MEA英文MSDS汇总.docx

MEA英文MSDS汇总.docx

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MEA英文MSDS汇总

MaterialSafetyDataSheet（MSDS）

1.PRODUCTANDCOMPANYIDENTIFICATION

Productname:

Monoethanolamine

ProductNumber:

MEA

Supplier:

LOTTECHEMICAL.

LotteTowerBldg.,395-67Shindaebangdong,Dongjak-SeoulKOREA

（Zipcode:

156-012）

TEL:

82-2-829-4114

FAX:

82-2-843-1010

2.HAZARDSIDENTIFICATION

EmergencyOverview

OSHAHazardsNoknownOSHAhazards

GHSClassification

Skinirritation（Category3）

GHSLabelelements,includingprecautionarystatements

Pictogram

SignalwordDanger

Hazardstatement（s）

H302+H312+H332Harmfulifswallowed,incontactwithskinorifinhaled.

H314Causessevereskinburnsandeyedamage.

H412Harmfultoaquaticlifewithlonglastingeffects.

Precautionarystatement（s）

P273Avoidreleasetotheenvironment.

P280Wearprotectivegloves/protectiveclothing/eyeprotection/face

protection.

P305+P351+P338IFINEYES:

Rinsecautiouslywithwaterforseveralminutes.Remove

contactlenses,ifpresentandeasytodo.Continuerinsing.

P310ImmediatelycallaPOISONCENTERordoctor/physician.

SupplementalHazardnone

Statements

Otherhazard

Thissubstance/mixturecontainsnocomponentsconsideredtobeeitherpersistent,

bioaccumulativeandtoxic（PBT）,orverypersistentandverybioaccumulative（vPvB）atlevelsof0.1%orhigher.

3.COMPOSITION/INFORMATIONONINGREDIENTS

Synonyms:

Monoethanolamine

2-Aminoethylalcohol

2-Aminoethanol

Formula:

C2H7NO

CAS-No.

EC-No.

Index-No.

Concentration

141-43-5

205-483-3

603-030-00-8

4.FIRSTAIDMEASURES

Generaladvice

Consultaphysician.Showthissafetydatasheettothedoctorinattendance.

Ifinhaled

Ifbreathedin,movepersonintofreshair.Ifnotbreathing,giveartificialrespiration.Consultaphysician.

Incaseofskincontact

Washoffwithsoapandplentyofwater.Consultaphysician.

Incaseofeyecontact

Flusheyeswithwaterasaprecaution.

Ifswallowed

Nevergiveanythingbymouthtoanunconsciousperson.Rinsemouthwithwater.Consultaphysician.

5.FIRE-FIGHTINGMEASURES

Suitableextinguishingmedia

Usewaterspray,alcohol-resistantfoam,drychemicalorcarbondioxide.

Specialhazardsarisingfromthesubstanceormixture

Carbonoxides,Nitrogenoxides（NOx）

Adviceforfirefighters

Wearself-containedbreathingapparatusforfirefightingifnecessary.

Furtherinformation

Usewaterspraytocoolunopenedcontainers.

6.ACCIDENTALRELEASEMEASURES

Personalprecautions

Usepersonalprotectiveequipment.Avoiddustformation.Avoidbreathingvapors,mistorgas.

Ensureadequateventilation.Removeallsourcesofignition.Evacuatepersonneltosafeareas.

Bewareofvapoursaccumulatingtoformexplosiveconcentrations.Vapourscanaccumulateinlow

areas.

Environmentalprecautions

Preventfurtherleakageorspillageifsafetodoso.Donotletproductenterdrains.Dischargeintothe

environmentmustbeavoided.

Methodsandmaterialsforcontainmentandcleaningup

Containspillage,andthencollectwithanelectricallyprotectedvacuumcleanerorbywet-brushingand

placeincontainerfordisposalaccordingtolocalregulations.Keepinsuitable,closed

containersfordisposal.

7.HANDLINGANDSTORAGE

Precautionsforsafehandling

Avoidcontactwithskinandeyes.Avoidinhalationofvapourormist.

Keepawayfromsourcesofignition-Nosmoking.Takemeasurestopreventthebuildupof

electrostaticcharge.

Conditionsforsafestorage,includinganyincompatibilities

Storeincoolplace.Keepcontainertightlyclosedinadryandwell-ventilatedplace.Containerswhich

areopenedmustbecarefullyresealedandkeptuprighttopreventleakage.

8.EXPOSURECONTROLS/PERSONALPROTECTION

Controlparameters

Componentswithworkplacecontrolparameters

Exposurecontrols

Appropriateengineeringcontrols

Handleinaccordancewithgoodindustrialhygieneandsafetypractice.Washhandsbeforebreaksand

attheendofworkday.

Personalprotectiveequipment

Eye/faceprotection

Tightlyfittingsafetygoggles.Faceshield（8-inchminimum）.Useequipmentforeyeprotection

testedandapprovedunderappropriategovernmentstandardssuchasNIOSH（US）orEN

166（EU）.

Skinprotection

Handlewithgloves.Glovesmustbeinspectedpriortouse.Usepropergloveremovaltechnique

（withouttouchingglove'soutersurface）toavoidskincontactwiththisproduct.Disposeof

contaminatedglovesafteruseinaccordancewithapplicablelawsandgoodlaboratorypractices.

Washanddryhands.

TheselectedprotectivegloveshavetosatisfythespecificationsofEUDirective89/686/EECand

thestandardEN374derivedfromit.

