtoDevelopCatalogforPotentialBiobasedProducts.66ReferencesforAssigningChemicalandBiochemicalPathways.66TablesTable1BiorefineryStrategicFitCriteria.6Table2TopCandidatesfromtheFirstScreen.8Table3DownSelectionTop30Results.12Table4TheTopSugar-derivedBuildingBlocks.13Table5SugarTransformationto3-HPA.14Table6ReductiveTransformation3HPto1,3PDOviacatalyticdehydrogenation.14Table7DehydrativeTransformation3-HPAtoacrylicacidviacatalyticdehydration.14Table8PathwaystoBuildingBlocksfromSugars.19Table9PathwaystoBuildingBlockFromSugarsFourCarbon1,4Diacids（Succinic,Fumaric,andMalic.22Table10Family1:

ReductionsPrimaryTransformationPathway（s）toDerivativesFourCarbon1,4-Diacids（Succinic,Fumaric,andMalic）.22Table11Family2:

ReductiveAminationsPrimaryTransformationPathway（s）toDerivatives-FourCarbon1,4-Diacids（Succinic,Fumaric,andMalic）.22Table12Family3:

DirectPolymerizationPrimaryTransformationPathway（s）toDerivatives-FourCarbon1,4-Diacids（Succinic,Fumaric,andMalic.23Table13PathwaystoBuildingBlockFromSugars2,5-FurandicarboxylicAcid（FDCA）26Table14Family1:

ReductionPrimaryTransformationPathway（s）toDeriva