天然胶丁晴胶氟胶特性Natural rubber NBR fluorine gum characteristicsWord文件下载.docx
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2,accordingtotheformisdividedintoblockrubber,latex,liquidrubberandrubberpowder.
3,accordingtotheuseofdividedintogeneralandspecialtype.
Thegeneralrubberhasgoodcomprehensivepropertiesandiswidelyused.Themaincontentsareasfollows:
naturalrubber.Isoprenerubber,alsocalledsyntheticnaturalrubber.Styrenebutadienerubber,referredtoasSBR.Thebutadienerubber,referredtoasBR.
Nitrilerubber,referredtoasNBR.
Preparedbycopolymerizationofbutadieneandacrylonitrile.Withgoodoilresistance,heatresistance,coldresistance,pressureresistanceandwaterresistance,airtightnessandexcellentbondingproperties,andabrasionresistanceissuitable,thetemperatureisapproximately40DEGC120commonlyused,canbeusedforalongtimeatthetemperatureof120DEGCintheairoroilat150c..
Itiseasytousemetaltomouldthehydraulicsealsinanyshape.Therefore,NBRismostsuitableformakingsealsforhydrauliccylinderswhoseworkingpressureisnotgreaterthan32Mpa.Speciallydesignedformula,easytopresshairoil:
wearable,canbearthemechanicalaxisspeedofthecar3000rpm/below(atthistimetherubberhardnessis70degrees).
Siliconerubber.SILICONE
Thebackboneconsistsofalternatingatomsofsiliconandoxygen,withorganicgroupsonsiliconatoms.Highandlowtemperature,ozoneresistance,goodelectricalinsulation.Usetemperatureof-40DEGC+220DEGC;
inhightemperature,oilresistant,abrasionresistance,oilresistance!
Theutilitymodelisespeciallysuitableforthecrankshaftoilsealintheautomobileengine,whichisnotresistanttotemperatureandvolatileoil(diesel,gasoline),andhastheresistancetooxygen,ozoneandsunlight(ultravioletlight).
Fluorinerubber.Viton
Asyntheticrubbercontainingfluorineatomsinasubstructure.Usually,thenumberoffluorineatomsinthefluorinecontainingunitinthecopolymerisexpressedasfluorinerubber23,andthecopolymeristwovinylidenefluorideandthreefluorinevinylchloride.Fluorinerubber,hightemperature,oilresistance,chemicalresistance.Itisresistanttooil,hightemperature,chemicalresistance,andhasthecharacteristicsofacidandalkaliresistance.Usetemperature-30+280.Theutilitymodelissuitableforacrankshaftoilsealinajetengine,atimingoilsealandaOringandasealingringusedforchemicals
Characteristicsofsilicagel
Itisdividedintocoarseporesilicagelandfineporesilicagel
Silicagelcanabsorbwater,andcanalsoabsorbacetyleneandcarbondioxide.Withthedecreaseoftemperature,thefirstadsorptioniswater(atnormaltemperature,about25DEGC),followedbyacetyleneandcarbondioxide(thelowerthetemperature,thestrongertheadsorptioncapacity).
Takingadsorptionwaterasanexample,theparticlesizerangedfrom/mm4to8,andthedynamicadsorptioncapacitywas/%6to8.Afterdrying,theairmoisturecontentwas/g,M-30.03,andtheairdewpoint/temperaturewas-52afterdrying
Regenerationtemperature/temperature140~160
Silicagelhaslargeradsorptioncapacityforwater,lowerregenerationtemperatureandcheaperprice,sosilicagelismainlyusedasadsorbenttoadsorbcarbondioxideandacetyleneatlowtemperatureinairseparationunit.Itsdisadvantageisthatmorepowder.
Therearetwokindsofsilicagelporeandpore,andthetwoaredifferentindiameter.Theporesizeofcrudesilicagelis5~10nm(1nm=10-9m,NM),andthespecificsurfaceareaofsilicagelis100to300m2/gpergram.Ithasstrongwaterabsorptionabilityandisnoteasytobebrokenafterabsorbingwater,
Goodmechanicalstrength,oftenusedinthedryertoabsorbmoisture.Theporediameterofporesilicagelis2.5~4nm,andthespecificsurfaceareais400~600m2/g.Commonlyusedtoabsorbcarbondioxideandacetylene,adsorptionwatereasilybroken.Theadsorptionprocessiscarbondioxideadsorberin-110~-120underlowtemperature,goodadsorptioneffectofCO2,alsocanadsorbacetylene.Becausethetemperaturelowerthan-130DEGCcarbondioxidesolidprecipitation,solidcarbondioxidenotonlyadsorbedsilicagel,andwillplugtheadsorber.Theadsorptionofacetyleneiscarriedoutinliquidairandoxygenintheadsorber,theadsorptiontemperatureat-170~-180degreescelsius.