Fullcontact

Material:

Naturelatex/chloroprene

Minimumlayerthickness:

0,6mm

Breakthroughtime:

480min

Materialtested:

Lapren®（KCL706/AldrichZ677558,SizeM）

Splashcontact

Material:

Nitrilerubber

Minimumlayerthickness:

0,2mm

Breakthroughtime:

30min

Materialtested:

Dermatril®P（KCL743/AldrichZ677388,SizeM）

datasource:

KCLGmbH,D-36124Eichenzell,phone+49（0）665987300,e-mailsales@kcl.de,

testmethod:

EN374

Ifusedinsolution,ormixedwithothersubstances,andunderconditionswhichdifferfromEN374,

contactthesupplieroftheCEapprovedgloves.Thisrecommendationisadvisoryonlyandmust

beevaluatedbyanindustrialhygienistandsafetyofficerfamiliarwiththespecificsituationof

anticipatedusebyourcustomers.Itshouldnotbeconstruedasofferinganapprovalforany

specificusescenario.

BodyProtection

Completesuitprotectingagainstchemicals,Thetypeofprotectiveequipmentmustbeselected

accordingtotheconcentrationandamountofthedangeroussubstanceatthespecificworkplace.

Respiratoryprotection

Whereriskassessmentshowsair-purifyingrespiratorsareappropriateuseafull-facerespirator

withmulti-purposecombination（US）ortypeABEK（EN14387）respiratorcartridgesasabackup

toengineeringcontrols.Iftherespiratoristhesolemeansofprotection,useafull-facesuppliedair

respirator.Userespiratorsandcomponentstestedandapprovedunderappropriategovernment

standardssuchasNIOSH（US）orCEN（EU）.

Controlofenvironmentalexposure

Preventfurtherleakageorspillageifsafetodoso.Donotletproductenterdrains.Dischargeinto

theenvironmentmustbeavoided.

9.PHYSICALANDCHEMICALPROPERTIES

Appearance

FormLiquidat25℃

ColourColourless

Safetydata

pHNodataavailable

Meltingpoint/freezingpoint10-11°C-lit.

Boilingpoint171°C-lit.

Flashpoint96°C–closedup

IgnitiontemperatureNodataavailable

Auto-ignitiontemperatureNodataavailable

LowerexplosionlimitNodataavailable

UpperexplosionlimitNodataavailable

VapourpressureNodataavailable

Molecularweight≒61.08

WatersolubilityNodataavailable

Partitioncoefficient:

n-octanol/waterNodataavailable

RelativevapourdensityNodataavailable

OdourNodataavailable

OdourThresholdNodataavailable

EvaporationrateNodataavailable

10.STABILITYANDREACTIVITY

Reactivity

Nodataavailable

Chemicalstability

Absorbscarbondioxide（CO2）fromair.Stableunderrecommendedstorageconditions.

Possibilityofhazardousreactions

Nodataavailable

Conditionstoavoid

Exposuretomoisture.Heat,flamesandsparks.

Materialstoavoid

Strongacidsandoxidizingagents,Iron,Copper,Brass,Rubber

Hazardousdecompositionproducts

Otherdecompositionproducts-Nodataavailable

11.TOXICOLOGICALINFORMATION

Acutetoxicity

LD50Oral-Rat-1.720mg/kg

Inhalation:

Materialisextremelydestructivetothetissueofthemucousmembranesand

upperrespiratory

LD50Dermal-Rabbit-1.015mg/kg

Skincorrosion/irritation

Nodataavailable

Seriouseyedamage/eyeirritation

Eyes-Rabbit

Result:

Severeeyeirritation

Respiratoryorskinsensitization

Nodataavailable

Germcellmutagenicity

Nodataavailable

Carcinogenicity

IARC:

Nocomponentofthisproductpresentatlevelsgreaterthanorequalto0.1%isidentifiedas

probable,possibleorconfirmedhumancarcinogenbyIARC.

12.ECOLOGICALINFORMATION

Toxicity

ToxicitytofishLC50-Pimephalespromelas（fatheadminnow）-227mg/l-96h

ToxicitytodaphniaandEC50-Daphniamagna（Waterflea）-65mg/l-48h

otheraquaticinvertebrates

ToxicitytoalgaeEC50-Desmodesmussubspicatus（greenalgae）-15mg/l-72h

Persistenceanddegradability

Nodataavailable

Bioaccumulativepotential

Nodataavailable

Mobilityinsoil

nodataavailable

PBTandvPvBassessment

Thissubstance/mixturecontainsnocomponentsconsideredtobeeitherpersistent,

bioaccumulativeandtoxic（PBT）,orverypersistentandverybioaccumulative（vPvB）atlevelsof

0.1%orhigher.

Otheradverseeffects

Harmfultoaquaticlifewithlonglastingeffects.

13.DISPOSALCONSIDERATIONS

Product

Thiscombustiblematerialmaybeburnedinachemicalincineratorequippedwithanafterburner

andscrubber.Offersurplusandnon-recyclablesolutionstoalicenseddisposalcompany.

Contaminatedpackaging

Disposeofasunusedproduct.

14.TRANSPORTINFORMATION

UNnumber

ARD/RID:

2491IMDG:

2491IATA:

2491

UNpropershippingname

ARD/RID:

ETHANOLAMINE

IMDG:

ETHANOLAMINE

IATA:

Ethanolamine

Transporthazardclass

ADR/RID:

8IMDG:

8IATA:

8

Packinggroup

ADR/RID:

IIIIMDG:

IIIIATA:

III

Environmentalhazard

ADR/RID:

noIMDGMarinepollutant:

noIATA:

no

ExportHS-code

2922110001（China）

Others

Followallregulationsinyourcountry.

15.REGULATORYINFORMATION

ThissafetydatasheetcomplieswiththerequirementsofRegulation（EC）No.1907/2006.

Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture

Nodataavailable

ChemicalSafetyAssessment

Forthisproductachemicalsafetyassessmentwasnotcarriedout

16.OTHERINF