中华人民共和国国家标准次氯酸钠发生器Peoples Republic of China.docx
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中华人民共和国国家标准次氯酸钠发生器PeoplesRepublicofChina
中华人民共和国国家标准----次氯酸钠发生器〔People'sRepublicofChinanationalstandard--sodiumhypochloritegenerator〕
People'sRepublicofChinanationalstandard--sodiumhypochloritegenerator
SodiumhypochloritegeneratorGB12176-90
1themecontentandscopeofapplication
Thisstandardspecifiestheproductclassification,technicalrequirements,testmethodsandinspectionrulesofsodiumhypochloritegeneratorforelectrolysisoflowconcentrationsaltwater.
Thisstandardissuitablefordrinkingwaterdisinfection,wastewatertreatment,sanitationandepidemicpreventionandtheuseofsodiumhypochloritegeneratorinindustrialproductiondepartment.
2citationcriteria
GB3859semiconductorpowerconverterGB5461ediblesalt
HygienicstandardofdrinkingwaterforGB5749
GB5750StandardTestMethodfordrinkingwater
JB1043chemicalcorrosionprotectionlowvoltageapparatus
TestmethodforchemicalgascorrosionofJB1045electricalproducts
GeneraltechnicalrequirementsforpackagingofJB2759mechanicalandelectricalproducts
3termsandterms3.1electrolyzerelectrolyticcell
Inthesodiumhypochloritegeneratorforelectrolysisoflowconcentrationsaltwater,theelectrolyticreactionandsolutionreactionarecalledelectrolyticcells.Differentcellstructureandelectrodeshapecanbeadoptedintheelectrolyzeraccordingtodifferentoperationmodesandrequirements.
3.2effectivechlorineconcentration(C)concetrationofavailablechlorine
Theoxidationcapacityofsodiumhypochloritesolutionisquantitativelyexpressedbyeffectivechlorineconcentration.Theoxidationcapacityofeachlitersolutionisequivalenttotheoxidationcapacityofseveralgrammasschlorineinwater.Unitg/L.Theeffectivechlorineconcentrationis2timesoftheconcentrationofthepositivevalencechlorineinthesolution.Thesolutioncontains1gofsodiumhypochloriteandcontainseffectivechlorine0.953g.
3.3effectivechlorineyield(G)productionofavailablechlorine
Theoutputofsodiumhypochloritegeneratorisexpressedbyeffectivechlorineyield,whichisequaltoG(unitg/h)ofeffectivechlorineperhourwhentheequipmentisworkinginratedstate.Theeffectivechlorineyieldwascalculatedaccordingtoformula
(1):
G=CxQ
(1)
Formula:
Q-hourlysodiumhypochloritesolutionflowrate,L/h.
3.4currentefficiency(n)currentefficiency
Theratiooftheactualquantityoftheeffectivechlorinetothetheoreticalamountofproductioniscalledthecurrentefficiencyoftheelectrolyticcellafterflowingthroughacertainamountofelectricityintheelectrolyticcell.AccordingtotheelectrolysislawofFala'sbrother,thetheoreticalyieldofeffectivechlorineis1.323gwhentheelectricquantityof1A/hpassesthroughtheelectrolyzer.Thecurrentefficiencyiscalculatedaccordingtotheformula
(2):
N=G/Ixnx1.323x100%
(2)
Type:
I--electrolyticcurrent,A;
Nseriesseriesofelectrodes;
1.323-Theoreticalgenerationofeffectivechlorineperamperehour,g/(A?
H).
3.5electrolyticvoltage(V)electrolyticvoltage
Whenthesodiumhypochloritegeneratoroperatesinratedstate,thedirectvoltageappliedbetweentheanodeandcathodeoftheelectrolyticcelliscalledelectrolyticvoltage,unit(V).Theelectrolyticvoltageisexpressedbymultiplyingtheelectrolyticvoltageofeachpairofanodeandcathodebetweenthecathodeandanodeinseries.Suchas4V*3.
3.6ratedelectrolyticcurrent(I)nominalelectrolyticcurrent
Inordertomaintainthenominalyieldofsodiumhypochloritegenerator,theelectrolyticcurrentflowingthroughtheelectrolyticcelliscalledratedelectrolyticcurrent,unit(A).Whentheequipmentelectrolyzerispoweredbymanypairsofanodeandcathode,theratedelectrolyticcurrentcanbeexpressedbymultiplyingthecurrentbetweeneachpairofelectrodesandthenumberofparallelpoles,suchas50A*2.
3.7electrolyteconcentration(S)concentrationofelectrolytesolution
Sodiumhypochloritegeneratoradoptslowconcentrationsaltwateraselectrolyte.TheconcentrationofelectrolyteisexpressedingramsperliterofsolutioncontainingNaCI,unitg/L.
3.8DCpowerconsumption(PDC)DCpowerconsumption
Thesodiumhypochloritegeneratoroperatesunderratedcondition,
TheDCenergyconsumedbyeacheffectivechlorinegeneratedintheelectrolyticcelliscalledthedirectcurrentpowerconsumption.Theunitis(kW?
H)/kg,andtheformulaiscalculatedaccordingtotheformula(3).(1kg):
PDC=UxI/G=UxI/QxC(3)
Type:
U--VDC;
I--electrolyticcurrent(ADC);
G--effectivechlorineyield(g/h);
Q-sodiumchloridesolutionyield(L/h);
C--theeffectivechlorineconcentration(g/L)ofsodiumhypochlorite.
