电化学活性的化合物.docx
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电化学活性的化合物
具有电化学活性的化合物参考表
具有电化学活性的基团
举例
可氧化的化合物举例
下面是一个假想的化合物,说明具有电化学活性的各种官能团。
具有电化学活性的化合物是芳香族化合物,或含有羟基,甲氧基或胺等官能团。
脂肪族化合物,如硫醇(类)和胺类也具有电化学活性。
某些化合物例如:
碳水化合物,需要特殊的检测式,称之为脉冲安培检测法或简称PAD.
1)OXIDATIONONCARBONWORKINGELECTRODE.DCMODE
2)REDUCTIONONCARBONWORKINGELECTRODE.DCMODE
3)OXIDATIONONCARBONWORKINGELECTRODEFOLLOWINGDERIVATIZATION
4)OXIDATIONONMERCURYORMERCURY/GOLDAMALGAM.DCMODE
5)OXIDATIONONGOLDWORKINGELECTRODE.PADMODE
多化合物具有电化学活性,可以用HPLC-ECD(带电化学检测器的高压液相)进行检测。
以下所列的是各种具有电化学活性的化合物,这是基于他们的化学结构或引自科学文献。
所列化合物仅供参考,并非暗示可从ESA公司获得所有这些化合物的分析法。
氨基酸类AMINOACIDS(e.g.brain,plasma,CSF,microdialysis)
UnderivatizedDerivatized
Methionine蛋氨酸,甲硫氨酸withOPA/ßME
Tryptophan色氨酸
Tyrosine酪氨酸alpha-AMINO
BUTYRICACID丁酸
Alanine丙胺酸
Arginine精氨酸
Asparticacid天(门)冬氨酸
Asparagine天冬酰胺酸
ß-alanineß-丙胺酸
ß-aminobutyricacidß-氨基丁酸
(carnosine)肌肽
citrulline瓜氨酸
Cysteine(cystine)半光胺酸
gamma-aminobutyricacid
Glutamicacid-氨基丁酸
Glutamine谷氨酸盐
Glycine氨基乙酸
Histamine组胺
Histidine组胺酸
Isoleucine异亮安酸
Leucine亮氨酸
Lysine赖氨酸
Methionine蛋氨酸,甲硫氨酸
Nitro-arginineNitro-精氨酸
Phenylalanine苯基丙氨酸
Phospho-ethanolamine
Serine丝氨酸
Taurine
Threonine氨酸
Tryptophan色氨酸
Tyrosine酪氨酸
Valine
DerivatizedMiscellaneous
withNBDChlorideDi-peptides(widevarietycontainingtrp,tyrormet)
Hydroxy-proline羟基脯氨酸Homocarnosine
Proline脯氨酸N-acetyl-histidineN-乙酰基组氨酸
1-methylhistidine1-甲基组氨酸
3-methylhistidine3-甲基组氨酸
3-nitrotyrosine3-硝基酪氨酸
3,3,5tri-iodothyronine
Thyroxine甲状腺素
Tri-peptides(widevarietycontainingtrp,tyrormet)
抗氧化剂ANTIOXIDANTS
t-butylhydroquinone4,6-di-t-butyl-3-cresol
t-butyl-4-hydroxy-5-methylphenylsulfide2,6-di-t-butyl-4-ethylphenol
t-butylhydroxyanisole3,5-di-t-butylhydroxyanisole
3-t-butyl-4-hydroxy-5-methylphenylsulfide2,5-di-t-butylhydroquinone
butylhydroxytoluene2,6-di-t-butyl-4-hydroxymethylphenol
2-t-butyl-4-methylphenol2,6-di-t-butyl-4-methylphenol
2-t-butyl-6-methylphenol2,6-di-t-butylphenol
4-t-butyl-2-methylphenol2,4-di-t-butylphenol
2-t-butyl-5-methylphenol3,5-di-t-butylphenol
3-t-butyl-5-methylcatechol2,6-di-s-butylphenol
5-t-butyl-3-methylcatechol4,6-di-t-butylresorcinol
2-s-butylphenol2,2'-methylenebis(6-t-butyl-4-cresol)
4-s-butylphenol4,4'-methylenebis(6-t-butyl-4-cresol)
2-t-butylphenol4,4'-thio-bis(6-t-butyl-2-cresol)
3-t-butylphenol2,4,6-tri-t-butylphenol
4-t-butylphenoldodecylgallate
2,6-di-t-butyl-3-dimethylamino-p-cresolnonylgallate
2,6-di-t-butyl-4-benzoquinoneoctylgallate
2,6-di-butyl-4-n-butylphenolpropylgallate
3,5-di-t-butylcatechol
2,6-di-t-butyl-4-cresol
CHLORINATEDANILINES
2-chloroaniline
3-chloroaniline
4-chloroaniline
2,3-dichloroaniline
2,4-dichloroaniline
2,5-dichloroaniline
2,6-dichloroaniline
3,4-dichloroaniline
3,5-dichloroaniline
2,3,4-trichloroaniline
2,4,5-trichloroaniline
2,4,6-trichloroaniline
2,3,4,5-tetrachloroaniline
2,3,5,6-tetrachloroaniline
Pentachloroaniline
CHLORINATEDNAPHTHOLS
4-chloronaphthol2,4-dichloronaphthol
CHLORINATEDPHENOLS
2-chlorophenol
3-chlorophenol
4-chlorophenol
2,3-dichlorophenol
2,4-dichlorophenol
2,5-dichlorophenol
2,6-dichlorophenol
