化学反应工程实验数据处理要点.docx
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化学反应工程实验数据处理要点
实验：
连续均相反应器停留时间分布的测定
实验装置及流程：
实验数据记录
流量：
20L/H示踪剂注入量：
3ml
釜
A
B
C
单釜
平均t/s
100.81
182.9
293.68
139.4
方差
0.76
0.31
0.01
0.6
釜数
1.31
3.26
78.28
1.66
流量：
20L/H示踪剂注入量：
4ml
釜
A
B
C
单釜
平均t/s
113.96
190.5
322.44
149.18
方差
0.72
0.28
-0.05
0.52
釜数
1.39
3.52
-21.6
1.91
流量：
15L/H示踪剂注入量：
4ml
流量：
15L/H示踪剂注入量：
3ml
实验：
液固催化反应动力学测定
温度/℃
初始PH
初始碱浓度/（mol/L）
NaOH流量/（m3/h）
酯流量/（m3/h）
最终PH
最终碱浓度/（mol/L）
27.4℃
11.85
0.007079458
4.2
8.82
10.44
0.000275423
11.85
0.007079458
5.25
11.13
10.69
0.000489779
11.85
0.007079458
6.51
13.86
10.85
0.000707946
37.5℃
11.85
0.007079458
4.2
8.82
10.26
0.00018197
11.85
0.007079458
5.25
11.13
10.42
0.000263027
11.85
0.007079458
6.51
13.86
10.54
0.000346737
35.0℃
12.1
0.012589254
5.25
11.13
10.42
0.000263027
12.1
0.012589254
6.51
13.86
10.54
0.000346737
45.0℃
11.8
0.006309573
4.2
8.82
9.94
8.70964E-05
11.58
0.003801894
5.25
11.53
9.99
9.77237E-05
11.58
0.003801894
6.51
13.86
9.98
9.54993E-05
55.0℃
10.9
0.000794328
4.2
8.82
7.44
2.75423E-07
10.88
0.000758578
5.25
11.53
7.1
1.25893E-07
10.84
0.000691831
6.51
13.86
6.91
8.12831E-08
温度/℃
CA0/CA
t
k’
27.4℃
25.70395783
7.33333E-05
610000
14.45439771
5.86667E-05
10
4.73118E-05
35.0℃
47.86300923
5.86667E-05
1000000
36.30780548
4.73118E-05
37.5℃
38.9045145
7.33333E-05
720000
26.91534804
5.86667E-05
20.41737945
4.73118E-05
45.0℃
72.44359601
7.33333E-05
1300000
38.9045145
5.86667E-05
39.81071706
4.73118E-05
55.0℃
2884.031503
7.33333E-05
-220000000
6025.595861
5.86667E-05
8511.380382
4.73118E-05
温度T/K
温度倒数1/T（K-1）
k'
lnk'
300.55
0.003327233
610000
13.32121424
308.15
0.003245173
1000000
13.81551056
310.65
0.003219057
720000
13.48700649
318.15
0.003143171
1300000
14.07787482
328.15
0.003047387
-220000000
无解
实验：
气升式环流反应器流体力学及传质性能的测定
H0=942mm
H=948mm
时间t/s
流量L/（kg/h）
导电率
时间t/s
流量L/（kg/h）
导电率
0
2000
0.129
14
2000
0.154
0.5
2000
0.129
14.5
2000
0.156
1
2000
0.104
15
2000
0.156
1.5
2000
0.104
15.5
2000
0.156
2
2000
0.104
16
2000
0.163
2.5
2000
0.086
16.5
2000
0.163
3
2000
0.086
17
2000
0.169
3.5
2000
0.135
17.5
2000
0.169
4
2000
0.135
18
2000
0.168
4.5
2000
0.213
18.5
2000
0.168
5
2000
0.213
19
2000
0.166
5.5
2000
0.204
19.5
2000
0.166
6
2000
0.204
20
2000
0.161
6.5
2000
0.182
20.5
2000
0.161
7
2000
0.182
21
2000
0.162
7.5
2000
0.137
21.5
2000
0.162
8
2000
0.137
22
2000
0.164
8.5
2000
0.144
22.5
2000
0.164
9
2000
0.144
23
2000
0.166
9.5
2000
0.161
23.5
2000
0.166
10
2000
0.161
24
2000
0.166
10.5
2000
0.181
24.5
2000
0.166
11
2000
0.181
25
2000
0.164
11.5
2000
0.177
25.5
2000
0.164
12
2000
0.177
26
2000
0.163
12.5
2000
0.164
26.5
2000
0.163
13
2000
0.164
27
2000
0.163
13.5
2000
0.154
时间t/s
电压U/V
Umax-U*
ln[（Umax-U*）/（Umax-U）]
时间t/s
电压U/V
Umax-U*
ln[（Umax-U*）/（Umax-U）]
8
3.4
11.9
0
123
10.8
4.5
0.972461003
8.5
3.4
11.9
0
123.5
10.8
4.5
0.972461003
9
3.5
11.8
0.008438869
124
10.8
4.5
0.972461003
9.5
3.5
11.8
0.008438869
