乙醛酸MSDS和GHS.docx

1、乙醛酸MSDS和GHS乙醛酸MSDS和GHS化学品分类检验记录单 第 1页 共6页 化学品分类检验记录单 样品名称: 报验号: 样品编号: 检验项目:化学品分类及GHS 检验依据:联合国关于危险货物运输的建议书;国际海事组织国际海运危险货物规则;国际航空运输协会危险品规则(IATA) 记录见附页: 货物运输条件鉴定书 Certification for Safe Transport of Dangerous Goods 报检编号: 申报品名 中文Chinese 乙醛酸 Name of Goods 英文English Glyoxylic acid 分子式 CHO 223Molecular for

2、mula 申请单位 Applicant 生产单位 Manufacturer 样品外观与性状 淡黄色透明液体 Appearance and property Light yellow transparent liquid 主要危险性 8 Main Danger 次要危险性 无 Subsidiary Danger NONE 正确运输名称 腐蚀性液体，酸性的，有机的，未另列明(乙醛酸) Proper Shipping Name Corrosive liquid, acidic, organic, n.o.s. (Glyoxylic acid) CAS登记号 CHO : 298-12-4 223CAS

3、 Register Number 危险性类别 8 Class or Division 20 年 月 日发布 年 月 日第 次修改 发布人: 化学品分类检验记录单 第 2页 共6页 联合国编号 UN 3265 UN Number 包装类别 ? Packing Group 联合国关于危险货物运输的建议书，Recommendations on the 检测鉴定依据 Transport of Dangerous Goods;国际海事组织国际海运危险货物规Warranty of Test 则，International Maritime Dangerous Goods;国际航空运输协会危险品规则，Dan

4、gerous Goods Regulation(IATA); 委托人自送样品。本鉴定书适用于货物的航空运输和海洋运输，原件有效期至 特别声明 The client submits the sample. Certification for Safe Transport of Dangerous Special Statements Goods apply to cargo air transport and marine transport, the term of validity to 爆炸危险性鉴定 该货物无爆炸危险性 Determination for NONE Explosive D

5、anger 易燃危险性鉴定 该货物无易燃危险性 Determination for NONE Flammable Danger 氧化危险性鉴定 该货物无氧化危险性 Determination for NONE Oxidizing Danger 毒害与感染危险性鉴定 该货物无毒害性，无感染危险性 Determination for Toxic & NONE Infectious Danger 放射性危险性鉴定 该货物无放射性危险性 Determination for NONE Radioactive Danger 腐蚀危险性鉴定 该货物有腐蚀危险性 Determination for The g

6、oods have Corrosive Dangers Corrosive Danger 其它危险性鉴定 该货物无其它危险性 Determination for Other NONE Dangers 20 年 月 日发布 年 月 日第 次修改 发布人: 化学品分类检验记录单 第 3页 共6页 HO;分子量 (Molecular Weight):74.04;分子式(Molecular Formula):C223熔点 (Melting Point):-93?C;沸点(Boiling Point):111?C;密度(Density ):1.33g/mL(20?C);折射率(Refractive in

7、dex ) n20/D:1.414;水溶性(Water Solubility):与水混溶(Miscible)。淡黄色透明液体。能与水混溶，微溶理化性质 于乙醇、乙醚。不溶于酯类，芳香族类溶剂。该溶液在空气中放置极不Physical & Chemical 稳定但不变质，乙醛酸在水溶液中以水合形式存在，有腐蚀性和刺激性。Properties Light yellow transparent liquid. Miscible with water, slightly soluble in ethanol, ethyl ether. Insoluble in esters, aromatic solv

8、ents. The solution was placed in the air is very unstable, but not bad, glyoxylic acid in aqueous solution exist in hydrated form, corrosive and irritating. 处理:不使用时保持容器密闭，避免与眼睛、皮肤和衣物相接触。防止吸入蒸汽和气雾。在干燥的保护气体下处置，确保工作间有良好的通风或排气装置。接触后用肥皂水冲洗皮肤。空容器可能含有残留物，不要重新使用或损坏空容器。远离食品、饮料和饲料。 储藏:将容器密封。储存于阴凉(2-8?C)、干燥、通风

9、的防火区域。远离氧化剂存放。打开了的容器必须仔细重新封口并保持竖放位置以防止泄漏。不要在工作区域饮食。在进食、饮水前要用肥皂水洗手。 鉴定货物在贮存、运输中Handing: Keep containers closed when not in use. Avoid contact with skin, 的危险性分析 eyes and clothing. Avoid inhalation of vapor or mist. Handle under dry Analysis of Dangerous protective gas; ensure good ventilation at the w

10、orkplace. Wash skin with Properties For Goods in soap and water after contact. Empty containers may contain product residue. storage and Transport Do not reuse and damage empty container. Keep away from foodstuffs beverages and feed. Storage: Keep container tightly sealed. Store in a cool (2-8?C), d

11、ry, well-ventilated and fireproof storage place. Store away from oxidizing agents. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Consumption of food and beverage should be avoided in work areas. Wash hands with soap and water before eating and drinking.

