电化学活性的化合物.docx

电化学活性的化合物.docx

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电化学活性的化合物

具有电化学活性的化合物参考表

具有电化学活性的基团

举例

可氧化的化合物举例

下面是一个假想的化合物，说明具有电化学活性的各种官能团。

具有电化学活性的化合物是芳香族化合物，或含有羟基，甲氧基或胺等官能团。

脂肪族化合物，如硫醇（类）和胺类也具有电化学活性。

某些化合物例如：

碳水化合物，需要特殊的检测方式，称之为脉冲安培检测法或简称PAD.

1）OXIDATIONONCARBONWORKINGELECTRODE.DCMODE

2）REDUCTIONONCARBONWORKINGELECTRODE.DCMODE

3）OXIDATIONONCARBONWORKINGELECTRODEFOLLOWINGDERIVATIZATION

4）OXIDATIONONMERCURYORMERCURY/GOLDAMALGAM.DCMODE

5）OXIDATIONONGOLDWORKINGELECTRODE.PADMODE

许多化合物具有电化学活性，可以用HPLC-ECD（带电化学检测器的高压液相）进行检测。

以下所列的是各种具有电化学活性的化合物，这是基于他们的化学结构或引自科学文献。

所列化合物仅供参考，并非暗示可从ESA公司获得所有这些化合物的分析方法。

氨基酸类AMINOACIDS（e.g.brain,plasma,CSF,microdialysis）

UnderivatizedDerivatized

Methionine蛋氨酸，甲硫氨酸withOPA/ßME

Tryptophan色氨酸

Tyrosine酪氨酸alpha-AMINO

BUTYRICACID丁酸

Alanine丙胺酸

Arginine精氨酸

Asparticacid天（门）冬氨酸

Asparagine天冬酰胺酸

ß-alanineß-丙胺酸

ß-aminobutyricacidß-氨基丁酸

（carnosine）肌肽

citrulline瓜氨酸

Cysteine（cystine）半光胺酸

gamma-aminobutyricacid

Glutamicacid-氨基丁酸

Glutamine谷氨酸盐

Glycine氨基乙酸

Histamine组胺

Histidine组胺酸

Isoleucine异亮安酸

Leucine亮氨酸

Lysine赖氨酸

Methionine蛋氨酸，甲硫氨酸

Nitro-arginineNitro-精氨酸

Phenylalanine苯基丙氨酸

Phospho-ethanolamine

Serine丝氨酸

Taurine

Threonine苏氨酸

Tryptophan色氨酸

Tyrosine酪氨酸

Valine

DerivatizedMiscellaneous

withNBDChlorideDi-peptides（widevarietycontainingtrp,tyrormet）

Hydroxy-proline羟基脯氨酸Homocarnosine

Proline脯氨酸N-acetyl-histidineN-乙酰基组氨酸

1-methylhistidine1-甲基组氨酸

3-methylhistidine3-甲基组氨酸

3-nitrotyrosine3-硝基酪氨酸

3,3,5tri-iodothyronine

Thyroxine甲状腺素

Tri-peptides（widevarietycontainingtrp,tyrormet）

抗氧化剂ANTIOXIDANTS

t-butylhydroquinone4,6-di-t-butyl-3-cresol

t-butyl-4-hydroxy-5-methylphenylsulfide2,6-di-t-butyl-4-ethylphenol

t-butylhydroxyanisole3,5-di-t-butylhydroxyanisole

3-t-butyl-4-hydroxy-5-methylphenylsulfide2,5-di-t-butylhydroquinone

butylhydroxytoluene2,6-di-t-butyl-4-hydroxymethylphenol

2-t-butyl-4-methylphenol2,6-di-t-butyl-4-methylphenol

2-t-butyl-6-methylphenol2,6-di-t-butylphenol

4-t-butyl-2-methylphenol2,4-di-t-butylphenol

2-t-butyl-5-methylphenol3,5-di-t-butylphenol

3-t-butyl-5-methylcatechol2,6-di-s-butylphenol

5-t-butyl-3-methylcatechol4,6-di-t-butylresorcinol

2-s-butylphenol2,2'-methylenebis（6-t-butyl-4-cresol）

4-s-butylphenol4,4'-methylenebis（6-t-butyl-4-cresol）

2-t-butylphenol4,4'-thio-bis（6-t-butyl-2-cresol）

3-t-butylphenol2,4,6-tri-t-butylphenol

4-t-butylphenoldodecylgallate

2,6-di-t-butyl-3-dimethylamino-p-cresolnonylgallate

2,6-di-t-butyl-4-benzoquinoneoctylgallate

2,6-di-butyl-4-n-butylphenolpropylgallate

3,5-di-t-butylcatechol

2,6-di-t-butyl-4-cresol

CHLORINATEDANILINES

2-chloroaniline

3-chloroaniline

4-chloroaniline

2,3-dichloroaniline

2,4-dichloroaniline

2,5-dichloroaniline

2,6-dichloroaniline

3,4-dichloroaniline

3,5-dichloroaniline

2,3,4-trichloroaniline

2,4,5-trichloroaniline

2,4,6-trichloroaniline

2,3,4,5-tetrachloroaniline

2,3,5,6-tetrachloroaniline

Pentachloroaniline

CHLORINATEDNAPHTHOLS

4-chloronaphthol2,4-dichloronaphthol

CHLORINATEDPHENOLS

2-chlorophenol

3-chlorophenol

4-chlorophenol

2,3-dichlorophenol

2,4-dichlorophenol

2,5-dichlorophenol

2,6-dichlorophenol

3,4-dichlorophenol

3,5-dichlorophenol

