种有机溶剂的极性和其他物理常数列表表格文件下载.xls

1、pp.408-411 AppendixTable A-1.Compilation of hundred important organic solvents together with their physical constants,arranged by decreasing ET-values as empirical parameter of solvent polarity.No.Solvent NameName in ChineseET（h）bp（C）（1）Water水1100（2）Formamide甲酰胺0.799210.5（3）1,2-Ethanediol乙二醇0.79197.

2、5（4）Methanol甲醇0.76264.5（5）N-Methylformamide甲基甲酰胺0.722180-185（6）Diethylene glycol双乙二醇0.713245.7（7）TriethyIene glycol三乙二醇0.704288（8）2-Methoxyethanol2-甲氧基乙醇0.667124.6（9）Tetraethylene glycol四乙二醇0.664327.3（10）N-Methylacetamide甲基乙酰胺0.657206.7（11）Ethanol乙醇0.65478.3（12）2-Aminoethanol氨基乙醇0.651170.95（13）Aceti

3、c acid乙酸0.648117.9（14）1-Propanol丙醇0.61797.15（15）Benzyl alcohol苄醇0.608205.45（16）1-Butanol丁醇0.602117.7（17）1-Pentanol戊醇0.568138（18）3-Methyl-1-butanol,Isoamyl alcohol异戊醇0.565130.5（19）2-Methyl-1-propanol,Isobutyl alcohol异丁醇0.552107.9（20）2-Propanolm）异丙醇0.54682.2（21）2-Butanol2-丁醇0.50699.5（22）Cyclohexanol环己

4、醇0.5161.1（23）Propylene carbonate碳酸丙二酯0.491241.7（24）2-Pentanol2-戊醇0.488119（25）Nitromethane硝基甲烷0.481101.2（26）3-Pentanol3-戊醇0.463115.3（27）Acetonitrile乙腈0.4681.6（28）Dimethylsulfoxide二甲亚砜0.444189（29）Aniline苯胺0.42184.4（30）SulfoIane环丁砜0.41287.3（dec.）（31）Acetic anhydride乙酸酐0.407140（32）N,N-Dimethyl-formamide

5、二甲基甲酰胺0.404153（33）N,N-Dimethyl-acetamide二甲基乙酰胺0.401166.1（34）Propanenitrile丙腈0.40197.35（35）2-Methyl-2-propanol,t-Butanol叔丁醇0.38982.3（36）1.3-Dimethyl-imidazolidin-2-one,DMEU二甲基乙撑脲0.364225.5（37）1-Methylpyrrolidin-2-one甲基砒咯烷酮0.355202（38）Acetone丙酮0.35556.1（39）1.3-Dimethyl-2-oxo-hexahydropyrimidine,DMPU二甲

6、基亚丙基脲0.352230（40）1,2-Diaminoethane乙二胺0.349116.9（41）Cyanobenzene腈基苯0.333191.1（42）1,2-Dichloroethane1,2-二氯乙烷0.32783.5（43）2-Butanone丁酮,甲乙酮0.32779.6（44）Nitrobenzene硝基苯0.324210.8（45）2-Methyl-2-butanol,t-Pentyl alcohol叔戊醇0.321102（46）2-Pentanone2-戊酮0.321102.3（47）Tetramethylurea四甲基脲0.318175.2（48）Morpholine吗

7、啉0.318128.9（49）Hexamethylphosphoric acid triamide,HMPT六甲基磷酰胺0.315233（50）3-Methyl-2-butanone异戊酮0.31594.2（51）Dichloromethane二氯甲烷0.30939.6（52）Acetophenone苯乙酮0.306202（53）Pyridine吡啶0.302115.25（54）Methyl acetate乙酸甲酯0.28756.9（55）Cyclohexanone环己酮0.281155.65（56）4-Methyl-2-pentanone4-甲基-2-戊酮0.269117.4（57）1,1-

8、Dichloroethane1,1-二氯乙烷0.269573（58）Quinoline喹啉0.269237.1（59）3-Pentanone3-戊酮0.265102（60）Chloroform氯仿0.25961.2（61）3,3-Dimethyl-2-butanone3,3-二甲基-2-丁酮0.256106.3（62）Triethylene glycol dimethyl ether三乙二醇二甲基醚0.253216（63）2,4-Dimethyl-3-pentanone2,4-二甲基-3-戊酮0.247125.25（64）Diethylene glycol dimethyl ether双乙二醇

