MEA英文MSDS汇总.docx

1、MEA英文MSDS汇总Material Safety Data Sheet (MSDS)1. PRODUCT AND COMPANY IDENTIFICATIONProduct name : MonoethanolamineProduct Number : MEASupplier : LOTTE CHEMICAL.LotteTower Bldg., 395-67 Shindaebang dong, Dongjak-Seoul KOREA (Zipcode : 156-012)TEL : 82-2-829-4114FAX : 82-2-843-10102. HAZARDS IDENTIFICAT

2、IONEmergency OverviewOSHA HazardsNo known OSHA hazardsGHS ClassificationSkin irritation (Category 3)GHS Label elements, including precautionary statementsPictogramSignal word DangerHazard statement(s)H302+H312+H332 Harmful if swallowed, in contact with skin or if inhaled.H314 Causes severe skin burn

3、s and eye damage.H412 Harmful to aquatic life with long lasting effects.Precautionarystatement(s) P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/eye protection/ face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remov

4、econtact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician.Supplemental Hazard none Statements Other hazard This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic(PBT), or very persiste

5、nt and very bioaccumulative(vPvB) at levels of 0.1% or higher.3. COMPOSITION/INFORMATION ON INGREDIENTSSynonyms : Monoethanolamine 2-Aminoethyl alcohol 2-AminoethanolFormula :C2H7NOCAS-No.EC-No.Index-No.Concentration141-43-5205-483-3603-030-00-84. FIRST AID MEASURESGeneral adviceConsult a physician.

6、 Show this safety data sheet to the doctor in attendance.If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactFlush eyes with w

7、ater as a precaution.If swallowedNever give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.5. FIRE-FIGHTING MEASURESSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Special hazards arising from the substance

8、or mixtureCarbon oxides, Nitrogen oxides (NOx)Advice for firefightersWear self-contained breathing apparatus for firefighting if necessary.Further informationUse water spray to cool unopened containers.6. ACCIDENTAL RELEASE MEASURESPersonal precautionsUse personal protective equipment. Avoid dust fo

9、rmation. Avoid breathing vapors, mist or gas. Ensure adequateventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating toform explosive concentrations. Vapours can accumulate in low areas.Environmental precautionsPrevent further leakage or spillage

10、 if safe to do so. Do not let product enter drains. Discharge into theenvironment must be avoided.Methods and materials for containment and cleaning upContain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing andplace in container for disposal according to l

11、ocal regulations. Keep in suitable, closedcontainers for disposal.7. HANDLING AND STORAGEPrecautions for safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapour or mist.Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostaticcharge.Cond

12、itions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters Componen

13、ts with workplace control parametersExposure controls Appropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks andat the end of workday.Personal protective equipmentEye/face protectionTightly fitting safety goggles. Faceshield (8

14、-inch minimum). Use equipment for eye protectiontested and approved under appropriate government standards such as NIOSH (US) or EN166(EU).Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching gloves outer surface) to avoid skin

15、 contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC andthe standard EN 374 derived from it.Full contactMate

16、rial: Nature latex/chloropreneMinimum layer thickness: 0,6 mmBreak through time: 480 minMaterial tested:Lapren (KCL 706 / Aldrich Z677558, Size M)Splash contactMaterial: Nitrile rubberMinimum layer thickness: 0,2 mmBreak through time: 30 minMaterial tested:Dermatril P (KCL 743 / Aldrich Z677388, Siz

17、e M)data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail saleskcl.de,test method: EN374If used in solution, or mixed with other substances, and under conditions which differ from EN 374,contact the supplier of the CE approved gloves. This recommendation is advisory only and mus

18、tbe evaluated by an industrial hygienist and safety officer familiar with the specific situation ofanticipated use by our customers. It should not be construed as offering an approval for anyspecific use scenario.Body ProtectionComplete suit protecting against chemicals, The type of protective equip

19、ment must be selectedaccording to the concentration and amount of the dangerous substance at the specific workplace.Respiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face respiratorwith multi-purpose combination (US) or type ABEK (EN 14387) respir

20、ator cartridges as a backupto engineering controls. If the respirator is the sole means of protection, use a full-face supplied airrespirator. Use respirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).Control of environmental exposurePrev

21、ent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge intothe environment must be avoided.9. PHYSICAL AND CHEMICAL PROPERTIESAppearanceForm Liquidat 25ColourColourlessSafety datapHNo data availableMeltingpoint/freezing point 10 - 11 C - lit.Boiling point 171 C

22、- lit.Flash point 96 C closed upIgnition temperature No data availableAuto-ignitiontemperature No data availableLower explosion limit No data availableUpper explosion limit No data availableVapour pressure No data availableMolecular weight 61.08Water solubility No data availablePartition coefficient

23、:n-octanol/waterNo data availableRelative vapourdensityNo data availableOdour No data availableOdour Threshold No data availableEvaporation rate No data available10. STABILITY AND REACTIVITY ReactivityNo data availableChemical stabilityAbsorbs carbon dioxide (CO2) from air.Stable under recommended s

24、torage conditions.Possibility of hazardous reactionsNo data availableConditions to avoidExposure to moisture.Heat, flames and sparks.Materials to avoidStrong acids and oxidizing agents, Iron, Copper, Brass, RubberHazardous decomposition productsOther decomposition products - No data available11. TOX

25、ICOLOGICAL INFORMATIONAcute toxicityLD50 Oral - Rat - 1.720 mg/kgInhalation:Material is extremely destructive to the tissue of the mucous membranes and upper respiratoryLD50 Dermal - Rabbit - 1.015 mg/kgSkin corrosion/irritationNo data availableSerious eye damage/eye irritationEyes - RabbitResult: S

26、evere eye irritationRespiratory or skin sensitizationNo data availableGerm cell mutagenicityNo data availableCarcinogenicityIARC: No component of this product present at levels greater than or equal to 0.1% is identified asprobable, possible or confirmed human carcinogen by IARC.12. ECOLOGICAL INFOR

27、MATIONToxicityToxicity to fish LC50 - Pimephalespromelas (fathead minnow) - 227 mg/l - 96 hToxicity to daphnia and EC50 - Daphnia magna (Water flea) - 65 mg/l - 48 hother aquatic invertebratesToxicity to algae EC50 - Desmodesmussubspicatus(green algae) -15 mg/l -72 hPersistence and degradabilityNo d

28、ata availableBioaccumulative potentialNo data availableMobility in soilno data availablePBT and vPvB assessmentThis substance/mixture contains no components considered to be either persistent, bioaccumulative andtoxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or hig

29、her.Other adverse effectsHarmful to aquatic life with long lasting effects.13. DISPOSAL CONSIDERATIONSProductThis combustible material may be burned in a chemical incinerator equipped with an afterburner andscrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.Contamina

30、ted packagingDispose of as unused product.14. TRANSPORT INFORMATIONUN numberARD/RID: 2491 IMDG: 2491 IATA: 2491UN proper shipping nameARD/RID: ETHANOLAMINE IMDG: ETHANOLAMINE IATA: Ethanolamine Transport hazard classADR/RID: 8 IMDG: 8 IATA: 8Packing groupADR/RID: III IMDG: III IATA: IIIEnvironmental

31、 hazardADR/RID: no IMDG Marine pollutant: no IATA: noExport HS-code2922110001 (China)OthersFollow all regulations in your country.15. REGULATORY INFORMATIONThis safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.Safety, health and environmental regulations/legislation specific for the substance or mixtureNo data availableChemical Safety AssessmentFor this product a chemical safety assessment was not carried out16. OTHER INF