1、5.89 0.30 9.05,17.32,19.74,21.00 In3+ 1.30,1.88 Pb2+ 1.77,2.60,3.00,2.30 5.17,9.42,12.70,14.90 Rh3+ 2,3,4,5,6 14.3,16.3,17.6,18.4,17.2 Sc3+ 2.08,3.08 Sn2+ 1,2,3 1.11,1.81,1.46 Tl3+ 9.7,16.6,21.2,23.9,29.2,31.6 U4+ 0.18 Y3+ 1.32 3 Cl- 1,2,4 3.04,5.04,5.30 2.44,4.7,5.0,5.6 1.95,2.50,2.60,2.80 1.42 2,3
2、 5.5,5.7 0.1, -0.6 1.17 Fe3+ 9.8 6.74,13.22,14.07,15.07 1.62,2.44,1.70,1.60 1.42,2.23,3.23 6.1,10.7,13.1,15.7 2,3,4 11.5,14.5,16.0 Sb3+ 2.26,3.49,4.18,4.72 1.51,2.24,2.03,1.48 8.14,13.60,15.78,18.00 Th4+ 1.38,0.38 0.43,0.61,0.53,0.20 Zr4+ 0.9,1.3,1.5,1.2 CN- 21.1,21.7,20.6 Au+ 38.3 5.48,10.60,15.23,
3、18.78 24.0,28.59,30.30 35.0 42.0 41.4 31.3 5.3,11.70,16.70,21.60 5 F- Al3+ 6.11,11.12,15.00,18.00,19.40,19.80 Be2+ 4.99,8.80,11.60,13.10 0.4 Cr3+ 4.36,8.70,11.20 0.9 Fe2+10.8Fe3+1,2,3,55.28,9.30,12.06,15.77Ga3+1,2,34.49,8.00,10.50Hf4+1,2,3,4,5,69.0,16.5,23.1,28.8,34.0,38.0Hg2+1.03In3+1,2,3,43.70,6.4
4、0,8.60,9.80Mg2+1.30Mn2+5.48Ni2+0.50Pb2+1,21.44,2.54Sb3+3.0,5.7,8.3,10.9Sn2+4.08,6.68,9.50Th4+8.44,15.08,19.80,23.20TiO2+5.4,9.8,13.7,18.0Zn2+0.78Zr4+9.4,17.2,23.7,29.5,33.5,38.36I-Ag+6.58,11.74,13.68Bi3+1,4,5,63.63,14.95,16.80,18.80Cd2+2.10,3.43,4.49,5.41Cu+28.851.8812.87,23.82,27.60,29.832.00,3.15,
5、3.92,4.47Pd2+424.5Tl+0.72,0.90,1.08Tl3+11.41,20.88,27.60,31.827OH-2.0,3.99Al3+1,49.27,33.03As3+14.33,18.73,20.60,21.20Be2+9.7,14.0,15.21,2,412.7,15.8,35.2Ca2+1.34.17,8.33,9.02,8.62Ce3+4.6Ce4+13.28,26.46Co2+4.3,8.4,9.7,10.2Cr3+10.1,17.8,29.9Cu2+7.0,13.68,17.00,18.55.56,9.77,9.67,8.5811.87,21.17,29.67
6、10.6,21.8,20.910.0,20.2,29.6,38.92.581,33.9,8.34.97,8.55,11.33Pa4+14.04,27.84,40.7,51.47.82,10.85,14.5813.0,25.82,3,424.3,36.7,38.3Sc3+8.910.4Th3+12.86,25.37Ti3+12.714.40,11.30,14.14,17.6614.3,28.3,41.9,55.38NO3-Ba2+0.921.260.280.401.00.351.180.339P2O74-Cd3+5.66.16.7,9.012.385.75.8,7.47.3,10.158.7,1
7、1.010SCN-4.6,7.57,9.08,10.081.67,3.00,4.00,4.80,5.50,6.101.39,1.98,2.58,3.61.87,2.9812.11,5.181.90,3.002.21,3.64,5.00,6.30,6.20,6.109.08,16.86,19.70,21.701.18,1.64,1.810.78,0.99,1.001.17,1.77,1.741.08,1.781.33,1.91,2.00,1.6011S2O32-8.82,13.463.92,6.4410.27,12.22,13.842.1029.44,31.90,33.242,35.13,6.3