3,4-dichlorophenol
3,5-dichlorophenol
2,3,4-trichlorophenol
2,3,5-trichlorophenol
2,3,6-trichlorophenol
2,4,5-trichlorophenol
2,4,6-trichlorophenol
3,4,5-trichlorophenol
2,3,4,5-tetrachlorophenol
2,3,4,6-tetrachlorophenol
2,3,5,6-tetrachlorophenol
pentachlorophenol
3,5-dimethylphenol
2,3,6-trimethylphenol
2,3,5-trimethylphenol
2,3,5-trimethylphenol
DNA加合物DNAADDUCTS
3-methylGuanine8-nitroGuanine
7-methylGuanine8-hydroxy-2'-deoxyguanosine
O-6-methylGuanine8-hydroxyguanosine
GNmethylGuanine5-oxocytidine
GRmethylGuanine
药DRUGS(microdialysis,plasmaextracts)
1-Phenylethylamine
10-Hydroxyamitriptyline
10-Hydroxyimipramine
10-Hydroxynortriptyline
11-Hydroxyclomipramine
2-Hydroxydesipramine
2-Hydroxymipramine
2-Phenylethylamine
3-Monoacetylmorphine
4-Hydroxypropranolol
6-Monoacetylmorphine
Acebutolol
Acepromazine
Acetamide乙酰胺
Acetophenazine
Acetorphine
N-Acetylproccainamide(NAPA)
Adiphenine
Ajmaline
Allylprodine
Alphacetylmethadol
Alphameprodine
Alphamethadol
Alphaprodine
Alprenolol
Alverine
Amiloride
Aminopromazine
Amoxicillin
Amthocaine
Amidopyrine
Amiodarone
Amitriptyline
Amotriphene
Anileridine
Antazoline
Apomorphine阿朴吗啡
Atenolol
Atropine阿托品
Azacyuclonal
Bamethane
Benactyzine苯乃静(一种安定药)
Benperidol
Benzethidine
Benzhexol
Benzocaine
Benzoylecgonine
Benzphetamine
Benzquinamide
Benztropine
Benzylmorphine
Benzylpenicillin卞青霉素
Betacetylmethadol
Betahistine
Betameprodine
Betamethadol
Betaprodine
Bezitramide
Bromhexine
Bromodiphenhydramine溴苯海拉明(抗组胺药)
Bromperidol
Brompheniramine
Brompromazine
Brucine
Buclizine
Bufotenine蟾毒色胺
Bephenine
Bupivacaine
Buprenorphine
Butacaine
Butaperazine
Butethamate
Butriptyline
Carbenicillin
Carbinoxamine
Carphenazine
Cephaline
Chlorcyclizine
Chloropyriline
Chloroquine氯喹(治疟疾)
Chlorpheniramine
Chlorphenoxamine
Chlorprenaline
Chlorproethazine
Chlropromazine
Chlroprothixene
Cimetidine
Cinchocaine
Cinchonidine金鸡纳啶
Cinnarizine
Clemastine
Clemizole
Clomipramine
Clonidine
Cocaine古柯碱,可卡因
Codeine可待因(自鸦片中提取的碱质)
Cyclazocine
Cyclizine
Cyclopentamine
Cyclopentolate
Cyproheptadine
Cyrenorphine
Debrisoquine
Deptropine
Desacetylthymoxamine
Desacetylvinblastine
Desalkyldisopyramide
Deserpidine
Desethlamiodarone
Desipramine
Desmthyldesipramine
Desomorphine
Dextromthorphan
Dextromoramide
Dextropropxyphene
Dextrorphan
Diapromide
Dibenzepin
Diethazine
Diethylpropion
Diethylstilbestrol
Dienostrol
Diethylthiambutene
Digydrocodeine
Dihydrocodeinone
Dihydroergotamine
Dihydromorphine
Dimenoxadole
Dimethyindene
Dimethisoquin
Dimethothiazine
Dimethoxanate
Dimethylthiambutene
Dioxaphetylbutyrate
Diphenhydramine
Diphenoxylate
Diphenoxylicacid
Diphenlpyraline
Dipipanone
Diprenorphine
Dipyridamole
Disopyramide
Dopamine多巴胺(一种治脑神经病的药物)
Dothiepin
Dothiepin5-oxide
Doxapram
Doxepin多虑平,凯舒(一种抗抑郁药)
Doxylamine抗敏安
Droperidol
Embramine
Emetine依米丁,吐根碱,吐根素(用作催吐剂等)
Ephedrine麻黄碱,麻黄素
Ergocornine
Ergocristine
Ergocristinine
Ergocryptine
Ergometrine麦角新碱(用于催产和缓解偏头痛)
Ergosine
Ergosinine
Ergotamine麦角胺(主要用于治偏头痛和防止产后大出血)
Estrone雌激素酮
Etafedrine
Etamiphylline
Ethinyloestradiol
Ethoheptazine
Ethopropazine
