1、有机物换算成cod表表1 常见化合物的CODCr、CODMn、BOD5、TOD和TOC之相关值(1) 烃及卤代烃类序号化合物名称结构式化合物浓度(mg)THODCODcrCODcrTHOD (%)BOD5BOD5THOD (%)THOCTOCTOC THOC(%)BOD5CODcrTHOD THOC1甲烷CH4100040007502一氯甲烷CH3Cl10009504772872383二氯甲烷CH2Cl21000376(360)014124三氯甲烷CHCl310005363351005(101)5三溴甲烷CHBr31000(253)0(48)6四氯化碳CCl41000(416)208078(7
2、8)7乙烷CH3CH310003725798818环氧乙烷CH2CH2O10001877(2210)11702005459二氯乙烷C2H4Cl210001132(810)2425(243)101、2二氯乙烷ClCH2CH2Cl1000(258)113254519824318511三氯烷Cl2CHCH2Cl1000840(180)12四氯乙烷Cl2CHCHCl21000(201)667496242143(143)22313丙烷H3CCH2CH31000362981714环氧丙烷CH2CHCH3O10002203(2210)62015CH2CHCH2Cl Cl1000(182)1132480247
3、34919716CH2CHCH2Cl Br Br1000425(440)15317CH2=C-CH=H3C10003294(3240)425(440)88218CF3CH2ClCH21000727(350)27319正十二烷C12H2010003482(3480)28084720汽油7821石油1000(3500 4500)3000 4300300 43022重油3000 366033023煤油53024乙烯H2C=CH21000342985725二氯乙烯Cl2C=CH21000667990250(2) 醇类化合物序号化合物名称结构式化合物浓度(mg)THODCODcrCODcTHOD (%)
4、rBOD5BOD5THOD (%)rTHOCTOCTOC THOC(%)rBOD5COD5THOD THOCTHON1甲醇CH3OH10001005015007514201440901020112088753739981032乙醇C2H3OH1000100502080198010901570100072523苯甲醇C6H5CH2OH100025157304氯乙醇ClCH2CH2OH10009932985氰乙醇NCCH2CH2OH100013508001976氨基乙醇NH2CH2CH2OH100013101200930343937乙酰氨基乙醇CH2CH2OHNH2COCH310001400110
5、08甲氧基乙醇CH2CH2OHOCH310001682(1680)110065547313569乙氧基乙醇CH2CH2OHOC2H610001953(1960)106010苯乙醇C6H5CH2CHOH21000(2620)1500158011正丙醇C3H2OH10001002396(2400)24022202240154015805994412异丙醇CH3CHOHCH310002396(2400)224022501590599133.氯丙醇CH2CH2CH2OHCl10001354(1350)1360141,3二氯丙醇CH2CH2CHOHCl Cl1000868(1200)8401160101
6、5丙烯醇CH2=CHCH2OH10002203(2216)1682420179016丁醇C4H9OH10002590(2600)240024101140126017异丁醇CH3CHCH2OHCH3/10002590(2600)229923001600166018特丁醇C4H9OH10002590(2600)2180848400019戊醇C5H11 OH10002723(2730)1230162020异戊醇CH3CHCH2OHCH3/10002723(2730)150020异戊醇50136(120)7663343521己 醇C6H16OH10002819(2820)22环己醇C6H6OH1000
7、2819(2820)1600234.甲基戊醇(2)CH3CHCH2CHCH8CH3/ OH10002829(2820)24辛醇C5H17OH10002949(2950)全120073725异壬醇C9H10OH10002995(3000)28009374926乙二醇CH2OHCH2OH1000100501289(1290)12401004905038829387391.427聚乙二醇(CHCHOHOH)n10003003028丙二醇(1,2)CH2CHCH3OH OH10001682(1690)1630116047329丙二醇(1,3)CH2CH2CHOH OH10001682(1680)164
8、0全27647330甲基,丁二醇(1,3)CH3C CH2CH2OHCH3 OH10002151(2140)全1350576311,氯丙二醇(1,2)ClCHCHCH3 OH OH10001017(920)327322,甲基戊二醇(2,4)CH3CCH2CHCH3CH3/ OH OH10002302(2301)60933丙三醇CH2 CH CH2 OH OH OH1000100601216(1200)221.5100117011809536810770513910434季戊四醇C(CH2OH)410001410(1420)6035ClCH2 /CH2OHCClCH2/ CH2OH100036聚
