外文翻译低热硅酸盐水泥混凝土的抗裂性能Word文件下载.docx
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Abstract:
Thepropertiesoflow-heatPortlandcementconcrete(LHC)werestudiedindetail.TheexperimentalresultsshowthattheLHCconcretehascharacteristicsofahigherphysicalmechanicalbehavior,deformationanddurability.Comparedwithmoderate-heatPortlandcement(MHC),theaveragehydrationheatofLHCconcreteisreducedbyabout17.5%.Undersamemixingproportion,theadiabatictemperatureriseofLHCconcretewasreducedby2℃-3℃,andthelimitstensionofLHCconcretewasincreasedby10×
10-6-15×
10-6thanthatofMHC.Moreover,itisindicatedthatLHCconcretehasabetteranti-crackbehaviorthanMHCconcrete.
Keywords:
low-heatportlandcement;
massconcrete;
highcrackresistance;
moderate-heatportlandcement
1Introduction
Theinvestigationoncrackofmassconcreteisahotproblemtowhichattentionhasbeenpaidforalongtime.Thecracksoftheconcreteareformedbymulti-factors,buttheyaremainlycausedbythermaldisplacementsinmassconcrete[1-3].Sothekeytechnologyonmassconcreteishowtoreducethermaldisplacementsandenhancethecrackresistanceofconcrete.
Aswellknown,thehydrationheatofbondingmaterialsisthemainreasonthatresultsinthetemperaturedifferencebetweenoutsideandinsideofmassconcrete[4,5].Inordertoreducetheinnertemperatureofhydroelectricconcrete,severalmethodshavebeenproposedinmixproportiondesign.Theseincludeusingmoderate-heatportlandcement(MHC),reducingthecontentofcement,andincreasingthePortlandcement(OPC),MHChasadvantagessuchaslowheatofhydration,highgrowthrateoflong-termstrength,etc[6,7].SoitismorereasonabletouseMHCinapplicationofmassconcrete.
Low-heatportlandcement(LHC),namelyhighbelitecementiscurrentlyattractingagreatdealofinterestworldwide.ThisislargelyduetoitslowerenergyconsumptionandCO2emissioninmanufacturethanconventionalPortlandcements.LHChasalotofnoticeableproperties,suchaslowheatofhydrationexcellentdurability,etc,sothefurtherstudycontinuestobeimportant[8-10].Thelong-termstrengthofC2ScanapproachtoorevenexceedthatofC3S[11].Inaddition,C2ShasaseriesofcharacteristicssuperiortoC3S.TheseincludethelowcontentofCaO,lowhydrationheat,goodtoughness,compacthydrationproducts,excellentresistancestochemicalcorrosion,littledryshrinkage,etc[12,13].
Forhydroelectricconcrete,thedesignrequirementshavesomecharacteristics,suchaslongdesignage,lowdesignstrength,lowhydrationtemperaturerise,andlowtemperaturegradient[14].AlltheserequirementsagreewiththecharacteristicsofLHC.Furthermore,LHChasahighhydrationactivityatlaterages,theeffectofwhichcanimprovetheinnermicro-crack.Basedonabove-mentionedanalyses,thepropertiesoflow-heatPortlandcementconcretewerestudiedindetailinthispaper.Comparedwiththemoderate-heatPortlandcement(MHC)concrete,theanti-crackbehaviorofLHCconcretewasanalyzed.
2Experimental
MHCwasproducedinGezhoubaHoldingCompanyCementPlant,China;
andLHCwasproducedinHunanShimenSpecialCementCo.Ltd.,China.ThechemicalcompositionsandmineralcompositionsofcementarelistedinTable1andTable2respectively,andthephysicalandmechanicalpropertiesofcementarelistedinTable3.
Inspiteofalittledifferenceinchemicalcompositions,thereisanobviousdissimilaritybetweenthemineralcomponentofLHCandthatofMHCbecauseofthedifferentburningschedule.TheC3S(Alite)contentofMHCishigherthanthatofLHC,andtheC2S(Belite)contentofLHCishigherthanthatofMHC.Aliteisformedattemperaturesofabout1450℃,whileBeliteisformedataround1200℃.Therefore,LHCcanbemanufacturedatlowerkilntemperaturesthanMHC.AndtheamountofenergytheoreticallyrequiredtomanufactureLHCislowerthanthatofMHC.
Belitehydratescomparativelyslowly,andtheearlycompressivestrengthsofpastes,mortars,andconcretescontainingLHCaregenerallylowerasaresult.Thelong-termstrengthanddurabilityofconcretemadefromLHCcanpotentiallyexceedthoseofMHC.TheresultsfromTable3showthattheearlystrengthofLHCpastesislowerthanthatofMHCpastes,andthatthestrengthgrowthrateofLHCishigherthanthatofMHC.
Thehydrationheatofbondingmaterialswastested.ClassIflyashofbondingmaterialscamefromShandongZhouxianPowerPlant,China.TheexperimentalresultsshowninTable4indicatethatthehydrationheatofLHCismuchlowerthanthatofMHC.The1-day,3-dayand7-dayhydrationheatofLHCwithoutflyashis143kJ/kg,205kJ/kg,227kJ/kg,respectively.The1-day,3-dayand7-dayhydrationheatofMHCwithoutflyashis179kJ/kg,239kJ/kg,278kJ/kg,respectively.ComparedwithMHC,theaveragehydrationheatofLHCconcreteisreducedbyabout17.5%.Obviously,lowhydrationisofadvantagetoabatethepressuretotemperaturecontrol,andtoreducethecrackprobabilityduetothetemperaturegradients.TheadiabatictemperatureofLHCconcreteandMHCconcretewastested.Asaresult,theadiabatictemperatureriseofLHCconcreteislowerthanthatofMHCconcreteandthedifferentvaluerangesfrom2℃to3℃ingeneral.