Ethylmorphine
Etonitazene
Etorphine
Etoxeridine
Fencamfamin
Fenethazine
Fenfluramine(抑制食欲以治肥胖的)氟苯丙胺
Fenoterol
Fentanyl
Flavoxate
Fluopromazine
Flupenthixol
Flupenthixol5-oxide
Fluphenazine
Flurazepam
Glycopyrronium
Haloperidol
Halopyramine
Harmine
Herion
Hexoestrol
Histapyrrodine
Homatropine
Hydrastinine白毛莨分碱
Hydrochlorothiazide
Hydrocodone
Hydromorphinol
Hydromorphone
Hydroxypethidine
Hydroxyzine
Hyoscine
Hyoscyamine
Ibogaine
Imipramine
ImipramineN-oxide
Indapamine
Indole吲哚
Iprindole
Isolysergide
Isomethadone
Isothpendyl
Isoxsuprine
Ketanserin
Ketobemidone
Labetalol
Laudanosine
Levallorphan
Levomepromazene
Levomethorphan
Amylocaine
Benzocaine
Tetracaine
Lidocaine
Phenacetin乙酰对氨苯乙醚,非那西汀(解热镇痛剂的一种)
Paracetamol
Salicylamide
Amitriptylene
Protriptylene
Nortriptyline
Carbamazepine
Imipramine
Desipramine
Tripramine
Opipramine
Sulphacetamide
Sulphadiazine
Sulphaguanidine
Sulphamerrazine
SulphathiazolLevorphanol
Lidoflazine
Lignocaine利诺卡因,二乙氨基(麻醉用)
Lofepramine
Lorcainide
Loxapine
Lysergamide
Lysergicacid麦角酸
Lysergide(LSD)
Lysergol
Maprotiline
Mebanazine
Mebeverine
Mebhydrolin
Mecamylamine
Meclophenoxate
Meclozine
Medazepam
Mephentermine
Mepivacaine
Meptazinol
Mepyramine
Mequitazine
Mescaline酶斯卡灵(一种致幻剂)
Mesoridazine
Metacillin
Metaraminol
Metazocine
Methadone
Methapyriline
Methdilazine
Methizine
Methoserpidine
Methotrimeprazine
Methoxamine
Methoxyphenamine
Methoxypromazine
Methlamphetamine
Methyldesorphine
Methylephendrine
Methylergometrine
Methylphenidate
Methylsergide
Metoclopramide
Metopimazine
Metoprolol
Mianserin
Monoethylglycinexylidide(MEGX)
Morazone
Morpheridine
MorphineN-oxide
Morphine吗啡
Myrophine
Nadolol
Nalorphine
Naloxone
Naphazoline
Narceine罂粟碱
Nefopam
Nialamide
Nicocodine
Nicotine烟碱
Nifedipine
Nomifensine
Norbutriptyline
Norchlorpromazine
Norchlomipramine
Norcodeine
Norcyclizine
Nordextropropoxyphene
Nordothiepin
Nordotheipin5-oxide
Nordoxepin
Norphenfluramine
Normianserin
Normorphine
Nororphenadrine
Norpethidine
Nortrimipramine
Nortriptyline
Norverapamil
Norzimelidine
Noscapine
Opipramol
Orphenadrine
Oxacillin
Oxeladin
Oxomemazine
Oxprenolol
Oxycodone
Oxymetazolin
Oxymorphone
Oxypertine
p-Chlorodisopyramide(CDP)
Papaverine
Pargyline
Pecazine
Penbutolol
Pentazocine
Penthienate
Perazine
Perhexiline
Perphenazine
Pethidine
Pethidinicacid
Phenadoxone
Phenampromide
Phenazocine
Phenbutrazate
Phencyclidine
Phendimetrazine
Phenelzine
Phenglutamide
Phenindamine
Pheniramine
Phenmetrazine
Phenomorphan
Phenoperidine
Phenothiazine
Phenolxybenzamine
Phentolamine
Phenylephrine
Phenltoloxamine
Pholcodeine
Physostigmine
Piminnodine
Pimozide
Pindolol
Pipamazine
Pipazethate
Piperacetazine
Piperidolate
Pipradrol
Pirbuterol
Pirenzepine
Pitramide
Pizotifen
Practolol
Prajmalium
Pramoxine
Prazosin
Prenylamine
Prilocaine
Primaquine
Proadifen
Procainamide
Procaine普卡因(一种局部麻醉药)
Prochlorperazine
Procyclidine
Proheptazine
Prolintane
Promazine
Promethazine
Pronethalol
Propanolol
Properadine
Propiomazine
Propranolol
Prothipendyl
Protokylol
Protriptyline
Proxymetacaine
Pseudoephedrine
Psiloci