锅炉水循环和水处理外文翻译.docx
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锅炉水循环和水处理外文翻译
专业外文资料翻译
一.英文资料
BoilerCirculation&WaterTreatment
Anadequateflowofwaterandwater-steammixtureisnecessaryforsteamgenerationandcontroloftubemetaltemperaturesinallthecircuitsofasteam-generatingunit.Atsupercriticalpressures,thisflowisproducedmechanicallybymeansofpumps.Atsubcriticalpressures,circulationisproducedeithernaturallybytheactionoftheforceofgravity,bypumps,orbyacombinationofthetwo.
Fig-1Simplenatural-circulationcircuit(diagrammatic)
includingprimarysteamseparatorindrum
Theforceofgravityavailabletoproduceflowinnaturalcirculationcomesfromthedifferencebetweenthedensities(1b/cuft)ofthefluidsinthedowncomer(downflow)andriser(upflow)portionsofthecircuit(Fig-1).Maximumpumpingeffectoccursifthefluidinthedowncomersiswateratorslightlybelowsaturationtemperatureandfreeofsteambubbles.Heat-absorbingrisesatsaturationtemperatureconveytotheboilerdrumawater-steammixtureoflessdensitythanthatofthewaterinthedowncomers.Thisdifferenceindensityestablishestheforceavailableforcirculation.
Theflowinthevariouscircuitsofboilerunitsdesignedforforcedcirculationatsubcriticalpressures,isproducedbymechanicalpumps.Therearetwogeneraltypesofforced-circulationsystems,a“once-through”systemanda“recirculating”system.
The“once-through”force-circulationtypereceiveswaterfromthefeedsupply,pumpingittotheinletoftheheat-absorbingcircuits.Fluidheatingandsteamgenerationtakeplacealongthelengthofthecircuituntilevaporationiscomplete.Furtherprogressthroughtheheatedcircuitsresultsinsuperheatingthevapor.Conventionallythistypeofforcecirculationrequiresnosteam-and-waterdrum.Amodificationofthe“once-through”typeevaporatestopartialdryness(90%quality)removeingtheexcesswaterinaseparator.
The“recirculation”forced-circulation-typeunithaswatersuppliedtotheheat-absorbingcircuitsthroughaseparatecirculatingpump.Thewaterpumpedisconsiderablyinexcessofthesteamproducedand,likeanatural-circulationboiler,asteam-and-waterdrumisrequiredforsteamseparation.Theseparatedwatertogetherwithfeedwaterfromthefeedpumpisreturnedthroughdowncomercircuitstothecirculatingpumpforanother“roundtrip.”
Intherecirculatingtypeofforcedcirculationthereisanetthermallossfortheboilunitbecauseoftheseparatecirculatingpump.Whilepracticallyalltheenergyrequiredtodrivethepumpsreappearsinthewaterasaddedenthalpy,thisenergyoriginallycamefromthefuelataconversion-to-useful-energyfactoroflessthan1.0.Ifanelectricmotordriveisused,thenetenergylost,referredtothefuelinputinaplantwith33%thermalefficiency,isabouttwicetheenergysuppliedtothepumpmotor.
Naturalcirculation
Inanatural-circulationsystem,circulationincreaseswithincreasedheatinput(andincreasedsteamoutput)untilapointofmaximumfluidflowisreached.Beyondthispoint,anyfurtherincreaseinheatabsorptionresultsinaflowdecrease.Thefromofthecurve,showninFig-2,isproducedbytwoopposingforces,Anincreaseindowncomersandrisersastheheatabsorptionincreases.Atthesametime,thefrictionandotherflowlossesinbothdowncomersandrisersalsoincrease.Whentherateofincreaseintheselosses(causedprimarilybytheincreaseinspecificvolumeintherisercircuits)becomesgreaterthanthegainfromincreasingdensitydifference,istodesignallthecircuitstooperateintheregionoftherisingpartofthecurve,totheleftofthepeakinFig-2.
Whendesignconditionsarelimitedtotherisingportionofthecirculationcurve,anatural-circulationboilertendstobeself-compensatingforthenumerousvariationsinheat-absorptionconditionsencounteredinanoperatingunit.Theseincludesuddenoverloads,changeinheat-absorbing-surfacecleanliness,nonuniformfuelbedorburnerconditions,andeventheinabilitytoforecastpreciselyactualconditionsovertheoperatinglifetime.
Fig-2typicalrelationshipbetweencirculationinaboilercircuit(atagivenpressure)andamountofsteamsteamproduced(scalearbitraiy)
Nosimilarcompensatingeffectisinherentinaforced-circulationunitoperatingatsubcriticalpressures,sincealargepartofthetotalresistanceoftherisercircuits,muchgreaterthanthenaturalcirculationeffect,iscausedbyflow-distributiondevicesrequiredatthecircuitinlets.Undertheseconditions,becauseofthedisproportionatelylargeresistanceofthedistributors,anincreaseinheatabsorptiontoanindividualcircuitorgroupofcircuitscausesonlyaslightchangeintheflowrate.