Afteraddingflyash,allspecimensshowalowerhydrationheat,anditdecreaseswithincreasingflyashcontent.ForMHCwith30%flyash,the1d,3d,7daccumulativehydrationheatisreducedby14.5%,20.5%,21.9%,respectively;
andforLHCwith30%flyash,the1d,3d,7daccumulativehydrationheatisreducedby21.7%,26.3%,23.3%,respectively.Obviously,theeffectofflyashonthehydrationheatofLHCismorethanthatofMHC.ItiswellknownthattheflyashactivationcouldbeactivatedbyCa(OH)2.LHChasalowercontentofC3SandahighercontentofC2SthanMHC,sotheCa(OH)2,namelytheexcitercontentinhydrationproductsofLHCpastesislower.Decreasingthehydrationactivationofflyashreducesthehydrationheatofbondingmaterials.
3ResultsandDiscussion
Inthisexperiment,ZB-1AtyperetardingsuperplasticizerandDH9air-entrainingagentwereused.ThedosageofZB-1was0.7%bytheweightoftheblending,andthedosageofDH9wasadjustedtogiveanair-containingof4.5%to6.0%.Theparametersthataffectedthedosageincludedthecompositionandthefinenessofthecementused,andwhethertheflyashwasused.Fourgradationsofaggregatewereused,120mm-80mm:
80mm-40mm:
40mm-20mm:
20mm-5mm=30:
30:
20:
20.
Thetermwater-to-cementitiouswasusedinsteadofwater-to-cement,andthewater-to-cementitiousratiowasmaintainedat0.50foralltheblending.Theslumpofconcretewasmaintainedatabout40mm,andtheaircontentwasmaintainedatabout5.0%intheexperimental.Afterbeingdemoulded,allthespecimenswereinastandardcuringchamber.ThemixproportionparameterofconcreteislistedinTable5.
3.1Physicalandmechanicalproperties
Thephysicalandmechanicalpropertiesincludestrength,elasticmodulus,limitstension,andsoon.TheresultsofstrengthshowninTable6indicatetheearlystrength(7dcuringages)ofLHC(oddsamples)concreteincreasesslowly.Theratiobetween7dcompressivestrengthand28dcompressivestrengthofLHCconcreteisabout0.4,whileforMHCconcretetheratioisabout0.6.ComparedwithMHCconcrete,thegrowthrateofstrengthofLHCconcretebecomesfasterafter7dcuringages.Thecompressivestrengthfor28d,90d,180dcuringagesofLHCconcretecontaining20%offlyashis30.2MPa,43.8MPa,48.5MPa,respectively,whilethatofMHCconcretecontaining20%offlyashis28.3MPa,35.6MPa,39.8MPa,respectively.ThecontentofC2SinLHCishigherthanthatinMHC,whichresultsintheabove-mentioneddifference.
Table6showsthatthestrengthgrowthrateofconcretemadewithflyashblendedcementsishigherthanthatofblankspecimens;
themorethedosageofflyash,thehigherthegrowthrate.Flyashhasaglassynature,whichcanreactwithCa(OH)2.SinceCa(OH)2isahydrationproductofcement,thereactionbetweenflyashandCa(OH)2,called“secondaryhydration”,willhappenatlatishages.ThemagnitudeofCa(OH)2isaffectedbysomefactors,suchasthewater-to-cementitious,thedosageofcement.
TheelasticmodulusandthelimitstensionofconcretearegiveninTable7.Undersamemixingproportion,theelasticmodulusofLHCconcreteisapproximatelyequaltothatofMHC;
the28-daylimitstensionofLHCconcreteisincreasedby10×
10-6to15×
10-6thanthatofMHC,andthe90-daylimitstensionofLHCconcreteisincreasedby12×
10-6thanthatofMHCconcrete.TheaboveresultsshowthattheuseofLHCimprovesthelimitstensionofconcrete.Increasingthelimitstensionofconcretewillbebenefittothecrackresistanceofconcrete.
3.2Deformationcharacteristics
Deformationcharacteristicsofconcreteincludedryingshrinkage,autogenousdeformation,creep,etc.ThedryingshrinkageofconcreteisshowninFig.1.Thedryingshrinkageincreaseswithage.Atearlyagesaupto90days,alltheLHCconcretespecimensshowalowerdryingshrinkage;
anditdecreaseswithincreasingtheflyashcontent.Whencontaining30%offlyash,thedryingshrinkageofLHCconcreteis363×
10-6at90days,whileforMHCconcretethevalueis408×
10-6.Asaresult,thevolumestabilityofLHCconcreteisbetterthanthatofMHCconcreteindryingenvironment.
ExperimentresultsofautogenousdeformationofconcretearegiveninFig.2.ThereisanobviousdifferencebetweenthedevelopmentofautogenousdeformationofLHCconcreteandthatofMHCconcrete.TheautogenousdeformationofLHCconcretehasanexpansivetendency.Atearlyagesup