124.5
10.7
4.6
0.950482097
10
3.6
11.7
0.016949558
125
10.7
4.6
0.950482097
10.5
3.6
11.7
0.016949558
125.5
10.7
4.6
0.950482097
11
3.6
11.7
0.016949558
126
10.7
4.6
0.950482097
11.5
3.6
11.7
0.016949558
126.5
10.6
4.7
0.928975891
12
3.6
11.7
0.016949558
127
10.6
4.7
0.928975891
12.5
3.4
11.9
0
127.5
10.7
4.6
0.950482097
13
3.4
11.9
0
128
10.7
4.6
0.950482097
13.5
3.6
11.7
0.016949558
128.5
10.9
4.4
0.994933859
14
3.6
11.7
0.016949558
129
10.9
4.4
0.994933859
14.5
3.6
11.7
0.016949558
129.5
10.9
4.4
0.994933859
15
3.6
11.7
0.016949558
130
10.8
4.5
0.972461003
15.5
3.7
11.6
0.025533302
130.5
10.8
4.5
0.972461003
16
3.7
11.6
0.025533302
131
10.9
4.4
0.994933859
16.5
3.6
11.7
0.016949558
131.5
10.9
4.4
0.994933859
17
3.6
11.7
0.016949558
132
11
4.3
1.017923377
17.5
3.6
11.7
0.016949558
132.5
11
4.3
1.017923377
18
3.6
11.7
0.016949558
133
11.1
4.2
1.041453875
18.5
3.6
11.7
0.016949558
133.5
11.1
4.2
1.041453875
19
3.6
11.7
0.016949558
134
11.2
4.1
1.065551426
19.5
3.8
11.5
0.034191365
134.5
11.2
4.1
1.065551426
20
3.8
11.5
0.034191365
135
11.2
4.1
1.065551426
20.5
3.7
11.6
0.025533302
135.5
11.2
4.1
1.065551426
21
3.7
11.6
0.025533302
136
11.2
4.1
1.065551426
21.5
3.7
11.6
0.025533302
136.5
11.2
4.1
1.065551426
22
3.7
11.6
0.025533302
137
11.2
4.1
1.065551426
22.5
3.7
11.6
0.025533302
137.5
11.2
4.1
1.065551426
23
3.6
11.7
0.016949558
138
11.2
4.1
1.065551426
23.5
3.6
11.7
0.016949558
138.5
11.2
4.1
1.065551426
24
3.7
11.6
0.025533302
139
11.2
4.1
1.065551426
24.5
3.7
11.6
0.025533302
139.5
11.3
4
1.090244039
25
3.7
11.6
0.025533302
140
11.3
4
1.090244039
25.5
3.7
11.6
0.025533302
140.5
11.4
3.9
1.115561847
26
3.6
11.7
0.016949558
141
11.4
3.9
1.115561847
26.5
3.6
11.7
0.016949558
141.5
11.4
3.9
1.115561847
27
3.8
11.5
0.034191365
142
11.4
3.9
1.115561847
27.5
3.8
11.5
0.034191365
142.5
11.3
4
1.090244039
28
3.8
11.5
0.034191365
143
11.3
4
1.090244039
28.5
3.8
11.5
0.034191365
143.5
11.3
4
1.090244039
29
3.8
11.5
0.034191365
144
11.3
4
1.090244039
29.5
3.8
11.5
0.034191365
144.5
11.4
3.9
1.115561847
30
3.8
11.5
0.034191365
145
11.4
3.9
1.115561847
30.5
4
11.3
0.051735674
145.5
11.5
3.8
1.141537333
31
4
11.3
0.051735674
146
11.5
3.8
1.141537333
31.5
4
11.3
0.051735674
146.5
11.5
3.8
1.141537333
32
4
11.3
0.051735674
147
11.5
3.8
1.141537333
32.5
4.1
11.2
0.060624622
147.5
11.5
3.8
1.141537333
33
4.1
11.2
0.060624622
148
11.6
3.7
1.16820558
33.5
4.3
11
0.078643127
148.5
11.6
3.7
1.16820558
34
4.3
11
0.078643127
149
11.6
3.7
1.16820558
34.5
4.3
11
0.078643127
149.5
11.6
3.7
1.16820558
35
4.3
11
0.078643127
150
11.7
3.6
1.195604555
35.5
4.3
11
0.078643127
150.5
11.7
3.6
1.195604555
36
4.3
11
0.078643127
151
11.9
3.4
1.252762968
36.5
4.4
10.9
0.087775611
151.5
11.9
3.4
1.252762968
37
4.4
10.9
0.087775611
152
11.8
3.5
1.223775432
37.5
4.5
10.8
0.096992266
152.5
11.8
3.5
1.223775432
38
4.5
10.8
0.096992266
153
11.9
3.4
1.252762968
38.5
4.8
10.5