2,3,4-trichlorophenol

2,3,5-trichlorophenol

2,3,6-trichlorophenol

2,4,5-trichlorophenol

2,4,6-trichlorophenol

3,4,5-trichlorophenol

2,3,4,5-tetrachlorophenol

2,3,4,6-tetrachlorophenol

2,3,5,6-tetrachlorophenol

pentachlorophenol

3,5-dimethylphenol

2,3,6-trimethylphenol

2,3,5-trimethylphenol

2,3,5-trimethylphenol

DNA加合物DNAADDUCTS

3-methylGuanine8-nitroGuanine

7-methylGuanine8-hydroxy-2'-deoxyguanosine

O-6-methylGuanine8-hydroxyguanosine

GNmethylGuanine5-oxocytidine

GRmethylGuanine

药DRUGS（microdialysis,plasmaextracts）

1-Phenylethylamine

10-Hydroxyamitriptyline

10-Hydroxyimipramine

10-Hydroxynortriptyline

11-Hydroxyclomipramine

2-Hydroxydesipramine

2-Hydroxymipramine

2-Phenylethylamine

3-Monoacetylmorphine

4-Hydroxypropranolol

6-Monoacetylmorphine

Acebutolol

Acepromazine

Acetamide乙酰胺

Acetophenazine

Acetorphine

N-Acetylproccainamide（NAPA）

Adiphenine

Ajmaline

Allylprodine

Alphacetylmethadol

Alphameprodine

Alphamethadol

Alphaprodine

Alprenolol

Alverine

Amiloride

Aminopromazine

Amoxicillin

Amthocaine

Amidopyrine

Amiodarone

Amitriptyline

Amotriphene

Anileridine

Antazoline

Apomorphine阿朴吗啡

Atenolol

Atropine阿托品

Azacyuclonal

Bamethane

Benactyzine苯乃静（一种安定药）

Benperidol

Benzethidine

Benzhexol

Benzocaine

Benzoylecgonine

Benzphetamine

Benzquinamide

Benztropine

Benzylmorphine

Benzylpenicillin卞青霉素

Betacetylmethadol

Betahistine

Betameprodine

Betamethadol

Betaprodine

Bezitramide

Bromhexine

Bromodiphenhydramine溴苯海拉明（抗组胺药）

Bromperidol

Brompheniramine

Brompromazine

Brucine

Buclizine

Bufotenine蟾毒色胺

Bephenine

Bupivacaine

Buprenorphine

Butacaine

Butaperazine

Butethamate

Butriptyline

Carbenicillin

Carbinoxamine

Carphenazine

Cephaline

Chlorcyclizine

Chloropyriline

Chloroquine氯喹（治疟疾）

Chlorpheniramine

Chlorphenoxamine

Chlorprenaline

Chlorproethazine

Chlropromazine

Chlroprothixene

Cimetidine

Cinchocaine

Cinchonidine金鸡纳啶

Cinnarizine

Clemastine

Clemizole

Clomipramine

Clonidine

Cocaine古柯碱,可卡因

Codeine可待因（自鸦片中提取的碱质）

Cyclazocine

Cyclizine

Cyclopentamine

Cyclopentolate

Cyproheptadine

Cyrenorphine

Debrisoquine

Deptropine

Desacetylthymoxamine

Desacetylvinblastine

Desalkyldisopyramide

Deserpidine

Desethlamiodarone

Desipramine

Desmthyldesipramine

Desomorphine

Dextromthorphan

Dextromoramide

Dextropropxyphene

Dextrorphan

Diapromide

Dibenzepin

Diethazine

Diethylpropion

Diethylstilbestrol

Dienostrol

Diethylthiambutene

Digydrocodeine

Dihydrocodeinone

Dihydroergotamine

Dihydromorphine

Dimenoxadole

Dimethyindene

Dimethisoquin

Dimethothiazine

Dimethoxanate

Dimethylthiambutene

Dioxaphetylbutyrate

Diphenhydramine

Diphenoxylate

Diphenoxylicacid

Diphenlpyraline

Dipipanone

Diprenorphine

Dipyridamole

Disopyramide

Dopamine多巴胺（一种治脑神经病的药物）

Dothiepin

Dothiepin5-oxide

Doxapram

Doxepin多虑平，凯舒（一种抗抑郁药）

Doxylamine抗敏安

Droperidol

Embramine

Emetine依米丁,吐根碱,吐根素（用作催吐剂等）

Ephedrine麻黄碱,麻黄素

Ergocornine

Ergocristine

Ergocristinine

Ergocryptine

Ergometrine麦角新碱（用于催产和缓解偏头痛）

Ergosine

Ergosinine

Ergotamine麦角胺（主要用于治偏头痛和防止产后大出血）

Estrone雌激素酮

Etafedrine

Etamiphylline

Ethinyloestradiol

Ethoheptazine

Ethopropazine

Ethylmorphine

Etonitazene

Etorphine

Etoxeridine

