1、BINAP (2R,3S)-2,2-bis (diphenylphosphino)-1,1-binaphthyldvb DivinylbenzeneBn Benzyle- ElectrolysisBOC t-butoxycarbonyl % enantiomeric excessBpy (Bipy) 2,2-bipyridylEDA (en) ethylenediamineBu n-butylEDTA Ethylenediaminetetraacetic acidBz BenzoylEE 1-ethoxyethylc- CycloEt EthylCAM CarboxamidomethylFMN
2、 Flavin mononucleotideCAN Ceric ammonium nitratefod Tris-(6,6,7,7,8,8,-heptafluoro-2,2-dimethyl-3,5-octanedionatoCat. CatalyticFp flash point OR Cyclopentadienyl-bis -carbonyl ironCBz CarbobenzyloxyFVP Flash vacuum pyrolysisChirald (2S,3R)-(+)-4-dimethylamino-1,2-diphenyl-3-methylbutan-2-olh hoursCO
3、D 1,5-Cylcooctadienylhv Irradiation with lightCOT 1,3,5-cyclooctatrienyl1,5-HD 1,5-hexadienylCp CyclopentadienylHMPA HexamethylphosphoramideCSA 10-camphorsulfonic acidHMPT Hexamethylphosphorus triamideCTAB Cetyltrimethylammonium bromideiPr isopropylCy CyclohexylLAH Lithium aluminum hydrideDABCO 1,4-
4、diazabicyclo2.2.2octaneLDA Lithium diisopropylamidedba Dibenzylidene acetoneLHMDS Lithium hexamethyldisilazideDBE 1,2-dibromoethaneLTBA Lithium tri-tert-butoxyaluminum hydrideDBN 1,8-diazabicyclo5.4.0undec-7-enemCPBA meta-cholorperoxybenzoic acidDBU 1,5-diazabicyclo4.3.0non-5-eneMe MethylDCC 1,3-dic
5、yclohexylcarbodiimideMEM b-methoxyethoxymethylDCE 1,2-dichloroethaneMes MesitylDDQ 2,3-dichloro-5,6-dicyano-1,4-benzoquinoneMin Minute % diasteromeric excessMOM methoxymethylDEA DiethylamineMs MethanesulfonylDEAD Diethyl azodicarboxylateMS Molecular sieves (3 or 4 ?)Dibal-H Diisobutylaluminum hydrid
6、eMTM Methylthiomethyldiphos (dppe) 1,2-bis (diphenylphosphino)ethaneNaphth Naphthyldiphos-4 (dppb) 1,4-bis (diphenylphosphino)butaneNBD NorbornadieneNBS N-BromosuccinimideTASF Tris(diethylamino)sulfonium difluorotrimethyl silicateNCS N-chlorosuccinimideTBAF Tetrabutylammonium fluorideNi(R) Raney Nic
7、kelTBDMS, TBS t-butyldimethylsilylNMO N-methyl morpholine-n-oxideTBHP t-butylhydroperoxidePCC Pyridinium chlorochromatet-Bu Tert-butylPDC Pyridinium dichromateTEBA TriethylbenzylammoniumPEG Polyethylene glycolTEMPO Tetramethylpiperdinyloxy free radicalPh PhenylTFA Trifluoroacetic acidPhH BenzeneTFAA
8、 Trifluoroacetic anhydridePhMe TolueneTf or OTf TriflatePhth PhthaloylTHF TetrahydrofuranPip PiperidylTHP TetrahydropyranylPr n-propylTMEDA TetramethylethylenediaminePy PyridineTMP 2,2,6,6-tetramethylpiperidinequant. quantitative yieldTMS TrimethylsilylRed-Al (MeOCH2CH2O)AlH2NaTol TolylsBu sec-butylTr TritylsBuLi sec-butyllithiumTRIS TriisopropylphenylsulfonylSiamyl DiisoamylTs (Tos) Tosyl (p-toluenesulfonyl)
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