1、3CCH;答案:1很据以卜指汇笊料、试剂和写出其合庙反应的主要产物込号(CHihNCIKHI HC1oio(CHHSiCOBi(4)(5)BtCH?C H ; CH?CH:C H OCI亦0X|_|OMe OMe1NHeCHAc 广3!CHiGIJuhtiMH) J. R., rl j1. J. Urj.Chem., I9&4h 29. 312(kIOJBoa A. K-h et nJ. THrahedvonLett., 40:塑工(IIIc1即6 丫出In dart slats*CI-1JCJArDHWih(*n C. E. L A lit Ctient Soil,|yJ6, 58 J.;9
2、6.(U乂丿JHudson H R卄 L Chcm. Sckt. LA.I96&;血g17=o(14)ar、a(I7iea8Il创Vs Brir2. fl卜列北圧惧桃和产物的反网成屮弁別塡耳必沛的化孚试剂(或鬥反网臺艸.注和NBSAPhcV)z(X CCUi &Br/Hg( Li Mm jehlumcLhaiM1. NaNOj, HCI, HJ3; 1 HPF:rtr 3. A I6SMFNBS/Al. CCLfNBS/P1iCObU. CClj. TtflllK第二章I 凰下捋定凰科*试剂和5*11写出其合成反应的主要产物/ BFj - 0E 切H NNH3 * 也0Eton. 60C忡丰-
3、r富諾冊卿車齊飞輦蚩郑黑邸楚碁Afc由$杳楝玄塾二魁卷塾】刘無护6 、 366 、 36N NH5PhX PhhHY 丫Rssi E M. ct al. lctrnbilroii, 199&. $2; 10379.(5|opDAEka=1,4-di aaa hi 讥曰训 M2.2 叔他 he(7)XQ、NChPh.&II :W L j 3 H =5土PliCH 231亍UiHi.亠t-更ifH NHAC乂在卜列扌R定怎料和严物扪应血成申気别境入必斋鬧化手试刑LHit应应歿p和反廉帥怦O Q 0 -0GQjCjMg * 0/=0 =0CgOaCCH011 / 3611 / 365u2-*w=-亦
4、工一匚O 10M 唔 w1 L工 O 9sVXZ. 呈8-?M nm Q事 涂Mso电3亠=oGQoNd$nni rf-*- Us-B-g祐W MT c12 _ 3612 _ 361在下列IB迄原科和产物的反应丈申井瑯填人必需的优孕试剂讹巧讦梆)和反应董H* (移焉舒宝)ilflL Phi iX-hCJI-hN, 1. glycrrnli i.2tcu C 2GeHsCHQaEequiv, FPh.NCCOOEI 75mjC, 2.5-55h片EtOOC 八POO臼NaCN:ElOHHjO pH7&, heatfit Zr 亠 BrCHCQOC2Hi +匚巴0和帕HErI2OC, 5h沁仃 4
5、) =0 + NCCHsCOOC2H5AuOMIhPhHrheal2圆读I詡俳以尸有苑反应操惟的厚文请芹唾轴却H上耳曲C1)此反应的咸反应式瑕料. 试剂和生罂反应呆朴):(2此反应的反应机理t眉程九In li J-l. muiHJ-hutli.m】ed 仙蠢 Muk 11 litlrd ViAh ei rcflu.?( Lund-efihtr ait plxd 6J5 i.l. til y5 诜mnl alcohol (hMe 2), 5U0 ec. nf water 500(. (476 0c,b 4,7itwIk) of pure henzaldehydc Nimc .Ik snd 50g
6、. nf aodhimcyanidete4). Tn 11k ciiursc nf dhiul twenty mi nutt, crysuh hrjin it? .stlariitc Itlhh ihr ItcH ?uiluiun. Al ihf cud ttf the ihiriy iiiinut die blcuuin ifi ciH)kL f3hrft5d vilh 績氏和in.鼻tai 氐唔外teil wirli 勺 lin k WH出r” Tlit ieldufdry crude bcnrtiiwhich i、生hil* ar lihi YelJou, is 45ft 40 & (帅
