完整版附录Ⅵ物质的标准摩尔生成焓标准摩尔生成吉.docx
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完整版附录Ⅵ物质的标准摩尔生成焓标准摩尔生成吉
附录Ⅵ物质的标准摩尔生成焓、标准摩尔生成吉
布斯函数、标准摩尔熵和摩尔热容(100kPa)>
(1)单质和无机物
物质
ΔfHm(298.15K)
ΔfGm(298.15K)
Sm(298.15K)
Cp,m(298.15K)
kJ·mol-1
kJ·mol-1
J·K-1mol-1
J·K-1·mol-1
Ag(s)
0
0
42.712
25.48
Ag2CO3(s)
-506.14
-437.09
167.36
Ag2O(s)
-30.56
-10.82
121.71
65.57
Al(s)
0
0
28.315
24.35
Al(g)
313.80
273.2
164.553
Al2O3-α
-1669.8
-2213.16
0.986
79.0
Al2(SO4)3(s)
-3434.98
-3728.53
239.3
259.4
Br2(g)
111.884
82.396
175.021
Br2(g)
30.71
3.109
245.455
35.99
Br2(l)
0
0
152.3
35.6
C(g)
718.384
672.942
158.101
C(金刚石)
1.896
2.866
2.439
6.07
C(石墨)
0
0
5.694
8.66
CO(g)
-110.525
-137.285
198.016
29.142
CO2(g)
-393.511
-394.38
213.76
37.120
Ca(s)
0
0
41.63
26.27
CaC2(s)
-62.8
-67.8
70.2
62.34
CaCO3(方解石)
-1206.87
-1128.70
92.8
81.83
CaCl2(s)
-795.0
-750.2
113.8
72.63
CaO(s)
-635.6
-604.2
39.7
48.53
Ca(OH)2(s)
-986.5
-896.89
76.1
84.5
CaSO4(硬石膏)
-1432.68
-1320.24
106.7
97.65
Cl-(aq)
-167.456
-131.168
55.10
Cl2(g)
0
0
222.948
33.9
Cu(s)
0
0
33.32
24.47
CuO(s)
-155.2
-127.1
43.51
44.4
Cu2O-α
-166.69
-146.33
100.8
69.8
F2(g)
0
0
203.5
31.46
Fe-α
0
0
27.15
25.23
FeCO3(s)
-747.68
-673.84
92.8
82.13
FeO(s)
-266.52
-244.3
54.0
51.1
Fe2O3(s)
-822.1
-741.0
90.0
104.6
Fe3O4(s)
-117.1
-1014.1
146.4
143.42
H(g)
217.94
203.122
114.724
20.80
H2(g)
0
0
130.695
28.83
D2(g)
0
0
144.884
29.20
HBr(g)
-36.24
-53.22
198.60
29.12
HBr(aq)
-120.92
-102.80
80.71
HCl(g)
-92.311
-95.265
186.786
29.12
HCl(aq)
-167.44
-131.17
55.10
H2CO3(aq)
-698.7
-623.37
191.2
Hl(g)
-25.94
-1.32
206.42
29.12
H2O(g)
-241.825
-228.577
188.823
33.571
H2O(l)
-285.838
-237.142
69.940
75.296
H2O(s)
-291.850
(-234.03)
(39.4)
H2O2(l)
-187.61
-118.04
102.26
82.29
H2S(g)
-20.146
-33.040
205.75
33.97
H2SO4(l)
-811.35
(-866.4)
156.85
137.57
H2SO4(aq)
-811.32
HSO4(aq)
-885.75
-752.99
126.86
l2(g)
0
0
116.7
55.97
I2(g)
62.242
19.34
260.60
36.87
N2(g)
0
0
191.598
29.12
NH3(g)
-46.19
-16.603
192.61
35.65
NO(g)
89.860
90.37
210.309
29.861
NO2(g)
33.85
51.86
240.57
37.90
N2O(g)
81.55
103.62
220.10
38.70
N2O4(g)
9.660
98.39
304.42
79.0
N2O5(g)
2.51
110.5
342.4
108.0
O(g)
247.521
230.095
161.063
21.93
O2(g)
0
0
205.138
29.37
O3(g)
142.3
163.45
237.7
38.15
OH-(aq)
-229.940
-157.297
-10.539
S(单斜)
0.29
0.096
32.55
23.64
S(斜方)
0
0
31.9
22.60
(g)
124.94
76.08
227.76
32.55
S(g)
222.80
182.27
167.825
SO2(g)
-296.90
-300.37
248.64
39.79
SO3(g)
-395.18
-370.40
256.34