12、应遵循一般的化学物品预防措施。全套防化学试剂工作服，防护设备的类型必须根据特定工作场所中的危险物的浓度和含量来选择。休息以前和工作结束时洗手。 防护措施 The usual precautionary measures for handling chemicals should be Protection Measures followed. Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration an

13、d amount of the dangerous substance at the specific workplace. Wash hands before breaks and at the end of workday. 20 年 月 日发布 年 月 日第 次修改 发布人: 化学品分类检验记录单 第 4页 共6页 眼睛接触:用大量肥皂和水冲洗眼睛至少15分钟，其间提起眼睑。就医。 皮肤接触:立即用大量水和肥皂彻底冲洗至少15分钟，脱去污着衣物。如大面积皮肤受损或持续刺激请就医。衣物清洗后再使用。 吸入:立即将人员移至通风处。如果呼吸停止，速进行人工呼吸抢救。如果呼吸困难，需立即供氧。让

14、病人保暖，严重情况或不能立即完全恢复立即就医。 摄取:禁止催吐。切勿给失去知觉者从嘴里喂食任何东西。如患者意识清醒，用清水漱口;如感觉不适立即就医。 Eye: Flush eyes with plenty of soap and water for at least 15 minutes while 急救措施 holding eyelids open. Obtain medical aid. First-aid Measures Skin: Immediately flush skin with plenty of water and soap and rinse thoroughly for

15、 at least 15 minutes while removing contaminated clothing and shoes. If large areas of the skin is damaged or if irritation persists get medical attention. Wash clothing and shoes before reuse. Inhalation: Remove victim to fresh area. If not breathing, give artificial respiration, preferably mouth-t

16、o-mouth. If breathing is difficult, give oxygen. Keep patient warm. In severe cases, or if recovery is not rapid or complete seek immediate medical attention. Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. If patient is conscious, Wash out mouth with water.

17、 If patient feels unwell call a physician immediately. 使用水喷雾、干粉、泡沫或二氧化碳灭火器灭火。如必要的话，戴自给灭火方法 式呼吸器去救火。Use water spray, dry chemical powder and appropriate Fire-extinguishing Method foam or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary. 使用个人防护设备。将人员撤离到安全区域。避免与眼睛接触

18、。戴呼吸罩，保证充分的通风，防止吸入蒸汽、气雾或气体。避免接触泄漏物。如果安全易操作，切断泄露。用沙土、硅藻土、酸性粘合剂、通用粘合剂、锯屑等惰性吸附材料吸收泄露。尽可能多地收集泄漏处理物于有标签的合适容器中。处理完泄露后用水冲刷泄露区域。泄漏处理物禁止倒入下水道、沟渠或水渠。 泄漏应急措施 Use personal protective equipment. Evacuate personnel to safe areas. Avoid Accidental Release contact with eye. Wear respiratory protection, Ensure adequ

19、ate ventilation, Measures Avoid breathing vapors, mist or gas. Avoid contact with the spilled material. Shut off source of the leak only if is safe to do so. Absorb with sand, diatomite, acid binders, universal binders, sawdust and etc. inert absorbent material. Collect as much of the spilled materi

20、al as possible, placed the spilled material into a suitable closed disposal container. Wash spill site with plenty of water after material has been taken up. Keep spilled material out of sewers, ditches and bodies of water. 检验员(Inspector): 审核人(Verifier): 日 期(Date): 日 期(Date): 20 年 月 日发布 年 月 日第 次修改 发

21、布人: 化学品分类检验记录单 第 5页 共6页 GHS 分类试验报告单 委托单位: Applicant: 检测结果(Test result): 报检号(Inspection Number): 样品名称 参考法规 危险类别 警示标签 Name of Reference Classification Precautionary label Goods regulations 图形符号 Pictogram 皮肤腐蚀、刺激 类别1B 标记字符 Skin corrosion/irritation 危险 Signal Category 1B Danger word 敏化-皮肤 类别1 造成严重皮肤灼伤和眼

22、损伤(H314) Sensitization, skin 全球化学Causes severe skin burns and eye 乙醛酸 Category 1 品统一分damage (H314) Glyoxylic 严重眼损伤、眼刺激 类类和标签可能导致皮肤过敏反应(H317) acid 别1 制度 May cause an allergic skin reaction Serious eye damage /eye (GHS) 危险说明(H317) irritation Category 1 与代码 造成严重眼损伤(H318) 敏化-呼吸 类别1 Hazard Causes serious