Themethodofproducingflowinboilercircuits,whethernaturalormechanical,hasvirtuallynobearingontheeffectivenessofheat-absorbingsurfacesaslongastheinsidesurfaceiswerredatalltimesbythewaterinawater-steammixtureofsuitablequalitytomaintainnucleateboiling.Providedthisfundamentalrequirementismet,thewater-filmresistancetoheatflowisnegligiblysmall,andtheoverallheatconductancedependsongas-sideandtube-wallresistances.Withinthenucleateboilingregime,boilerheat-absorbingsurfaceinthefurnaceorconvectionportionoftheunitabsorbsabsorbssubstantiallythesameamountofheatpersqftregardlessofwhetherthecirculatingflowisproducedbynaturalmethodsorbypumps.
Witheithertypeofcirculation,anydeparturefromthenucleateboilingregimerequiresspecialconsiderationoftheforced-convectionstearn-filmheattransfercoefficientanditsrelationtopermissiblemetaltemperatures.
Forcedornaturalcirculation
Undercertainconditionsforcedcirculationcanbeusefullyappliedtosteamgeneration.Mechanicalmeanstomovethefluidwithinthecircuitsareemployedforboilersdesignedtooperateaboveornearthecriticalpressure(3208.2psia.)Thereareinstances,also,intheprocessandwaste-heatfieldswheretemperaturecontrolorconsolidatingheatpickupfromwidelyseparatedpointscanbeeconomicallyeffectedbytheuseofpumps.Theconditionwhereforcedcirculationcanbeappliedtoadvantagearequitespecific.
Naturalcirculationismosteffectivelyemplovedwhenlargechangesindensityusuallyrestrictedtosubcriticalpressuredesignswherethereisaconsiderabledifferenceindensitybetweensteamandwater.Atpressuresabove2900psianatural-circulationsystembecomesincreasinglylargeandcostly,andapumpmaybemoreeconomicaltoassurepositiveflow.
Theforced-circulationprinciple,however,isequallyoperableinboththesupercriticalandsubcriticalpressureranges.Theselectionoftheidentifyingname“Universal-Pressure”boilerreflectsthebroadapplicabilityoftheonce-throughforced-circulationprinciple.Itschoice,asopposedtotheretentionofnaturalcirculationinthesubcriticalrange,isessentiallydeterminedbytheeconomicsoftheinstallation.
Fig-3Densitiesofsteamandwateratsaturatedsteamtemperature
forpressuresfromatmospherictocritical
Thedifferentialindensitiesofsteamandwaterfortherangeof14.7to3208.2psiaisnotedinFig-3.Asubstantialdifferentialpersistswelluptowardthecriticalpressure.Aslongasthemaximumeffectivenessoffthisdifferentialismaintainedbytheefficientseparationofthesteamfromthewaterinthecircnlatingsystem,aswiththeuseofcyclonesteamseparator,mechanicalaidtocirculationisnotessential.
InternalTreatmentofWater
Therearenumerouschemicals,somecalledboilercompounds,onthemarketandrecommendedfor“internal”watersofteningandothertreatment.Theirdutyistostabilizehardnessagents,preventscalingorresidualmakedepositseasilyremovable.Suchchemicalsarealsousedforneutralizationofresidualhardnessinsystemsafterexternaltreatment.Chemicalsofthisnatureareintroducedatamoreorlessconstentrateindissolvedstateintofeedtanksorsystems.Themostfrequentlyusedchemicalswithcalciumandmagnesiumsaltsresultsinconsolablecalciumandmagnesiumphosphates.Otherinternaltreatmentagentsarecalciumhydroxide,sodiumcarbonate,sodiumhyates,tanninsandamines.
Themosteffectivemethodofintroducinginternaltreatmentcompoundstoensureareasonabledegreeofquantitycontrolisbymeansofdosageapparatusconsistingofoneormorecontainershavingmanualormotordrivenagitatorsandadosagepump.
Asageneralruleinternaltreatmentalone,forwatersofmuchmorethan5°(UK)(70p.p.m)hardnessisnotrecommendedbecausesystemandmake-upquantitiesandwatercompositionmaybecomecriticalandprecipitatedsludgeandsaltsareliabletoincreasedensityofwaterandsolidificationofsludgewithconsequentpropensitytofoamingandpriminginsteamplantandcirculationcomplications.
Internaltreatmentisgenerallyusedwithinlimitsforsmallishsystems,sayupto23MWorasresidualtreatmentandtoraisepHvaluetoarequisiteamount.
ExternalTreatmentofWater
Externalsofteningofsystemandmake-upwateristhemoreeffectiveandcomprehensivemethodofwatertreatmentforanysizeofplantandnetworkanditcansuitmostwatercharacteristics.Nowadaysexternaltreatmentinvolvestheprincipleofion-exchange,whichensureswaterofvirtuallyzerohardness.
Theion-exchangeprocesscanbedescribedasfollows.Moleculesofdissolvedsaltsaredissociatedinfromoffreeelectricallychargedionsinliquidsolution.Intheforchfieldtheytendtobeattractedtooppositecharges:
positivecationstothenegativecathodesandnegativeanionstothepositiveanode.Ion-exchangematerialsareinsolubleartificialresinstowhichactivatedchemicalgroupswithtieddissociabl