完整版附录Ⅵ物质的标准摩尔生成焓标准摩尔生成吉.docx

1、完整版附录物质的标准摩尔生成焓标准摩尔生成吉附录 物质的标准摩尔生成焓、标准摩尔生成吉布斯函数、标准摩尔熵和摩尔热容 (100kPa)(1) 单质和无机物物质fH m (298.15K) fGm (298.15K)Sm (298.1 5K)Cp,m (298.15K )-1 kJ molkJ mol -1JK -1molJK -1molAg(s)0042.71225.48Ag2CO3(s)-506.14-437.09167.36Ag2O(s)-30.56-10.82121.7165.57Al(s)0028.31524.35Al(g)313.80273.2164.553Al 2O3- -1669

2、.8-2213.160.98679.0Al 2(SO4) 3(s)-3434.98-3728.53239.3259.4Br2(g)111.88482.396175.021Br 2 (g)30.713.109245.45535.99Br 2 (l)00152.335.6C(g)718.384672.942158.101C( 金刚石 )1.8962.8662.4396.07C( 石墨 )005.6948.66CO(g)-110.525-137.285198.01629.142CO2(g)-393.511-394.38213.7637.120Ca(s)0041.6326.27CaC2(s)-62.8

3、-67.870.262.34CaCO3(方解 石)-1206.87-1128.7092.881.83CaCl2(s)-795.0-750.2113.872.63CaO(s)-635.6-604.239.748.53Ca(OH)2(s)-986.5-896.8976.184.5CaSO4( 硬石 膏)-1432.68-1320.24106.797.65Cl-(aq)-167.456-131.16855.10Cl 2(g)00222.94833.9Cu(s)0033.3224.47CuO(s)-155.2-127.143.5144.4Cu2O-166.69-146.33100.869.8F2(g)

4、00203.531.46Fe- 0027.1525.23FeCO3(s)-747.68-673.8492.882.13FeO(s)-266.52-244.354.051.1Fe2O3(s)-822.1-741.090.0104.6Fe3O4(s)-117.1-1014.1146.4143.42H(g)217.94203.122114.72420.80H2(g)00130.69528.83D2(g)00144.88429.20HBr(g)-36.24-53.22198.6029.12HBr(aq)-120.92-102.8080.71HCl(g)-92.311-95.265186.78629.1

5、2HCl(aq)-167.44-131.1755.10H2CO3(aq)-698.7-623.37191.2Hl(g)-25.94-1.32206.4229.12H2O(g)-241.825-228.577188.82333.571H2O(l)-285.838-237.14269.94075.296H2O(s)-291.850(-234.03 )(39.4 )H2O2(l)-187.61-118.04102.2682.29H2S(g)-20.146-33.040205.7533.97H2SO4(l)-811.35(-866.4 )156.85137.57H2SO4(aq)-811.32HSO4

6、(aq)-885.75-752.99126.86l 2(g)00116.755.97I 2(g)62.24219.34260.6036.87N2(g)00191.59829.12NH3(g)-46.19-16.603192.6135.65NO(g)89.86090.37210.30929.861NO2(g)33.8551.86240.5737.90N2O(g)81.55103.62220.1038.70N2O4(g)9.66098.39304.4279.0N2O5(g)2.51110.5342.4108.0O(g)247.521230.095161.06321.93O2(g)00205.138

7、29.37O3(g)142.3163.45237.738.15OH-(aq)-229.940-157.297-10.539S（单斜）0.290.09632.5523.64S(斜方)0031.922.60(g)124.9476.08227.7632.55S(g)222.80182.27167.825SO2(g)-296.90-300.37248.6439.79SO3(g)-395.18-370.40256.3450.702-SO42- (aq)-907.51-741.9017.2(2) 有机化合物物 质 fH m (2 98 .1 5K ) fG m (2 98 .1 5K )Sm (298.1

8、5K)Cp ,m( 29 8. 15 K)kJ m ol1kJ m ol1JK- 1m ol1J K- 1 m ol1CH 4( g)甲 烷-74.84750 .827186.3035 .715C2H2 (g ), 乙 炔226.748209.20020 0.92843 .928C2H4 (g ), 乙52 .28368 .157219.5643 .5 6烯C2-8-32252H64.2.9.6(g66826050),71乙烷C320622663H6.4.77.8(g1483059),丙烯C3-1-22773H6033.0.5(g.839021),471丙烷C411152779H60.0.8.