9、乙烯醇(CH2=CHOC)nn=175018183037正十二烷醇10003040460(3) 醚类化合物 化合物名称化合物浓度(mg)THODCODCrCODCr/THOD (%)BOD5BOD5/THOD (%)THOCTOCTOC /THOC(%)BOD5/CODcrTHOD THOC1乙醚C2H5OC2H510002595(2590)82784902O(C2H4OH)210001000全1763O(C2H4OC2H5)210002173(2180)1004苯甲醚C5H6OCH310002516170777(4) 醛类化合物序号化合物名称结 构 式化合物浓度(mg)THODCODcrCO
10、DcrTHOD (%)BOD5BOD5THOD (%)THOCTOCTOC THOC(%)BOD5CODcrTHOD THOC1甲醛HCHO1000100501070499813765606804004020361890902苯甲醛C6H5CHO10002412(2420)287198080801500 16206767533二甲氧基缩甲醛CH(OCH3)210001620(1680)16402704804乙醛CH3CHO10001618(1820)82010506509105丙醛C2H5CHO10002204(2200)全11906丙烯醛CH=CHCHO10001998(2000)17208
11、066033642(643)7苯基丙烯醛C6H5CH2=CHCHO10002523(2559)8丁醛C3H7CHO10002441(2440)11609丁烯醛CH3CH=CHCHO10002280(2410)800103羟基丁醛H3CCHCH2CHOOH10001820(1750)11糠醛- CHOO10001665(1670)77012苯甲醛C6H5CHO10002412(2420)28719808015001620677925813三氯乙醛Cl3CCHO100022014二甲氧缩甲醛OCH3CHOCH310001620(1680)16402704863.33(5) 酮类化合物序号化合物名称
12、结 构 式化合物浓度(mg)THODCODcrCODcrTHOD (%)BOD5BOD5THOD (%)THOCTOCTOC THOC(%)BOD5CODcrTHOD THOC1丙酮CH3COCH310001002204(2210)22011022188027078594848101120(66)373762040772甲乙酮CHCOC2H5100010050244019202200(286)9077181074746065903甲基异丙基酮H3CCOCH(CH3)21000200272674环乙酮C6H6O26122610)10005甲基异丁基酮CH3COCH2CH(CH3)21000271
13、22720)120471933786甲基戊基酮CH3COC5H1110002805(2800)表2 工业中常见有机化合物的一些有关参数序号化合物名称熔点沸点密度kg/L水中溶解度g/LCOD值g/gBOD值g/g生物可降解性毒性mg/L1一乙胺易+292一甲胺易+3一氯乙酸61189易+4一氯甲烷-245005乙二胺117互溶+6乙二醇-13198互溶+100007乙二醇单乙醚135互溶+8乙二醇单丁醚-401709乙二醇单甲醚-85124互溶1000010乙苯-95+1211乙苯胺(混合物)+12乙炔-8400-132-乙基已醇-761+8214乙基仲戊基酮1601622515乙烯亚胺-71
14、5556互溶16乙脯互溶+68017乙酰乙酸乙酯18018118乙酰丙酮1391256719乙酰马啉14152020乙酰苯汞153021乙酰苯胺11430522乙酰胺222易+1000023乙酸互溶+24乙酸乙烯酯-1007325+625乙酸乙酯80+26乙酸丁酯14+11527乙酸丙酯-9510217028乙酸戊酯-75148+14535029乙酸异丁酯118+20030乙酸异丙酯-739018+19031乙酸环已酯17718332乙酸苯酯19611533乙酸叔丁酯967834乙酸钙+35乙酸钠123+36乙酸钾255+37乙酸铵易38乙醇-117互溶+650039乙醇胺11172互溶+63
15、0040乙醛-124互溶+41乙醛酸7942乙醚-116356943二乙汞0044二乙铵-45互溶+45N,N-二乙基苯胺2160046N,N-二乙基羟胺47二乙烯三胺五醋酸48二乙醇胺28269互溶+1000049二丙酮醇-5716982550二甘醇单乙醚202互溶25551二甘醇单丁酯-68231互溶52二甘醇单丁醚-68231互溶53二甲苯+54二甲苯胺(混合物)0055二甲氧基甲烷4433056二甲胺易+572,5二甲基-1,4二恶烷200582,4-二甲酚260592,5-二甲酚732120602,6二甲酚4620300,+613,4二甲酚65225623,5二甲酚6821963二异丙胺64二异丙醚-8669965二苯醚28259662,6二叔丁基-4-甲基酚7026567N,N二甲基甲酰胺-61153互溶,683,3-二甲基戊二酸102,69二甲基亚砜18970N,N-二甲基苯胺21921,712,4-二甲基苯胺2188722,5-二甲基苯胺2170734,4二氨基二苯甲烷93231/1115742,6-二氨基吡啶12128500752,6-二羟基异菸酸300,762,4-二硝基甲苯70300
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