材料导论总结Word文件下载.docx
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LifeCycleAnalysis(LCA):
productstodeterminetheirimpactontheglobalenvironment.
andLifeCycleInventory(LCI);
whatinthemainpurposeofLCA?
Dealingwiththematerialsandprocessesinvolvedinproductsintermsofcostandenvironmentalimpacts.
1-11Whatisthedifferencebetweendesignforassemblyanddesignfordisassembly?
Designforassembly(装配)emphasizes(着重)easyproductassemblybyrobotsandotherautomatedequipment;
Designfordisassemblyisaconceptthatplacesrecyclingatthebeginningordesignstageofthematerialscycletoensurethatwastegoingintomunicipallandfillswillbeminimized.
1-14Howcanthestageofrecycling/disposalbecomethefirststageinthematerialscycle?
1-18Understandthetermsofmetals,alloysandpowderedmetals.
Metalsareelementsthatcanbedefinedbytheirproperties,suchasductility(延展性),toughness(韧性),malleability(可锻性),electricalandheatconductivity(导热系数),andthermalexpansion(热膨胀).
Alloy(合金)consists(由组成)ofmetalelementscombinedwithotherelements.
Powderedmetals:
alloyingofmetalsinvolvesmelting(融化)themainingredients(材料)togethersothatoncooling,themetalalloyisgenerallyanonporous(无孔的)solid.
1-19Listthesubgroups(子组)ofmetallics.
Ferrous,NonferrousandPowderedmetal
1-20Givesomeexamplesforferrousmetalsandnonferrousmetals.
Ferrous(黑色金属):
Iron,Steel,Castiron
Nonferrous(有色金属):
Cooper,Aluminum,Tin
Powderedmetals(粉末金属):
Sintered(烧结的)steel,Sinteredbrass(黄铜)
1-21Describethemainstagesinpreparingpowderedmetals
1-26Listthetwotypesofplasticsregardingprocessingmethod,andgivesomeexamplesforeachtype.
Thermosets(热固):
epoxy(环氧树脂),phenolic(酚醛树脂),andpolyurethane(聚氨酯).
Thermoplastics:
acrylics(丙烯酸树脂),nylonandpolyethylene(聚乙烯).
1-32Listthetypicalpropertiesofceramics(陶瓷).
Hard,brittle,stiffandhavehighmeltingpoints.
1-33Whattypeofchemicalbondsexistinginceramics?
Ionicbondsandcovalentbonding
1-49Understandthefollowingterms;
(a)catalyst(催化剂):
asubstancethatentersintoachemicalreactioninsuchawayastomakethereactiongofasterwithoutitselfbeingconsumed.
(b)stoichiometry(化学计量数):
thebranchofchemistrythatdealswithcalculationofmassimpliedinchemicalequations.
(c)factorofsafety(安全系数):
definedastheratioofunnormaloperationconditions
(d)allowablestress(许用应力)(ordesign,working,safestress):
themaximumlevelofstressthatapartwillbepermitted(允许)toendureunderoperationconditions.
Module2:
2-2Whatismatter(物质)?
Anythingthathasmassandoccupiesvolume.
Listthefourstatesinwhichmatterexists.
Liquid,Solid,GasandPlasma(等离子体)
2-7Describetheatomicstructure(原子结构),andexemplify(示例)thestandardnotation(标准符号)forexpressingthecompositionofnucleus.
Proton,Neutron,Electron,…..
2-9WhatistheValenceElectron(价电子)?
Describeitsinfluencesonthechemicalpropertiesofanelementandontheformation(构造)ofchemicalbonding.
ValenceElectron:
Thoseelectronsthatoccupytheoutermostringorshellfromthenucleus.Valenceisthecapacityofanelementtocombinewithotherelements.
2-10Explainthefollowingterms:
ionization(离子化),ionizationpotential(电离势能),electronegativity(电负性),electronaffinity(电子亲和性),electronconfiguration(电子排布).
Ionization:
theprocessofpullingaway(removing)oraddingvalenceelectronsfromabalancedorneutralatom.
Ionizationpotential:
theenergyrequiredtocausethelossofavalenceelectron.
Electronegativity:
thedegreetowhichanatomattractselectrons.
Electronaffinity:
thesameaselectronegativity
Electronconfiguration:
themannerinwhichtheelectronsofanatomdistributethemselvesintheground,orlowestenergy,state
2-11DescribetheelectronstructurewithClassicalTheoryandQuantumMechanicalTheory(量子力学),listingfourquantum(量子数)numberstocharacterize(描绘)anelectronastoitssize,shapeandspatialorientation(空间环境).
ClassicalTheory:
thepositionofelectronsinrelationtothenucleusofanatommustbedescribedintermsofaprobabilitydistribution(概率分布)ratherthanbythepreciselydeterminedvalue(精确值).
QuantumMechanicalTheory:
thebasisforanewbranchofphysics.---theideathatlightisquantized—thatitismadeupofdiscrete(离散)amountsofenergy.