8、512SO42-2.71,2,3,4,51.98,3.41,4.08,4.34,4.604.04,5.381.34,2.401.78,1.88,2.362.42.75Pr3+3.62,4.923.32,5.503.79,6.64,7.77 金属-有机配位体配合物的稳定常数(25)(表中离子强度都是在有限的围,I0。)Stability Constants of Metal Ion-Organic Coordination Compounds 序号(No.)配位体(Ligand)金属离子 (Metal ion)配位体数目 n (Number of ligand)lgn乙二胺四乙酸(EDTA)(H
9、OOCCH2)2NCH227.3216.117.789.322.811.016.416.31Co3+36.023.018.714.8324.2320.2521.8024.95Li+2.798.6413.8Mo(V)6.36Na+1.6618.5618.318.5Sc2+23.122.1Sr2+8.8023.217.322.5U4+17.50VO2+18.0Y3+18.3219.4乙酸 (Acetic acid) CH3COOH 0.73,0.64 Ba2+ 0.41 Ca2+ 0.6 1.5,2.3,2.4 1.68,2.69,3.13,3.18 1.5,1.9 4.63,7.08,9.60
10、Cu2+(20) 2.16,3.20 3.50,5.95,7.90,9.08 9.84,2.06 1.12,1.81 2.52,4.0,6.4,8.5 3.3,6.0,7.3 6.17,11.28,15.10,18.3 1.5 乙酰丙酮 (Acetyl acetone) CH3COCH2CH3 Al3+(30) 8.6,15.5 3.84,6.66 5.40,9.54 Cr2+ 5.96,11.7 8.27,16.34 5.07,8.67 11.4,22.1,26.7 21.5 Mg2+ 3.65,6.27 4.24,7.35 Mn3+ 3.86 Ni2+(20) 6.06,10.77,13.
11、09 6.32 Pd2+(30) 16.2,27.1 8.8,16.2,22.5,26.7 Ti3+ 10.43,18.82,24.90 V2+ 5.4,10.2,14.7 Zn2+(30) 4.98,8.81 8.4,16.0,23.2,30.1 草酸(Oxalic acid) HOOCCOOH 2.41 7.26,13.0,16.3 2.31 3.0 3.52,5.77 4.79,6.7,9.7 6.23,10.27 2.9,4.52,5.22 9.4,16.2,20.2 9.66 Hg22+ 6.98 3.43,4.38 3.97,5.80 9.98,16.57,19.42 5.3,7.
12、64,8.5 4.91,6.76 6.86,11.31,14.32,16.70 24.48 4.89,7.60,8.15 9.80,17.14,20.86,21.15 乳酸 (Lactic acid) CH3CHOHCOOH 0.64 1.70 1.90 3.02,4.85 7.1 1.37 1.43 2.22 2.40,3.80 Sc2+ 5.2 5.5 2.20,3.75 水酸 (Salicylic acid) C6H4(OH)COOH 14.11 5.55 6.72,11.42 8.4,15.3 10.60,18.45 6.55,11.25 5.90,9.80 6.95,11.75 4.
13、25,7.60,10.05,11.60 TiO2+ 6.09 6.3 6.85 7 磺基水酸(5-sulfosalicylic acid) HO3SC6H3(OH)COOH Al3+(0.1mol/L) 13.20,22.83,28.89 Be2+(0.1mol/L) 11.71,20.81 Cd2+(0.1mol/L) 16.68,29.08 Co2+(0.1mol/L) 6.13,9.82 Cr3+(0.1mol/L) 9.56 Cu2+(0.1mol/L) 9.52,16.45 Fe2+(0.1mol/L) 5.9,9.9 Fe3+(0.1mol/L) 14.64,25.18,32.12
14、 Mn2+(0.1mol/L) 5.24,8.24 Ni2+(0.1mol/L) 6.42,10.24 Zn2+(0.1mol/L) 6.05,10.65 8 酒石酸 (Tartaric acid) (HOOCCHOH)2 1.62 8.30 2.98,9.01 2.8 2.1 3.2,5.11,4.78,6.51 7.49 7.0 1.36 2.49 2.06 1,3 3.78,4.7 2.68,8.32 9 丁二酸(Butanedioic acid) HOOCCH2CH2COOH 2.08 3.08 2.0 2.2 3.33 7.28 1.20 2.26 2.36 1.6 10 硫脲(Thiourea) H2NC(S)NH2 7.4,13.1 11.9 0.6,1.6,2.6,4.6 3,4 13.0,15.4 22.1,24.7,26.8 1.4,3.1,4.7,8.3 11 乙二胺(Ethyoenediamine) H2NCH2CH2NH2 4.70,7.70 Cd2+(20) 5.47,10.09,12.09
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