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Thiosulfateleachingofgoldfromwastemobilephones
JournalofHazardousMaterials,Volume178,Issues1-3,15June2010,Pages1115-1119
VinhHungHa,Jae-chunLee,JinkiJeong,HuynhTrungHai,ManisK.Jha
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Abstract
Thepresentcommunicationdealswiththeleachingofgoldfromtheprintedcircuitboards(PCBs)ofwastemobilephonesusinganeffectiveandlesshazardoussystem,i.e.,acopper–ammonia–thiosulfatesolution,asanalternativetotheconventionalandtoxiccyanideleachingofgold.Theinfluenceofthiosulfate,ammoniaandcoppersulfateconcentrationsontheleachingofgoldfromPCBsofwastemobilephoneswasinvestigated.Goldextractionwasfoundtobeenhancedwithsolutionscontaining15–20
mMcupric,0.1–0.14
Mthiosulfate,and0.2–0.3
Mammonia.SimilartrendswereobtainedfortheleachingofgoldfromtwodifferenttypesofscrapsandPCBsofwastemobilephones.Fromthescrapsamples,98%ofthegoldwasleachedoutusingasolutioncontaining20
mMcopper,0.12
Mthiosulfateand0.2
Mammonia.Similarly,theleachingofgoldfromthePCBssampleswasalsofoundtobegood,butitwaslowerthanthatofscrapsamplesinsimilarexperimentalconditions.Inthiscase,only90%ofthegoldwasleached,evenwithacontacttimeof10
h.Theobtaineddatawillbeusefulforthedevelopmentofprocessesfortherecyclingofgoldfromwastemobilephones.
ArticleOutline
1.Introduction
2.Experimental
2.1.Materialsandreagents
2.2.Leachingtests
2.3.Analyticalmethods
3.Resultsanddiscussion
3.1.Leachingofgoldbythiosulfate
3.2.Effectofthiosulfateconcentration
3.3.Effectofcopper(II)concentration
3.4.Effectofammoniaconcentration
3.5.Effectofleachingtime
4.Conclusions
Acknowledgements
References
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ModellingandsimulationofRayleighfading,pathloss,andshadowingfadingforwirelessmobilenetworks
SimulationModellingPracticeandTheory,Volume19,Issue2,February2011,Pages626-637
ZhiRen,GuangyuWang,QianbinChen,HongbinLi
Inthispaper,wefirstderivetwoexplicitmathematicalexpressionsofbiterrorrates(BERs)withRayleighfadingfordifferentialphaseshiftkeying(DPSK)andquadratureamplitudemodulation(QAM),andestablishcorrespondingsimulationmodelstorealizetheeffectofRayleighfading.Next,weproposeamathematicalexpressiontodefinetheeffectofshadowingfadingandanapproachtocomputingit.Then,weoptimizetheeffectofpathlossthroughadaptingthevalueofthepathlossexponenttodifferentenvironments.Finally,usingapacket-orientedsimulationtool,OPtimizedNetworkEngineeringTool(OPNET),werealizetheeffectsofRayleighfadingandshadowingfading,optimizetheeffectofpathloss,andinvestigatetheintegratedimpactoftheseeffectsontheperformanceofwirelessmobilenetworksincludingwirelesslocalareanetworks(WLANs)andmobileadhocnetworks(MANETs).Simulationresultsnotonlycoincidewiththeexperimentalresultsinpresentliterature,butalsoshowthattheseeffectsexertanon-negligibleimpactontheperformanceofwirelessmobilenetworks.Accordingly,ournewmodelsandapproachesmakethepresentover-optimisticsimulationresultsmoreaccurateandreasonable.
2.Theoreticalanalysisandmathematicalderivation
2.1.DerivationofBERwithRayleighfading
2.1.1.DPSK
2.1.2.QAM64
2.2.Definitionandcomputationoftheeffectofshadowingfading
2.2.1.Definitionoftheeffectofshadowingfading
2.2.2.Computationoftheeffectofshadowingfading
3.Simulationmodellingandoptimization
3.1.SimulationmodellingofRayleighfading
3.2.Optimizationoftheeffectofpathloss
4.Performanceresultsandevaluation
4.1.RealizationofRayleighfadinginsimulation
4.2.Realizationofshadowingfadinginsimulation
4.3.Optimizationoftheeffectofpathlossinsimulation
4.4.PerformanceevaluationofwirelessmobilenetworkswithRayleighfading,pathloss,andshadowingfading
4.4.1.IntegratedeffectofRayleighfading,pathloss,andshadowingfading
4.4.2.SimulationandanalysisofIEEE802.11WLANs
4.4.3.SimulationandanalysisofMANETs
5.