Threeyuanethylenepropylenerubberisakindofrubbermadebycopolymerizationofethyleneandpropylenethroughsolution,andthenthirdmonomer(ENB)isintroduced.Threeyuanethylenepropylenerubberisbasicallyasaturatedpolymer,agingresistanceisverygood,goodweatherresistance,goodelectricalinsulationperformance,goodchemicalresistance,goodimpactelasticity.Themaindisadvantageofethylenepropylenerubberisitsslowcuringrate.Itisdifficulttousewithotherunsaturatedrubber,anditsadhesionandadhesionareverypoor,sotheprocessingperformanceisnotgood.
Accordingtothecharacteristicsofethylenepropylenerubber,mainlyusedintherequirementsofagingresistance,waterresistance,corrosionresistance,electricalinsulationinseveralareas,suchaslightfortiresidewall,heatresistantconveyorbelt,wireandcable,anti-corrosionlining,gasket,buildingwaterproofsheet,sealdoorsandwindows,householdappliancesandaccessories,plasticmodification.Propertiesandapplicationsofethylenepropylenerubber.
Ethylenepropylenerubberismainlymadefromethyleneandpropylene.Itisresistanttoaging,electricalinsulationandozoneresistance.Ethylenepropylenerubbercanbefilledwithoilandfilledwithcarbonblack.Thepriceoftheproductislow,andthechemicalstabilityoftheethylenepropylenerubberisgood.Theabrasionresistance,elasticity,oilresistanceandtheproximityofstyrenebutadienerubberareclose.Ethylenepropylenerubberiswidelyused.Itcanbeusedasthetireside,rubberstripandinnertube,aswellaspartsofautomobiles.Itcanalsobeusedaswires,cables,wrappingandhighvoltageandextrahighvoltageinsulationmaterials.Canalsomanufactureandshoes,sanitaryproductsandotherlightcoloredproducts.Propertiesandimprovementofethylenepropylenerubber:
One,1,lowdensity,highfilling
Thedensityofethylenepropylenerubberisakindoflowerrubber,itsdensityis0.87.Coupledwiththelargeoilfilledandfilled,therebyreducingthecostofrubberproducts,makeupfortheshortcomingsofhighpriceofethylenepropylenerubber,EPDMrubberandhighMooneyvalue,highfillingaftermechanicalcandecreaseslightly.
2,agingresistance
Ethylenepropylenerubberhasexcellentweatherresistance,ozoneresistance,heatresistance,acidandalkaliresistance,watervaporresistance,colorstability,electricalproperties,oilfillingandroomtemperaturemobility.Ethylenepropylenerubberproductscanbeusedat120degreesforalongtimeandcanbeusedbrieflyorintermittentlyat150-200degreescentigrade.Addingsuitableantioxidantcanimprovetheuseoftemperature.Peroxidecrosslinkedthreeyuanethylenepropylenerubbercanbeusedinharshconditions.Threeyuanethylenepropylenerubberinozoneconcentration50pphm,stretch30%conditions,upto150hormore,notcracking.
3,corrosionresistance
Duetothelackofpolarethylenepropylenerubber,lowunsaturation,andvariouspolarchemicalssuchasalcohol,acid,alkali,oxidant,refrigerants,detergents,animalandvegetableoils,ketoneandfatwerehighresistance;
butinthegenusandgenusofaromaticlipidsolvent(suchasgasoline,benzene)andmineralpoorstabilityoil.
Underthelong-termactionofconcentratedacid,theperformancewillalsodecline.InISO/TO7620inacollectionofdataofnearly400kindsofcorrosivegasandliquidchemicalsonvariousrubberperformancefunction,andtheprovisionsofthe1-4gradeindicatesthedegreeoftheeffect,effectofcorrosivechemicalsonthepropertiesofrubber:
Levelvolumeswelling/%lowerhardnessvaluesinfluenceonproperties
1,10,10,slightorabsent
210-20,20smaller
330-60.30medium
4>
60>
30serious
4,steamresistance
Ethylenepropylenerubberhasexcellentwatervaporresistanceandissuperiortoitsheatresistance.Insuperheatedsteamat230DEGC,thereisnochangeinappearanceafter100h.Whilefluorinerubber,siliconerubber,fluorinesiliconerubber,butylrubber,nitrilerubberandnaturalrubberunderthesameconditions,experiencedashorttime,theappearanceofobviousdeterioration.
5、resistancetohotwaterperformance
Ethylenepropylenerubberhasbetterresistancetooverheatedwater,butitiscloselyrelatedtoallvulcanizationsystems.IntwotwoTMTDforcuringmorpholine,ethylenepropylenerubbervulcanizationsystem,125degreesinthesuperheatedwaterimmersionafter15months,thechangeofmechanicalpropertiesisverysmall,thevolumeexpansionrateofonly0.3%.
6,electricalperformance
Ethylenepropylenerubber(EPR)hasexcellentelectricalinsulationandcoronaresistance,anditselectricalpropertiesarebetterthanornearstyrenebutadienerubber,CSM,polyethyleneandxlpe.
7,elasticity
Becausethereisnopolarsubstituentsofethylenepropylenerubbermolecularstructure,themolecularcohesiveenergyoflowmolecularchaincanmaintainflexibilityinawiderange,afterdiscussiona