3.9alternatingcurrentconsumptionPACACpowerconsumption
Whenthesodiumhypochloritegeneratorworksunderratedcondition,theeffectivechlorineproducedbythewholemachinecanbecalledACpowerconsumption.Theunitis(kW=h)/kg,andtheformulaiscalculatedaccordingtotheformula(4).(1kg):
PAC=P1x1000/G(4)
Type:
P1--theinputactivepowerofthewholemachine,kW.
3.10saltconsumption(Us)saltconsumption
Whenthesodiumhypochloritegeneratoroperatesunderratedcondition,thequalityofNaCIconsumedbyproducing1kgeffectivechlorineiscalleditssaltconsumption,theunitiskg/kg,andtheformulaiscalculatedaccordingtotheformula(5):
Us=S/C(5)
Formula:
S-electrolyteconcentration,g/L;C-effectivechlorineconcentration,g/L;
4,productclassification
4.1classificationprinciple,sodiumhypochloritegeneratoraccordingtotheuse,operationmode,specificationsandqualitylevelclassification.
4.1.1sodiumhypochloritegeneratorisdividedintotwocategories:
sanitarydisinfectionandenvironmentalprotectionaccordingtoitsuse.Sanitarydisinfectioncanbeusedforenvironmentalprotection,andenvironmentalprotectionshallnotbeusedforsanitarydisinfection.Sanitarydisinfectionreferstothesodiumhypochloritegeneratorwhichisdirectlyrelatedtothehealthofhumanbodyfordisinfection,sanitationandtablewaredisinfection,vegetables,fruits,fooddisinfectionandsoon.Environmentalprotectionreferstothesodiumhypochloritegeneratorwhichisnotdirectlyrelatedtohumanhealth,suchasindustrialwastewatertreatment,hospitalsewagetreatmentandotherindustrialsectorsthatusesodiumhypochloritesolution.
Theoperationmodeof4.1.2sodiumhypochloritegeneratorisdividedintotwotypes:
continuousoperationandintermittentoperation.
4.1.3sodiumhypochloritegeneratorspecificationsaccordingtotheeffectivechlorineyieldequipmentisdividedinto5,10,25,50,75,100,150,200,250,300,400,500,750,1000,1500,2000,3000,5000,g/h,morethan5000g/hspecificationsaredeterminedaccordingtotheactualneeds.
4.1.4sodiumhypochloritegeneratorisdividedintohighqualityproducts(A),firstgradeproducts(B)andqualifiedproducts(C)accordingtoqualitygrade.
4.2productlabeling
Theproductmarkof4.2.1sodiumhypochloritegeneratorconsistsof3partsandisarrangedinthefollowingorder:
Productname;technicalcharacteristics;standardnumber.
4.2.2productnameis"sodiumhypochloritegenerator"".
Thetechnicalfeaturesof4.2.3consistoftheuseoftheequipment,themodeofoperation,thespecifications,thelettersandnumbersofthequalitygrade.
ThefirstChinesephoneticalphabetofthefeaturepartof4.2.3.1technologyindicatestheuseoftheequipment.Theletter"W"isusedforsanitarydisinfection,andtheletter"H"isusedforenvironmentalprotection.
ThesecondChinesephoneticalphabetsinthefeaturepartofthe4.2.3.2technologyrepresenttheoperationmodeoftheequipment,codeL-continuouselectrolyticmode,J-batchtypeelectrolyticprotection.
ThethirdArabiafiguresofthe4.2.3.3technologyfeaturerepresentthespecificationsoftheequipment,andthenumericalvalueistheratedoutputoftheequipment.
Thefourthlettersofthe4.2.3.4technologyfeatureindicatethequalityleveloftheproduct.LetterA-qualityproducts,B-gradeA,C-qualifiedproducts.
Thestandardpartofthe4.2.4productlabelindicatesthattheproductconformstothenationalstandardandisexpressedinGB12176.
4.3productlabelingexamples
Forexample:
fordisinfection,continuousoperation,theratedyieldof100%g/h,qualitygradereachedthefirstclassofsodiumhypochloritegenerator,itsproductsmarkedas:
SodiumhypochloritegeneratorWL100BGB12176-90
Four
4thequalitygrademarkusedinproductmarkandthemarkconformingtotherequirementsofthisnationalstandardmustbeapprovedbythestatespecializedagencyordesignatedqualitymonitoringunit.
4.5thespecificmodeloftheproductallowstheproductionplanttodetermineaccordingtotherequirementsofthisstandard.
5technicalrequirements
5.1theuseofenvironmentalconditions:
sodiumhypochloritegeneratorshouldbeabletoworkinthefollowingenvironment.
5.1.1ambienttemperature:
0~40oC.
5.1.2ambienthumidity:
themaximumrelativehumidityinairisnotmorethan90%(equivalenttoair20+5oC).
5.1.3inthequalitygradeforthequalityofsodiumhypochloritegeneratorontheselectionoflowvoltageelectricalappliancesinadditiontomeettheirrespectiveproducttechnicalrequirements,shouldalsocomplywiththeprovisionsofJB1043.
5.2basictechnicalrequirements
5.2.1sodiumhypochloritegeneratorshallbemanufacturedaccordingtothedrawingsandtechnicaldocumentsapprovedbytheprescribedprocedures.
Thespecificationsof5.2.2sodiumhypochloritegeneratorshallcomplywiththerequirementsofthisstandard4.1.3.
5.2.3sodiumhypochloritegeneratoraccordingtot