材料导论总结Word文件下载.docx

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材料导论总结Word文件下载.docx

LifeCycleAnalysis(LCA):

productstodeterminetheirimpactontheglobalenvironment.

andLifeCycleInventory(LCI);

whatinthemainpurposeofLCA?

Dealingwiththematerialsandprocessesinvolvedinproductsintermsofcostandenvironmentalimpacts.

1-11Whatisthedifferencebetweendesignforassemblyanddesignfordisassembly?

 

Designforassembly(装配)emphasizes(着重)easyproductassemblybyrobotsandotherautomatedequipment;

Designfordisassemblyisaconceptthatplacesrecyclingatthebeginningordesignstageofthematerialscycletoensurethatwastegoingintomunicipallandfillswillbeminimized.

1-14Howcanthestageofrecycling/disposalbecomethefirststageinthematerialscycle?

1-18Understandthetermsofmetals,alloysandpowderedmetals.

Metalsareelementsthatcanbedefinedbytheirproperties,suchasductility(延展性),toughness(韧性),malleability(可锻性),electricalandheatconductivity(导热系数),andthermalexpansion(热膨胀).

Alloy(合金)consists(由组成)ofmetalelementscombinedwithotherelements.

Powderedmetals:

alloyingofmetalsinvolvesmelting(融化)themainingredients(材料)togethersothatoncooling,themetalalloyisgenerallyanonporous(无孔的)solid.

1-19Listthesubgroups(子组)ofmetallics.

Ferrous,NonferrousandPowderedmetal

1-20Givesomeexamplesforferrousmetalsandnonferrousmetals.

Ferrous(黑色金属):

Iron,Steel,Castiron

Nonferrous(有色金属):

Cooper,Aluminum,Tin

Powderedmetals(粉末金属):

Sintered(烧结的)steel,Sinteredbrass(黄铜)

1-21Describethemainstagesinpreparingpowderedmetals

1-26Listthetwotypesofplasticsregardingprocessingmethod,andgivesomeexamplesforeachtype.

Thermosets(热固):

epoxy(环氧树脂),phenolic(酚醛树脂),andpolyurethane(聚氨酯).

Thermoplastics:

acrylics(丙烯酸树脂),nylonandpolyethylene(聚乙烯).

1-32Listthetypicalpropertiesofceramics(陶瓷).

Hard,brittle,stiffandhavehighmeltingpoints.

1-33Whattypeofchemicalbondsexistinginceramics?

Ionicbondsandcovalentbonding

1-49Understandthefollowingterms;

(a)catalyst(催化剂):

asubstancethatentersintoachemicalreactioninsuchawayastomakethereactiongofasterwithoutitselfbeingconsumed.

(b)stoichiometry(化学计量数):

thebranchofchemistrythatdealswithcalculationofmassimpliedinchemicalequations.

(c)factorofsafety(安全系数):

definedastheratioofunnormaloperationconditions

(d)allowablestress(许用应力)(ordesign,working,safestress):

themaximumlevelofstressthatapartwillbepermitted(允许)toendureunderoperationconditions.

Module2:

2-2Whatismatter(物质)?

Anythingthathasmassandoccupiesvolume.

Listthefourstatesinwhichmatterexists.

Liquid,Solid,GasandPlasma(等离子体)

2-7Describetheatomicstructure(原子结构),andexemplify(示例)thestandardnotation(标准符号)forexpressingthecompositionofnucleus.

Proton,Neutron,Electron,…..

2-9WhatistheValenceElectron(价电子)?

Describeitsinfluencesonthechemicalpropertiesofanelementandontheformation(构造)ofchemicalbonding.

ValenceElectron:

Thoseelectronsthatoccupytheoutermostringorshellfromthenucleus.Valenceisthecapacityofanelementtocombinewithotherelements.

2-10Explainthefollowingterms:

ionization(离子化),ionizationpotential(电离势能),electronegativity(电负性),electronaffinity(电子亲和性),electronconfiguration(电子排布).

Ionization:

theprocessofpullingaway(removing)oraddingvalenceelectronsfromabalancedorneutralatom.

Ionizationpotential:

theenergyrequiredtocausethelossofavalenceelectron.

Electronegativity:

thedegreetowhichanatomattractselectrons.

Electronaffinity:

thesameaselectronegativity

Electronconfiguration:

themannerinwhichtheelectronsofanatomdistributethemselvesintheground,orlowestenergy,state

2-11DescribetheelectronstructurewithClassicalTheoryandQuantumMechanicalTheory(量子力学),listingfourquantum(量子数)numberstocharacterize(描绘)anelectronastoitssize,shapeandspatialorientation(空间环境).

ClassicalTheory:

thepositionofelectronsinrelationtothenucleusofanatommustbedescribedintermsofaprobabilitydistribution(概率分布)ratherthanbythepreciselydeterminedvalue(精确值).

QuantumMechanicalTheory:

thebasisforanewbranchofphysics.---theideathatlightisquantized—thatitismadeupofdiscrete(离散)amountsofenergy.