Fourquantumnumbers:
1.shellsorprincipleenergylevels;
2.sublevel,subshell(亚层)ororbital(轨道);
3.thenumberofenergystatesforeachsubshell;
4.theelectronspin(电子自旋)moment.
2-13Exemplifytherelationshipthatcanbeusedtodeterminethemaximumnumberofelectronsatanyenergylevel.
2*n^2
2-19WhatistheChemicalBonding?
Whatarethegroupsandsubgroupsofthechemicalbounding?
Chemicalbonding:
explainedsimplyastheendproductoftheinteraction(相互作用)oftheelectricalforcesofattractionandrepulsion(排斥)betweenoppositelychargedorsimilarlychargedparticles(带电粒子)ofmatter.
Groups:
Primarybonding(主价键)andsecondarybonding
Subgroups:
Primarybonding:
covalentbonding,ionicbonding,metallicbonding;
SecondaryBonding:
hydrogenboning,vanderwaalsforces
2-20Understandtheterms:
(a)chemicalbonding;
(b)covalentorsharedelectron-pairbonding;
(c)triplecovalent:
oneinwhichtwoatomssharethreeoftheirelectronswitheachother.
(d)ionicbonding;
someelementsactuallyswaportransferelectronstootherelements
(e)metallicbonding;
theseareshieldedfromthestrongattractiveforcesofthepositivenucleusbytheinnerelectronsandthustheybondtothenucleusrelativelyweakly
(f)polarmolecule:
boththepositiveandnegativechargesarelocalizedwithinthemolecule
(g)nonpolarmolecule;
eachatomsharesthebondingelectronsequally,producinganelectricalchargedistributionthatissymmetricalaboutalinejoiningthetwonuclei
(j)hydrogenbond.Theoxygenatom,havingaslightnegativecharge,attractsapositivehydrogenatombelongingtoanadjacentwatermolecule
2-21Whatkeywordcanbeusedtodescribecovalentbonding,ionicbonding,andmetallicbonding?
Ionicbonding:
electronswapping
Covalentbonding:
electronsharing
Metallicbonding:
electronswarming
2-23Howisthehydrogenbondformed?
Thecovalentbondsbetweenthehydrogenandoxygenatomsinawatermolecule,beingpolar,resultinanasymmetricalchargedistribution.Theoxygenatom,havingaslightnegativecharge,attractsapositivehydrogenatombelongingtoanadjacentwatermoleculeandformsahydrogenbond.
Exemplifythecontributionsofhydrogenbondtothepropertiesandbehaviorofpolymericmaterials.
Thehydrogenbondaffectsthepropertiesandbehaviorofmaterials.Inthermoplastics,thehydrogenbondjoinslong,chainlikemoleculestoeachother.Theserelativelyweakbondscanbeeasilyloosenedorbrokenbyheating,permittingflow(流动)totakeplace.
2-24Listthetwoformsofmicrostructure(微观结构)ofsolid.Whatisthedifferencebetweenthemintermsofatomicarrangement?
Amorphous(无定型的):
containsnorepetitious(重复的)patternofatomlocationstoany
extent(范围).
Crystalline(晶体):
possesses(控制)anordered,three-dimensional(三维的),geometricarrangementthatrepeatsitself.
2-26Definetheterms:
unitcells(晶胞),spacelattices(空间点阵),andintercepts.
Unitecell:
usedtodescribethebasicbuildingblockorbasicgeometricarrangementofatomsinacrystal.
Spacelattices:
repeattheunitcellinallthreedimensions,youcreateacrystallinestructurewithadefinitepattern.Thislargerpatternofatomsinasinglecrystalisknownasaspacelattices.
Intercepts:
Thesidesofthebox,labeleda,b,c,arethelatticeparameters(晶格参数)inx,y,andzdirections,respectively.Thesedistancesarealsoknownasintercepts.
2-27Whatarethesevencrystalsystems?
Howmanyspacelatticescanatomsform?
1.simplecubicunitcell:
2.body-centeredcubic;
3.face-centeredcubic;
4.body-centeredtetragonal(四边)crystallatticeunitcell;
5.hexagonal(六边)crystalsystem;
6.close-packedhexagonalcrystallatticeunitcell
7.orthorhombic(正交晶)andmonoclinicunitcell
2-28Describetheinterceptsofcubic,tetragonal,andhexagonalcrystalsystems.
Cubic:
a=b=c
Tetragonal:
a=b≠c
Hexagonal:
a=a≠c
2-29Whatarethethreebasiccubiccrystalsystems?
Whataretheirabbreviations(缩写)?
Simplecubic—sc
Body-centeredcubic---bcc
Face-centeredcubic---fcc
2-37【polymorphism(多态性),allotropy(同素异形),atomicpackingfactor(原子堆积因数))Understandtheterms:
coordinationnumber(配位数),polymorphism,allotropy,atomicpackingfactorandvoidfraction(空隙率).
Coordinationnumber(CN):
todescribehowmanyatomsaretouchingeachotherinagroupofcoordinatedatoms.
Polymorphism:
thephenomenonthatelementsthatexistinmorethanon