9、5(g1674854),1,3-丁烯C4-0713085H8.1.65.6(g30715),1-丁烯C4-6653078H8.9.90.9(g96941),顺-2丁烯C4-1632987H81.06.8(g ), 反-2丁 烯177592C4-1582989H86.13.1(g ),2- 甲 基 两 烯907702C4-1-13197H10267.0.4(g ), 正 丁 烷.1502235C4-1-22996H10340.4.8(g ), 异 丁 烷.5279752C682122681H6.99.9.6(g ), 苯27723317C649121713H6.04.2.5.(l ), 苯285

10、973577C6-1312910H1223.98.6.(g.125127),4环己烷C6-1-03814H1467.08.3.(g.198509),9正己烷C6-1-42919H1498.05.4.(l.888993),2正己烷C649123110H5.92.9.3.CH993886763(8g)甲苯C611112115H5.94.9.7.CH952958113(9l)甲苯C618123513H4.92.2.3.(C95208626H27)(g)邻甲苯C6-2112418H44.0.6.7.(4349489CH953)2(l)邻甲苯C617113512H4.28.7.7.38978057(7C

11、H3)2(g)间甲苯C6-2102518H5.7.2.3.(4181173CH873)2(l)间甲苯C617123512H4 ( CH 3) 2( g)对甲 苯.9491.2662.536.86C6H4 ( CH 3)2( l)对 甲 苯-24.42611 0.244247.36183.7含氧化合物HC OH (g ), 甲 醛-115 .9 0-110.0220.235 .3 6HC OO H( g)甲 酸-362 .63-335 .69251.154.4HC OO H( l)甲-4 09.20-345.9128.9599 .0 4酸CH-2-123493O01617.4H(.1.88g)7

12、3甲醇CH-2-112813O38666.6H(.5.18l)75甲醇CH-1-126622C66335.8OH.3.68(g67),乙醛CH-4-315123C87929.3.OO.0.484H(l)乙酸CH-4-329723C36813.4OO.4.54H(g)乙酸C2-2-11611H577740.1.OH.6.3746(l36),乙醇C2-2-12871HO35682.1H(.3.51g)14乙醇CH-2-120123C48550.4.OC.2.3073H3833(l)丙酮CH-2-129753C16526.3OC.6.200H39(g),丙酮C2-2-125H573163.OC.2.

13、412H57(l),乙醚CH-4-3253C63159OO.2.3C2H5(l),乙酸乙酯C6 H5 CO OH ( s)苯 甲 酸-384 .55-245.5170.7155.2卤代烃CH 3C l( g)氯 甲 烷-82.0-58.6234.2940 .7 9CH 2C l2 (g ),氯 甲 烷-88-59270.6251 .3 8CH Cl3 ( l)氯 仿-131.8-71.4202.9116.3CHCl 3( g)氯 仿-100-67296.4865 .8 1CC-1-62113l4 (l ), 四 氯 化 碳39.38.54.431.75CC l4 (g ), 甲 氯 化 碳-1

14、 06.7-64.0309.4185 .5 1C6H5 Cl (l ), 氯 苯116.3-198.2197.5145.6含氮化合物NH (CH3) 2( g)甲 胺-27.659.1273.269 .3 7C5H5 N( l)吡 啶78 .8 7159.9179.1C6H5 NH2(35 .3 1153.35191.6199.6l)苯 胺C6151424H5.96.4.NO 2， (l ) 硝 基 苯0363本附录数据主要取自 Handbook of Chemistry and Physics, 70 th Ed., 1990; Editor John A.Dean,Langes Handbook of Chemistry, 1967 。