Fourquantumnumbers:

1.shellsorprincipleenergylevels;

2.sublevel,subshell(亚层)ororbital(轨道);

3.thenumberofenergystatesforeachsubshell;

4.theelectronspin(电子自旋)moment.

2-13Exemplifytherelationshipthatcanbeusedtodeterminethemaximumnumberofelectronsatanyenergylevel.

2*n^2

2-19WhatistheChemicalBonding?

Whatarethegroupsandsubgroupsofthechemicalbounding?

Chemicalbonding:

explainedsimplyastheendproductoftheinteraction(相互作用)oftheelectricalforcesofattractionandrepulsion(排斥)betweenoppositelychargedorsimilarlychargedparticles(带电粒子)ofmatter.

Groups:

Primarybonding(主价键)andsecondarybonding

Subgroups:

Primarybonding:

covalentbonding,ionicbonding,metallicbonding;

SecondaryBonding:

hydrogenboning,vanderwaalsforces

2-20Understandtheterms:

(a)chemicalbonding;

(b)covalentorsharedelectron-pairbonding;

(c)triplecovalent:

oneinwhichtwoatomssharethreeoftheirelectronswitheachother.

(d)ionicbonding;

someelementsactuallyswaportransferelectronstootherelements

(e)metallicbonding;

theseareshieldedfromthestrongattractiveforcesofthepositivenucleusbytheinnerelectronsandthustheybondtothenucleusrelativelyweakly

(f)polarmolecule:

boththepositiveandnegativechargesarelocalizedwithinthemolecule 

(g)nonpolarmolecule;

eachatomsharesthebondingelectronsequally,producinganelectricalchargedistributionthatissymmetricalaboutalinejoiningthetwonuclei

(j)hydrogenbond.Theoxygenatom,havingaslightnegativecharge,attractsapositivehydrogenatombelongingtoanadjacentwatermolecule

2-21Whatkeywordcanbeusedtodescribecovalentbonding,ionicbonding,andmetallicbonding?

Ionicbonding:

electronswapping

Covalentbonding:

electronsharing

Metallicbonding:

electronswarming

2-23Howisthehydrogenbondformed?

Thecovalentbondsbetweenthehydrogenandoxygenatomsinawatermolecule,beingpolar,resultinanasymmetricalchargedistribution.Theoxygenatom,havingaslightnegativecharge,attractsapositivehydrogenatombelongingtoanadjacentwatermoleculeandformsahydrogenbond.

Exemplifythecontributionsofhydrogenbondtothepropertiesandbehaviorofpolymericmaterials.

Thehydrogenbondaffectsthepropertiesandbehaviorofmaterials.Inthermoplastics,thehydrogenbondjoinslong,chainlikemoleculestoeachother.Theserelativelyweakbondscanbeeasilyloosenedorbrokenbyheating,permittingflow(流动)totakeplace.

2-24Listthetwoformsofmicrostructure(微观结构)ofsolid.Whatisthedifferencebetweenthemintermsofatomicarrangement?

Amorphous(无定型的):

containsnorepetitious(重复的)patternofatomlocationstoany 

extent(范围).

Crystalline(晶体):

possesses(控制)anordered,three-dimensional(三维的),geometricarrangementthatrepeatsitself.

2-26Definetheterms:

unitcells(晶胞),spacelattices(空间点阵),andintercepts.

Unitecell:

usedtodescribethebasicbuildingblockorbasicgeometricarrangementofatomsinacrystal.

Spacelattices:

repeattheunitcellinallthreedimensions,youcreateacrystallinestructurewithadefinitepattern.Thislargerpatternofatomsinasinglecrystalisknownasaspacelattices.

Intercepts:

Thesidesofthebox,labeleda,b,c,arethelatticeparameters(晶格参数)inx,y,andzdirections,respectively.Thesedistancesarealsoknownasintercepts.

2-27Whatarethesevencrystalsystems?

Howmanyspacelatticescanatomsform?

1.simplecubicunitcell:

2.body-centeredcubic;

3.face-centeredcubic;

4.body-centeredtetragonal(四边)crystallatticeunitcell;

5.hexagonal(六边)crystalsystem;

6.close-packedhexagonalcrystallatticeunitcell

7.orthorhombic(正交晶)andmonoclinicunitcell

2-28Describetheinterceptsofcubic,tetragonal,andhexagonalcrystalsystems.

Cubic:

a=b=c

Tetragonal:

a=b≠c

Hexagonal:

a=a≠c

2-29Whatarethethreebasiccubiccrystalsystems?

Whataretheirabbreviations(缩写)?

Simplecubic—sc

Body-centeredcubic---bcc

Face-centeredcubic---fcc

2-37【polymorphism(多态性),allotropy(同素异形),atomicpackingfactor(原子堆积因数))Understandtheterms:

coordinationnumber(配位数),polymorphism,allotropy,atomicpackingfactorandvoidfraction(空隙率).

Coordinationnumber(CN):

todescribehowmanyatomsaretouchingeachotherinagroupofcoordinatedatoms.

Polymorphism:

thephenomenonthatelementsthatexistinmorethanon

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