Fencamfamin

Fenethazine

Fenfluramine（抑制食欲以治肥胖的）氟苯丙胺

Fenoterol

Fentanyl

Flavoxate

Fluopromazine

Flupenthixol

Flupenthixol5-oxide

Fluphenazine

Flurazepam

Glycopyrronium

Haloperidol

Halopyramine

Harmine

Herion

Hexoestrol

Histapyrrodine

Homatropine

Hydrastinine白毛莨分碱

Hydrochlorothiazide

Hydrocodone

Hydromorphinol

Hydromorphone

Hydroxypethidine

Hydroxyzine

Hyoscine

Hyoscyamine

Ibogaine

Imipramine

ImipramineN-oxide

Indapamine

Indole吲哚

Iprindole

Isolysergide

Isomethadone

Isothpendyl

Isoxsuprine

Ketanserin

Ketobemidone

Labetalol

Laudanosine

Levallorphan

Levomepromazene

Levomethorphan

Amylocaine

Benzocaine

Tetracaine

Lidocaine

Phenacetin乙酰对氨苯乙醚,非那西汀（解热镇痛剂的一种）

Paracetamol

Salicylamide

Amitriptylene

Protriptylene

Nortriptyline

Carbamazepine

Imipramine

Desipramine

Tripramine

Opipramine

Sulphacetamide

Sulphadiazine

Sulphaguanidine

Sulphamerrazine

SulphathiazolLevorphanol

Lidoflazine

Lignocaine利诺卡因,二乙氨基（麻醉用）

Lofepramine

Lorcainide

Loxapine

Lysergamide

Lysergicacid麦角酸

Lysergide（LSD）

Lysergol

Maprotiline

Mebanazine

Mebeverine

Mebhydrolin

Mecamylamine

Meclophenoxate

Meclozine

Medazepam

Mephentermine

Mepivacaine

Meptazinol

Mepyramine

Mequitazine

Mescaline酶斯卡灵（一种致幻剂）

Mesoridazine

Metacillin

Metaraminol

Metazocine

Methadone

Methapyriline

Methdilazine

Methizine

Methoserpidine

Methotrimeprazine

Methoxamine

Methoxyphenamine

Methoxypromazine

Methlamphetamine

Methyldesorphine

Methylephendrine

Methylergometrine

Methylphenidate

Methylsergide

Metoclopramide

Metopimazine

Metoprolol

Mianserin

Monoethylglycinexylidide（MEGX）

Morazone

Morpheridine

MorphineN-oxide

Morphine吗啡

Myrophine

Nadolol

Nalorphine

Naloxone

Naphazoline

Narceine罂粟碱

Nefopam

Nialamide

Nicocodine

Nicotine烟碱

Nifedipine

Nomifensine

Norbutriptyline

Norchlorpromazine

Norchlomipramine

Norcodeine

Norcyclizine

Nordextropropoxyphene

Nordothiepin

Nordotheipin5-oxide

Nordoxepin

Norphenfluramine

Normianserin

Normorphine

Nororphenadrine

Norpethidine

Nortrimipramine

Nortriptyline

Norverapamil

Norzimelidine

Noscapine

Opipramol

Orphenadrine

Oxacillin

Oxeladin

Oxomemazine

Oxprenolol

Oxycodone

Oxymetazolin

Oxymorphone

Oxypertine

p-Chlorodisopyramide（CDP）

Papaverine

Pargyline

Pecazine

Penbutolol

Pentazocine

Penthienate

Perazine

Perhexiline

Perphenazine

Pethidine

Pethidinicacid

Phenadoxone

Phenampromide

Phenazocine

Phenbutrazate

Phencyclidine

Phendimetrazine

Phenelzine

Phenglutamide

Phenindamine

Pheniramine

Phenmetrazine

Phenomorphan

Phenoperidine

Phenothiazine

Phenolxybenzamine

Phentolamine

Phenylephrine

Phenltoloxamine

Pholcodeine

Physostigmine

Piminnodine

Pimozide

Pindolol

Pipamazine

Pipazethate

Piperacetazine

Piperidolate

Pipradrol

Pirbuterol

Pirenzepine

Pitramide

Pizotifen

Practolol

Prajmalium

Pramoxine

Prazosin

Prenylamine

Prilocaine

Primaquine

Proadifen

Procainamide

Procaine普鲁卡因（一种局部麻醉药）

Prochlorperazine

Procyclidine

Proheptazine

Prolintane

Promazine

Promethazine

Pronethalol

Propanolol

Properadine

Propiomazine

Propranolol

Prothipendyl

Protokylol

Protriptyline

Proxymetacaine

Pseudoephedrine

Psilocin