chapter 6 脂肪 英文版 营养学.docx

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chapter6脂肪英文版营养学

LipidBasics

Idon'thaveanycleversongparodiesthisweek.:

(Iknow,it'sdisappointing.Maybeyoucanmakeoneupandpostitintheforums?

Ourfabulousandexcitingtopicthisweekislipids!

Sotasty,andsoabused.Let'sstartwiththebasics,asusual.

Technicallyspeaking,therearethreetypesofmoleculesthatfallunderthecategoryof"lipids."Theseare triglycerides, phospholipids,and sterols.It'sprettyeasytoseethatbothtriglyceridesandphospholipidshavefattyacidandglycerolcomponents...butwhataboutsterols?

Theirchemicalstructurelookscompletelydifferent.Evenso,theonethingthatallthreehaveincommonistheirhydrophobicnature,andthisisthebasisoftheircategorizationaslipids.

AsIjustmentioned,bothphospholipidsandtriglycerideshavefattyacidcomponents,solet'stakeacloserlookattheseforamoment. Each fattyacid hasamethylgroup ononeendanda carboxylgroup ontheother.Theseareconnectedbya"carbonbackbone."Thisbackbonecanbejustafewormanycarbonsinlength.Thefattyacidsinfoodsmostcommonlycontainanevennumberofcarbonsintheirchains,andthisisimportantbecauseit'sthecarbonbackbonethatultimatelydeterminestheconsistencyandthetasteofthefat.

Therearetwofeaturesofthecarbonbackbonethatmostinfluenceit'sconsistency.Thefirstisthe length ofthecarbonbackbone.Ifthefattyacidhas2-4carbons,it'sconsideredtobea"short-chain"fattyacid.Ifithas6-10,it'sa"medium-chain"andifithas12ormorecarbonsit'sa"long-chain"fattyacid.Theshorterthefattyacid,themorelikelyitistobeliquidatroomtemperature;conversely,thelongerthefattyacid,themorelikelyitistobesolidatroomtemperature.

Thesecondmajorfactoraffectingconsistencyisthesaturationofthecarbonchain.Rememberfromchemistryclassthatcarboniscapableofmakingfourbonds.Whenallthecarbonsinafattyacidchainareallmakingfourbondseach,thefattyacidissaturated.Ifanyofthecarbonsinthechainaremakingadoublebonds,though,thenthatfattyacidisunsaturated.Ifthere'sjustonedoublebond,it'sa monounsaturated fat,whiletwoormoredoublebondsmakeafattyacid polyunsaturated.Asfarasconsistencygoes,themoresaturatedafattyacidis,themorelikelyitistobesolidatroomtemperature.Fattyacidsthatarepolyunsaturatedaremorelikelytobeliquid.Attheendoftheday,boththelengthandsaturationofthechaininfluencehowliquidorsolidthefatis.Scientistsgobackandforthrepeatedlybetweenmono-versuspolyunsaturatedasfaraswhichtypeoffatisthe"healthiest"toincludeinourdiets.Currentthinkingisthatoncewefulfilourminimumneedforpolyunsaturatedfat(discussedinthenextsection)it'sbesttogettherestofourfatfrommonounsaturatedsources.Weshouldminimizetheamountofsaturatedfatsinourdietasmuchaspossible.

It'sonlyunsaturatedfatsthatcanbe essential.Saturatedfats,whileextemelyimportant,arenotessentialbyournutritiondefinition-yourbodyhastheabilitytomakeallitneedssothere'snoneedforyoutogettheminyourdiet.Ifafatisunsaturated,wecanlookat thepositionofthefirstdoublebond inordertofigureoutwhetherit'sanessentialfattyacidornot.Whenmakingthedetermination,wenumberthemethylcarbonas"carbon#1."Iknow,Iknow,thisdoesnotfollowtherulesyouweretaughtinorganicchemistry.Idon'tknowwhyit'sdonethiswayforfattyacids,butitis.Ifitmakesyoufeelbetteratall,themethylcarbonisalsocalledthe"omegacarbon."Fromcarbon#1wecountdownthechaintothefirstcarboninvolvedinadoublebond.Ifthisendsupbeingbeforetheninthcarboninthechain,it'sanessentialfattyacid(a.k.a.essentialfat).

Checkoutthepolyunsaturatedfattyacidinthepicture,above.Noticethatthefirstdoublebondoccursatcarbonnumbersix.Thisisan omega-6 fattyacid!

Themostcommonexampleofanomega-6fattyacidislinoleicacid.Ontheotherhand,ifthefirstdoublebondwereatcarbonnumberthree,itwouldbean omega-3 fattyacid.Theomega-3'sthatyou'llhearthemostaboutarealpha-linolenicacid,docosahexaenoicacid(DHA)andeicosapentaenoicacid(EPA).Now,althoughhumansdoneedtoobtaintheseessentialfattyacidsinourdiet,itdoesn'ttakemuch-theaverageadultneedsonly2-4tablespoonsofplantoilseachdaytofulfilltherequirement.Fattyfishlikesalmon,halibut,whitefish,etc.arealsoagreatsource-aslongasthey'rebakedorbroiledandnotdeep-fried.

Theomega-3andomega-6fattyacidshavesomevitalbiologicalroles.Mostimportantly,theyaretheprecursorstomoleculescalled eicosanoids.Iknowyourtextbookgoesintosomeprettygorydetailaboutthevariouseicosanoidsandtheirfunctions.However,forourpurposes,Iwouldbethrilled

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