9、二甲基醚0.244159.8（dec.）（65）1,2-Dimethoxyethane乙二醇二甲基醚0.23184.5（66）Ethyl acetate乙酸乙酯0.22877.1（67）1,2-Dichlorobenzene邻二氯苯0.225180.5（68）2,6-Dimethyl-4-heptanone2,6-二甲基-4-庚酮0.225168.2（69）Diethylene glycol diethyl ether双乙二醇二乙基醚0.21188.9（70）Tetrahydrofuran四氢呋喃0.20766（71）Methoxybenzene苯甲醚0.198153.6（72）Diethyl

10、 carbonate碳酸二乙酯0.194126.8（73）Fluorobenzene氟苯19484.7（74）1,1-Dichloroethene1,1-二氯乙烯0.19431.6（75）Chlorobenzene氯苯0.188131.7（76）Bromobenzene溴苯0.182155.9（77）Ethoxybenzene苯乙醚0.182169.8（78）lodobenzene碘苯0.17188.3（79）1,1,1-Trichloroethane1,1,1-三氯乙烷0.1774.1（80）1,4-Dioxane二噁烷0.164101.3（81）Trichloroethene三氯乙烯0.1

11、687.2（82）t-Butyl methyl ether叔丁基甲醚0.14855.2（83）Piperidine哌啶0.148106.2（84）Diethylamine二乙基胺0.14555.55（85）Diphenyl ether二苯醚0.142258.1（86）Diethylether乙醚0.117344（87）Benzene苯0.111801（88）Di-n-propyl ether二丙醚0.10290.1（89）Toluene甲苯0.099110.6（90）1,4-Dimethylbenzene对二甲苯0.074138.4（91）Di-n-butyl ether二丁醚0.071140

12、.3（92）Carbon disulfide二硫化碳0.06546.2（93）Tetrachloromethane四氯甲烷0.05276.6（94）Triethylamine三乙基胺0.04388.9（95）Tri-n-butylamine三丁基胺0.043214（96）cis-Decahydro-naphthaline顺十氢萘0.015195.8（97）n-Heptane正庚烷0.01298.4（98）n-Hexane正己烷0.00968.7（99）n-Pentane正戊烷0.00936.1（100）Cyclohexane环己烷0.00680.7a The physical constant

13、s were taken from the following references:#（1）R.C.Weast and M.J.Astle:#CRC Handbook of Data on Organic Compounds.Vol.I and II,CRC Press,Boca Raton/Florida 1985;#（2）R C.Weast（ed.）:#Handbook of Chemistry and Physics,66th edition.CRC Press,Boca Raton/Florida 1985/86;#（3）J.A.Riddick,W.B.Bunger,and T.K.

14、Sakano:#Organic Solvents.Physical Properties and Methodrof Purification.4th edition.In A.Weissberger（ed.）:#Techniques of Chemistry,Vol.II,Wiley-lnterscience,New York 1986:#（4）A.L.McClellan:#Tables of Experimental Dipole Moments.Freeman.San Francisco.London 1963;#（5）A.A.Maryott and E.R.Smith:#Table o

15、f Dielectric Constants of Pure Liquids.NBS Circular 514;#Washington 1951;#（6）Deilsteins Handbook of Organic Chemistry.Springer-Verlag,Berlin;#（7）M.Windholz（ed.）:#The Merck Index.10th edition,Rahway/New Jersey 1983.b C.Reichardt and E.Harbusch-Grnert.Liebigs Ann.Chem 1983,721;#C.Laurence,P.Nicolet.M.

16、Lucon,and C.Reichardt,Bull.Soc Chim Fr 1987,125:#ibid.1987,1001;#cf.also Table 7-3 in Chapter 7.c Melting point.d Boiling point at 1013 mbar.e Relative permittivity（dielectric constant）for the pure liquid at 25C unless followed by another temperature in parentheses.f Dipole moment in Coulombmeter（10（-30）C m）.measured in benzene,tetrachloromethane,1,4-dioxane.Or n-hexane at 20-30C.1 Debye=3.336x10-30 Cm.g Refractive index at the average D-line of sodium（16969 cm-1）at 20C unless followed by another temperature in p