50.70
SO42-(aq)
-907.51
-741.90
17.2
(2)有机化合物
物质
ΔfHm(298.15K)
ΔfGm(298.15K)
Sm(298.15K)
Cp,m(298.15K)
kJ·mol-1
kJ·mol-1
J·K-1mol-1
J·K-1·mol-1
烃 类
CH4(g), 甲烷
-74.847
50.827
186.30
35.715
C2H2(g), 乙炔
226.748
209.200
200.928
43.928
C2H4(g), 乙烯
52.283
68.157
219.56
43.56
C2H6(g), 乙烷
-84.667
-32.821
229.60
52.650
C3H6(g), 丙烯
20.414
62.783
267.05
63.89
C3H6(g), 丙烷
-103.847
-23.391
270.02
73.51
C4H6(g), 1,3-丁二烯
110.16
150.74
278.85
79.54
C4H8(g), 1-丁烯
-0.13
71.60
305.71
85.65
C4H8(g), 顺-2-丁烯
-6.99
65.96
300.94
78.91
C4H8(g), 反-2-丁烯
-11.17
63.07
296.59
87.82
C4H8(g), 2-甲基两烯
-16.90
58.17
293.70
89.12
C4H10(g), 正丁烷
-126.15
-17.02
310.23
97.45
C4H10(g), 异丁烷
-134.52
-20.79
294.75
96.82
C6H6(g), 苯
82.927
129.723
269.31
81.67
C6H6(l), 苯
49.028
124.597
172.35
135.77
C6H12(g), 环己烷
-123.14
31.92
298.51
106.27
C6H14(g), 正己烷
-167.19
-0.09
388.85
143.09
C6H14(l), 正己烷
-198.82
-4.08
295.89
194.93
C6H5CH3(g),甲苯
49.999
122.388
319.86
103.76
C6H5CH3(l),甲苯
11.995
114.299
219.58
157.11
C6H4(CH2)(g)邻二甲苯
18.995
122.207
352.86
133.26
C6H4(CH3)2(l), 邻二甲苯
-24.439
110.495
246.48
187.9
C6H4(CH3)2(g),间二甲苯
17.238
118.977
357.80
127.57
C6H(CH3)2(l), 间二甲苯
-25.418
107.817
252.17
183.3
C6H4(CH3)2(g),对二甲苯
17.949
121.266
352.53
126.86
C6H4(CH3)2(l), 对二甲苯
-24.426
110.244
247.36
183.7
含 氧 化 合 物
HCOH(g), 甲醛
-115.90
-110.0
220.2
35.36
HCOOH(g), 甲酸
-362.63
-335.69
251.1
54.4
HCOOH(l), 甲酸
-409.20
-345.9
128.95
99.04
CH3OH(g), 甲醇
-201.17
-161.83
237.8
49.4
CH3OH(l), 甲醇
-238.57
-166.15
126.8
81.6
CH2COH(g), 乙醛
-166.36
-133.67
265.8
62.8
CH3COOH(l), 乙酸
-487.0
-392.4
159.8
123.4
CH3COOH(g), 乙酸
-436.4
-381.5
293.4
72.4
C2H5OH(l), 乙醇
-277.63
-174.36
160.7
111.46
C2HOH(g), 乙醇
-235.31
-168.54
282.1
71.1
CH3COCH3(l),丙酮
-248.283
-155.33
200.0
124.73
CH3COCH3(g),丙酮
-216.69
-152.2
296.00
75.3
C2H5OC2H5(l),乙醚
-273.2
-116.47
253.1
CH3COOC2H5(l), 乙酸乙酯
-463.2
-315.3
259
C6H5COOH(s), 苯甲酸
-384.55
-245.5
170.7
155.2
卤 代 烃
CH3Cl(g), 氯甲烷
-82.0
-58.6
234.29
40.79
CH2Cl2(g), 二氯甲烷
-88
-59
270.62
51.38
CHCl3(l), 氯仿
-131.8
-71.4
202.9
116.3
CHCl3(g), 氯仿
-100
-67
296.48
65.81
CCl4(l), 四氯化碳
-139.3
-68.5
214.43
131.75
CCl4(g), 甲氯化碳
-106.7
-64.0
309.41
85.51
C6H5Cl(l), 氯苯
116.3
-198.2
197.5
145.6
含氮化合物
NH(CH3)2(g), 二甲胺
-27.6
59.1
273.2
69.37
C5H5N(l), 吡啶
78.87
159.9
179.1
C6H5NH2(l), 苯胺
35.31
153.35
191.6
199.6
C6H5NO2,(l)硝基苯
15.90
146.36
244.3
本附录数据主要取自HandbookofChemistryandPhysics,70thEd.,1990;EditorJohnA.Dean,Lange'sHandbookofChemistry,1967。