0.125163143
153.5
11.9
3.4
1.252762968
39
4.8
10.5
0.125163143
154
11.9
3.4
1.252762968
39.5
4.8
10.5
0.125163143
154.5
11.9
3.4
1.252762968
40
4.8
10.5
0.125163143
155
11.9
3.4
1.252762968
40.5
4.8
10.5
0.125163143
155.5
11.9
3.4
1.252762968
41
4.9
10.4
0.134732594
156
11.9
3.4
1.252762968
41.5
4.9
10.4
0.134732594
156.5
11.9
3.4
1.252762968
42
5.1
10.2
0.15415068
157
11.9
3.4
1.252762968
42.5
5.1
10.2
0.15415068
157.5
12.9
2.4
1.601069663
43
5.4
9.9
0.184003643
158
12.9
2.4
1.601069663
43.5
5.4
9.9
0.184003643
158.5
12.8
2.5
1.560247668
44
5.1
10.2
0.15415068
159
12.8
2.5
1.560247668
44.5
5.1
10.2
0.15415068
159.5
12.7
2.6
1.521026955
45
5.3
10
0.173953307
160
12.7
2.6
1.521026955
45.5
5.3
10
0.173953307
160.5
12.7
2.6
1.521026955
46
5.3
10
0.173953307
161
12.7
2.6
1.521026955
46.5
5.3
10
0.173953307
161.5
13.1
2.2
1.68808104
47
5.6
9.7
0.204412515
162
13.1
2.2
1.68808104
47.5
5.6
9.7
0.204412515
162.5
11.8
3.5
1.223775432
48
5.6
9.7
0.204412515
163
11.8
3.5
1.223775432
48.5
5.6
9.7
0.204412515
163.5
12.7
2.6
1.521026955
49
5.6
9.7
0.204412515
164
12.7
2.6
1.521026955
49.5
5.7
9.6
0.214775302
164.5
12.8
2.5
1.560247668
50
5.7
9.6
0.214775302
165
12.8
2.5
1.560247668
50.5
5.8
9.5
0.225246602
165.5
12.8
2.5
1.560247668
51
5.8
9.5
0.225246602
166
12.8
2.5
1.560247668
51.5
5.8
9.5
0.225246602
166.5
12.8
2.5
1.560247668
52
5.8
9.5
0.225246602
167
13.2
2.1
1.734601055
52.5
6
9.3
0.246524
167.5
13.2
2.1
1.734601055
53
6
9.3
0.246524
168
12.9
2.4
1.601069663
53.5
6.2
9.1
0.268263987
168.5
12.9
2.4
1.601069663
54
6.2
9.1
0.268263987
169
13.1
2.2
1.68808104
54.5
6.2
9.1
0.268263987
169.5
13.1
2.2
1.68808104
55
6.2
9.1
0.268263987
170
13.1
2.2
1.68808104
55.5
6.4
8.9
0.290487123
170.5
13.1
2.2
1.68808104
56
6.4
8.9
0.290487123
171
12.9
2.4
1.601069663
56.5
6.4
8.9
0.290487123
171.5
12.9
2.4
1.601069663
57
6.3
9
0.279313823
172
13
2.3
1.643629277
57.5
6.3
9
0.279313823
172.5
13
2.3
1.643629277
58
6.3
9
0.279313823
173
13.1
2.2
1.68808104
58.5
6.3
9
0.279313823
173.5
13.1
2.2
1.68808104
59
6.4
8.9
0.290487123
174
13.1
2.2
1.68808104
59.5
6.4
8.9
0.290487123
174.5
13
2.3
1.643629277
60
6.5
8.8
0.301786679
175
13
2.3
1.643629277
60.5
6.5
8.8
0.301786679
175.5
13
2.3
1.643629277
61
6.6
8.7
0.313215374
176
13
2.3
1.643629277
61.5
6.6
8.7
0.313215374
176.5
12.8
2.5
1.560247668
62
6.6
8.7
0.313215374
177
12.8
2.5
1.560247668
62.5
6.6
8.7
0.313215374
177.5
12.8
2.5
1.560247668
63
7
8.3
0.360282885
178
12.8
2.5
1.560247668
63.5
7
8.3
0.360282885
178.5
12.7
2.6
1.521026955
64
6.9
8.4
0.348306694
179
12.7
2.6
1.521026955
64.5
6.9
8.4
0.348306694
179.5
12.7
2.6
1.521026955
65
7
8.3
0.360282885
180
12.7
2.6
1.521026955
65.5
7
8.3
0.360282885
180.5
12.7
2.6
1.521026955
66
7
8.3
0.360282885
181
12.7
2.6
1.521026955
66.5
7.1
8.2
0.372404246
181.5
13.3
2
1.78339122
67
7.1
8.2
0.372404246
182
13.3
2
1.78339122
67.5
7.2
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