7、-怕 per cctu l, 3; +68,Tn a I L thice-ncckcd rnund hononied flaik eq nipped with a nvclunicl xtirrrrb Em refills cniMkritKCL mA hnl gltKH tulv -K-uliing hdew ihf surine df tM liquid for lhe imwriuLinti al hydragn chlnri, m phcd 50 助 0,36 TTinlf if p-Tiiniplieinil rNmc I), ml, oF ciwitcniratrii hyrlni
8、chlnrK: aci of cjflLcniniird sulfuric 血itl (N(xr 即nd 7fi g. (1 irul曰 uf mihylal fN(Kt? J). The inixtuir is uinrd while the ejnperatiue is im in tainted al 70 F fur 4 5 hDiir* by iuhude of a water hnth (Nolt? 4). During this time hydrugtn ehkif de 也 huhhldd 保阳 the rex (ten mixture ihwugi ibe hem 刖坤 r
9、obe, nd the enceiw g亦 k aiiy ihrvugh 6 relink 訊”河畑它门“胡 h啊nl 懐 射卫布网口“】小1 irapfSwThe Z-bydmxy-5-nil mticnzy 1 diloridc begins lo cpanilc 商 a Mtlid about I hour aFlcr the heginninf of the rmcliciTk Al iIk crnl lh mil in? in ccokd in ic? hir I hnur whdTthv mor* crysiak tqunice, afi-er ulikli llie acid 叫
10、LHirh JIV “Lhwt* filtered ul dtC3ntrd hiM” die cryULiLii Nie Hh 2 -li driX%-5-mirubrlV yl cbhriiik 祐 pudfied by rccrystalli74iLitm fnim I 專 ml. “门kh benzene (Nuiv 丁)* The yield 禧-K 鲁.(W% ba址d ufl p-altrupibeTvlf of a wbitt product meliin ar 12弓 LW*.答案1.阴脂以下描定酿弭.试剂和反应条fb写出其音威反应的生要产物:彗瞬特案】、題兮注释B ENZAL
11、ACEP )PJIEhONEcn3刊人厂Y吐 0H 0J, Am. Owm 148X 105:1667.AKM COCH)J. On;一 Clum. 2007. 72. S244.4mo1. pyrrohiiiner g-1s;此底应的反应机理也程儿誉苇伟和CD臥电帶乗匕反向式:2)耕考料累;反应式:反应机珂臾氟甲基ft反应第五章1完成反应(1)(2)H0 0H0H-H:OOGHg(8)CHpNHjNaNO2/H+ 4 (9)(10)2.完成下列合成过程(即填写反应条件或填写括号内的产物)题及答案GHO2Kt NCOOH(3)曰CH,2.4 02XC6H5OM/1.:OMI GO壬如25 /
12、3625 / 36GHCOOEt第六章MO,C rO/H,O()WJC13(6)CH2Ch2.填写反应条件SO?O(CH2)CH3第一题答案题号CHOMOg” COTHI3COCI ,恥 NiiOH31 / 3631 / 36哄:入 ZH:/ OCOCHg第七章(习题及答案)OGH*THF 252改错(题及答案)” CH.CHOHCOOFtWCOCOO斑加化mi3.设计合成题h3cc-a I I 貳崗坏l2陆、氛乙播、乙ffffr成旧Cf (3)第3题答案:CICHjCCXH *CHICOOCjHs)j 聲呵 COOG缶h 羊 CHCMCJ 尹血 (C2H50OC)iCHtCHjltCHlCOOCH :阳;严十 HC(CH, )HCOOC?“qH 心此_ 叱一C=O Zn/HCI H2CC=Q泌 | HOAC - | |(H2C)rCHOH (H2Cl7 CHj
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