美国能源部---生物质平台化合物利用路线图_精品文档资料下载.pdf

1、A.Aden and J.Bozell（NREL）;J.Holladay and J.White（PNNL）;and Amy Manheim（DOE-HQ）Other Contributions（research,models,databases,editing）:D.Elliot,L.Lasure,S.Jones and M.Gerber（PNNL）;K.Ibsen,L.Lumberg and S.Kelley（NREL）August 2004 National Renewable Energy Laboratory NOTICE This report was prepared as an

2、 account of work sponsored by an agency of the United States government.Neither the United States government nor any agency thereof,nor any of their employees,makes any warranty,express or implied,or assumes any legal liability or responsibility for the accuracy,completeness,or usefulness of any inf

3、ormation,apparatus,product,or process disclosed,or represents that its use would not infringe privately owned rights.Reference herein to any specific commercial product,process,or service by trade name,trademark,manufacturer,or otherwise does not necessarily constitute or imply its endorsement,recom

4、mendation,or favoring by the United States government or any agency thereof.The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States government or any agency thereof.Available electronically at http:/www.osti.gov/bridge Available for a process

5、ing fee to U.S.Department of Energy and its contractors,in paper,from:U.S.Department of Energy Office of Scientific and Technical Information P.O.Box 62 Oak Ridge,TN 37831-0062 phone:865.576.8401 fax:865.576.5728 email:mailto:reportsadonis.osti.gov Available for sale to the public,in paper,from:U.S.

6、Department of Commerce National Technical Information Service 5285 Port Royal Road Springfield,VA 22161 phone:800.553.6847 fax:703.605.6900 email:ordersntis.fedworld.gov online ordering:http:/www.ntis.gov/ordering.htm Printed on paper containing at least 50%wastepaper,including 20%postconsumer waste

7、 Acknowledgement:The authors gratefully acknowledge the support andassistance from NREL staff members S.Bower,E.Jarvis,M.Ruth,and A.Singh andreview by Paul Stone and Mehmet Gencer,independent consultants from thechemical industry as well as specific input and reviews on portions of the report by T.E

8、ggeman of Neoterics International and Brian Davison of Oak Ridge NationalLaboratory.iiiTable of Contents Executive Summary.1 1 Background.3 2 Objective.4 3 Overall Approach.5 4 Initial Screening to the Top 30.6 5 Selected Sugar-derived Chemicals.13 6 Syngas Results Top Products.17 7 Pathways and Cha

9、llenges.18 8 Moving Forward.20 9 Top 12 Candidate Summary Bios.21 9.1 Four Carbon 1,4-Diacids（Succinic,Fumaric,and Malic）.22 9.2 2,5-Furan dicarboxylic acid（FDCA）.26 9.3 3-Hydroxy propionic acid（3-HPA）.29 9.4 Aspartic acid.31 9.5 Glucaric acid.36 9.6 Glutamic acid.39 9.7 Itaconic acid.42 9.8 Levulin

10、ic acid.45 9.9 3-Hydroxybutyrolactone.49 9.10 Glycerol.52 9.11 Sorbitol（Alcohol Sugar of Glucose）.58 9.12 Xylitol/arabinitol（Sugar alcohols from xylose and arabinose）.61 10 Catalog of Potential Chemicals and Materials from Biomass.65 ivBibliography.66 References Used to Develop Catalog for Potential

11、 Biobased Products.66 References for Assigning Chemical and Biochemical Pathways.66 Tables Table 1 Biorefinery Strategic Fit Criteria.6 Table 2 Top Candidates from the First Screen.8 Table 3 Down Selection Top 30 Results.12 Table 4 The Top Sugar-derived Building Blocks.13 Table 5 Sugar Transformatio

12、n to 3-HPA.14 Table 6 Reductive Transformation 3HP to 1,3 PDO via catalytic dehydrogenation.14 Table 7 Dehydrative Transformation 3-HPA to acrylic acid via catalytic dehydration.14 Table 8 Pathways to Building Blocks from Sugars.19 Table 9 Pathways to Building Block From Sugars Four Carbon 1,4 Diaci

13、ds （Succinic,Fumaric,and Malic.22 Table 10 Family 1:Reductions Primary Transformation Pathway（s）to Derivatives Four Carbon 1,4-Diacids（Succinic,Fumaric,and Malic）.22 Table 11 Family 2:Reductive Aminations Primary Transformation Pathway（s）to Derivatives-Four Carbon 1,4-Diacids（Succinic,Fumaric,and Ma

14、lic）.22 Table 12 Family 3:Direct Polymerization Primary Transformation Pathway（s）to Derivatives-Four Carbon 1,4-Diacids（Succinic,Fumaric,and Malic.23 Table 13 Pathways to Building Block From Sugars 2,5-Furan dicarboxylic Acid（FDCA）26 Table 14 Family 1:Reduction Primary Transformation Pathway（s）to Deriva