23、 eye damage (H318) Sensitization, respiratory statements 吸入可能导致过敏或哮喘病症状或Category 1 呼吸困难(H334) May cause allergy or asthma symptoms or breathing difficulties if inhaled (H334) 检验员(Inspector): 主任检验员(Director of Inspector): 20 年 月 日发布 年 月 日第 次修改 发布人: 化学品分类检验记录单 第 6页 共6页 防范说明表(Precautionary statements)

24、危险类型(Hazard category) 信号词(Signal word) 危险说明(Hazard statement) 1B 危险 造成严重皮肤灼伤和眼损伤(H314) (1B Danger Causes severe skin burns and eye damage (H314) 1 警告 可能导致皮肤过敏反应(H317) (1 Warning May cause an allergic skin reaction (H317) 1 危险 造成严重眼损伤(H318) (1 Danger Causes serious eye damage (H318) 1 危险 吸入可能导致过敏或哮喘病

25、症状或呼吸困难(H334) (1 Danger May cause allergy or asthma symptoms or breathing difficulties if inhaled (H334) 防 范 说 明Precautionary statements 预防Prevention 反应Response 贮存Storage 处置Disposal 戴防护手套、穿防护服、立即呼叫解毒中心或医生。具体治疗(见本标签) 存放处须加锁 处置内装物或容戴防护眼罩和戴防护面Immediately call a POISON CENTER or Store locked up 器按照地方、区具

26、 doctor/physician. Specific treatment ( see on this label) 域、国家或国际Wear protective gloves/ 如呼吸系统病症:呼叫解毒中心或医生 规章 protective clothing/ eye If experiencing respiratory symptoms: Immediately call Dispose of protection/ face a POISON CENTER or doctor/physician contents protection 如皮肤沾染(或头发):立即脱去受污染的衣。用水清/

27、container in 作业后应彻底进行清洗 洗/沐浴。 accordance with Wash thoroughly after IF ON SKIN (or hair): Remove/Take off immediately local /regional handling all contaminated clothing. Rinse skin with /national 避免吸入气体、蒸气或water/shower. /international 喷雾 如发生皮肤刺激或皮疹:求医或就诊 regulations Avoid breathing gas/ IF skin irri

28、tation or rash occurs: Get medical vapors/ spray advice/attention 受沾染的工作服不得带如误吸入:将受害人转移到空气新鲜处，保持呼出工作场地 吸舒适的休息姿势 Contaminated work IF INHALED: Remove victim to fresh and air clothing should not be and keep at rest in a position comfortable for allowed out of the breathing. workplace 脱掉所有沾染的衣服，清洗后方可使用

29、 如通风不足，须戴呼吸Take off and wash contaminated clothing before reuse 防护装置 如误吞咽:漱口。不得诱导呕吐 In case of inadequate IF SWALLOWED: Rinse. Do NOT induce vomiting ventilation wear 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜respiratory protection 并可方便地取出，取出隐形眼镜。继续冲洗。 IF IN EYES: Rinse cautiously with water for several times minutes.

30、Remove contact lenses, if present and easy to do. Continue rinsing. 20 年 月 日发布 年 月 日第 次修改 发布人: 危险性说明: 造成严重皮肤灼伤和眼损伤 可能导致皮肤过敏反应 造成严重眼损伤 吸入可能导致过敏或哮喘病症状或呼吸困难 危险 警告说明: 戴防护手套、穿防护服、戴防护眼罩和戴防护面具 作业后应彻底进行清洗 避免吸入气体、蒸气或喷雾 受沾染的工作服不得带出工作场地 如通风不足，须戴呼吸防护装置 立即呼叫解毒中心或医生。具体治疗(见本标签) 如呼吸系统病症:呼叫解毒中心或医生 如皮肤沾染(或头发):立即脱去受污染

31、的衣。用水清洗/沐浴。 如发生皮肤刺激或皮疹:求医或就诊 如误吸入:将受害人转移到空气新鲜处，保持呼吸舒适的休息姿势 脱掉所有沾染的衣服，清洗后方可使用 如误吞咽:漱口。不得诱导呕吐 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 存放处须加锁，处置内装物或容器按照地方、区域、国家或国际规章 制造商/供应商: 更详细的资料，请参考化学品安全说明书(MSDS) Hazard statements: Causes severe skin burns and eye damage May cause an allergic skin reaction Causes serious eye damage May cause allergy or asthma symptoms or breathing difficulties if inhaled Danger Precautionary statements: Wear protective gloves/ protective clothing/ eye protection/ face protection Wash thoroughly after handling. Avoid breathing gas/ vapors/